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Light-weight graphene conductive thin film and preparation method thereof

A technology of conductive film and graphene, which is applied in the field of lightweight graphene conductive film and its preparation, can solve the problems of low mechanical strength, poor mechanical properties, and high film brittleness, so as to improve mechanical stability and strength, and improve dispersion compatibility performance, to achieve the effect of dispersion uniformity

Inactive Publication Date: 2018-09-28
戚明海
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Conductive thin film is a very important optoelectronic material. It has the characteristics of low resistance and is widely used in various optoelectronic materials such as solar cells, electrode materials, and displays. At present, inorganic oxide thin films are widely used. Good chemical resistance, low resistivity, good chemical temperature resistance, but as an inorganic filler, its film has high brittleness, poor toughness, and high synthesis temperature, all of which limit their further development. Therefore, polymers gradually appear in the market Conductive materials, including polyaniline, polypyridine, etc., polyaniline is widely used due to its good stability in the air, easy access to raw materials, cheap monomers, simple synthesis methods, and easy adjustment of conductivity, such as electrode materials , electrochromic materials, metal anti-corrosion materials, electromagnetic shielding materials, anti-static materials, molecular devices, etc., but because polyaniline has the disadvantages of low mechanical strength and poor mechanical properties; at the same time, the use of inorganic particles to enhance polyaniline is easy to cause particles agglomeration, thereby reducing the mechanical stability of the finished film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A kind of lightweight graphene conductive film, it is made up of the raw material of following weight part:

[0024] Stearic acid 3, organic calcium carbonate 14, 2-mercaptobenzimidazole 1, coconut acid diethanolamide 2, graphene oxide 6, polyaniline 90, borax 3, calcium ricinoleate 1, phosphorus trichloride 4, Pentaerythritol 3, hexamethylcyclotrisiloxane 0.2, barium stearate 1.

[0025] Described a kind of lightweight graphene conductive film, described organic calcium carbonate is made up of the raw material of following weight part:

[0026] Sodium carbonate 16, calcium oxide 14, melamine 2, hexafluoroacetylacetone 0.2, casein 0.4;

[0027] The preparation method of described organic calcium carbonate, comprises the following steps:

[0028] (1) Take calcium oxide, add it to deionized water 20 times its weight, and stir evenly;

[0029] (2) Take hexafluoroacetylacetone, add it to 9 times its weight in absolute ethanol, stir evenly, add melamine, raise the tempera...

Embodiment 2

[0039] A kind of lightweight graphene conductive film, it is made up of the raw material of following weight part:

[0040] Stearic acid 4, organic calcium carbonate 10, 2-mercaptobenzimidazole 0.5, coconut acid diethanolamide 1, graphene oxide 5, polyaniline 80, borax 2, calcium ricinoleate 0.8, phosphorus trichloride 3, Pentaerythritol 2, hexamethylcyclotrisiloxane 0.1, barium stearate 0.8.

[0041] Described a kind of lightweight graphene conductive film, described organic calcium carbonate is made up of the raw material of following weight part:

[0042] Sodium carbonate 10, calcium oxide 10, melamine 1, hexafluoroacetylacetone 0.1, casein 0.1;

[0043] The preparation method of described organic calcium carbonate, comprises the following steps:

[0044] (1) Take calcium oxide, add it to deionized water 17 times its weight, and stir evenly;

[0045] (2) Take hexafluoroacetylacetone, add it to anhydrous ethanol 5 times its weight, stir evenly, add melamine, raise the tem...

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Abstract

The invention discloses a light-weight graphene conductive thin film and a preparation method thereof. The light-weight graphene conductive thin film is prepared from the following raw materials in parts by weight: 10 to 14 parts of organic calcium carbonate, 0.5 to 1 part of 2-mercapto benzimidazole, 1 to 2 parts of coco fatty acid diethanol amide, 5 to 6 parts of graphene oxide, 80 to 90 parts of polyaniline, 2 to 3 parts of borax, 0.8 to 1 part of calcium ricinoleate, 3 to 4 parts of phosphorus trichloride, 2 to 3 parts of pentaerythritol, 0.1 to 0.2 part of hexamethylcyclotrisiloxane, and0.8 to 1 part of barium stearate. The light-weight graphene conductive thin film has the advantages that the graphene and the calcium carbonate are blended and combined, so that the mechanical strength of the finished material is improved; by modifying the surface, the dispersing uniformity is realized, and the mechanical stability strength of the finished product is improved; by adding the graphene, the stable conductive property of the finished thin film is realized.

Description

technical field [0001] The invention belongs to the field of thin films, and in particular relates to a lightweight graphene conductive thin film and a preparation method thereof. Background technique [0002] Conductive thin film is a very important optoelectronic material. It has the characteristics of low resistance and is widely used in various optoelectronic materials such as solar cells, electrode materials, and displays. At present, inorganic oxide thin films are widely used. Good chemical resistance, low resistivity, good chemical temperature resistance, but as an inorganic filler, its film has high brittleness, poor toughness, and high synthesis temperature, all of which limit their further development. Therefore, polymers gradually appear in the market Conductive materials, including polyaniline, polypyridine, etc., polyaniline is widely used due to its good stability in the air, easy access to raw materials, cheap monomers, simple synthesis methods, and easy adjus...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/02C08K13/06C08K9/04C08K3/26C08K5/20C08K3/04C08K3/38C08J5/18
CPCC08J5/18C08J2379/02C08K3/042C08K5/20C08K9/04C08K13/06C08K2003/265C08K2003/387C08K2201/001
Inventor 戚明海
Owner 戚明海