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Anti-impact conductive film and preparation method thereof

A conductive film, impact-resistant technology, used in equipment for the manufacture of conductive/semiconductor layers, cable/conductor manufacturing, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problem of low mechanical strength of polyaniline, synthetic High temperature, poor mechanical properties and other problems, to achieve the effect of improving mechanical stability, good electrical conductivity and high impact strength

Inactive Publication Date: 2018-10-02
繁昌县盛民机械制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Conductive thin film is a very important optoelectronic material. It has the characteristics of low resistance and is widely used in various optoelectronic materials such as solar cells, electrode materials, and displays. At present, inorganic oxide thin films are widely used. Good chemical resistance, low resistivity, good chemical temperature resistance, but as an inorganic filler, its film has high brittleness, poor toughness, and high synthesis temperature, all of which limit their further development. Therefore, polymers gradually appear in the market. Conductive materials, including polyaniline, polypyridine, etc., polyaniline is widely used due to its good stability in the air, easy access to raw materials, cheap monomers, simple synthesis methods, and easy adjustment of conductivity, such as electrode materials , electrochromic materials, metal anti-corrosion materials, electromagnetic shielding materials, anti-static materials, molecular devices, etc., but due to the rigidity of polyaniline chains and the strong interaction between chains, its solubility is extremely poor, almost insoluble in solvents Therefore, its wide application in technology is limited, and at the same time, polyaniline has the disadvantages of low mechanical strength and poor mechanical properties;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A kind of impact-resistant conductive film, it is made up of the raw material of following weight part:

[0019] Polytetrafluoroethylene 110, carbon nanotubes 10, diphenyl imidazoline 0.8, polyamide wax micropowder 4, 6-hydroxy-2-naphthoic acid 0.7, dodecyl dimethyl betaine 1, polyethylene glycol 4 , Zinc stearate 1, polyoxyethylene oleate 3, polyaniline 13.

[0020] A method for preparing an impact-resistant conductive film, comprising the following steps:

[0021] (1) Take diphenylimidazoline, add it to 7 times its weight in absolute ethanol, stir evenly, raise the temperature to 60°C, add zinc stearate, and keep stirring for 10 minutes to obtain an alcohol dispersion;

[0022] (2) Mix dodecyl dimethyl betaine and carbon nanotubes, add to deionized water 24 times the weight of the mixture, and ultrasonicate for 5 minutes to obtain a carbon nanotube dispersion;

[0023] (3) Mix polyamide wax micropowder and 6-hydroxy-2-naphthoic acid, add it to dimethylformamide whic...

Embodiment 2

[0028] A kind of impact-resistant conductive film, it is made up of the raw material of following weight part:

[0029] Polytetrafluoroethylene 130, carbon nanotubes 16, diphenyl imidazoline 1, polyamide wax micropowder 6, 6-hydroxy-2-naphthoic acid 1, dodecyl dimethyl betaine 2, polyethylene glycol 5 , zinc stearate 2, polyoxyethylene oleate 4, polyaniline 13.

[0030] A method for preparing an impact-resistant conductive film, comprising the following steps:

[0031] (1) Take diphenylimidazoline, add it to 9 times its weight in absolute ethanol, stir evenly, raise the temperature to 65°C, add zinc stearate, and keep stirring for 20 minutes to obtain an alcohol dispersion;

[0032] (2) Mix dodecyl dimethyl betaine and carbon nanotubes, add them to deionized water 30 times the weight of the mixture, and ultrasonicate for 10 minutes to obtain a carbon nanotube dispersion;

[0033] (3) Mix polyamide wax micropowder and 6-hydroxy-2-naphthoic acid, add it to dimethylformamide wh...

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Abstract

The invention discloses an anti-impact conductive film, which is prepared from the following raw materials in parts by weight: 110-130 parts of polytetrafluoroethylene, 10-16 parts of carbon nanotubes, 0.8-1 part of diphenyl imidazoline, 4-6 parts of polyamide wax micro-power, 0.7-1 part of 6-hydroxy-2-naphthoic acid, 1-2 parts of dodecyl dimethyl betaine, 4-5 parts of polyethylene glycol, 1-2 parts of zinc stearate, 3-4 parts of oleic acid polyoxyethylene ester and 10-13 parts of polyaniline. The nanotubes are firstly processed by adopting a diphenyl imidazoline ethanol solution and then dispersed into an amide solution, so that surface activity of the nanotubes are effectively improved, the aggregation is effectively reduced, and the mechanical stability of the finished film is improved.

Description

technical field [0001] The invention belongs to the field of thin films, and in particular relates to an impact-resistant conductive thin film and a preparation method thereof. Background technique [0002] Conductive thin film is a very important optoelectronic material. It has the characteristics of low resistance and is widely used in various optoelectronic materials such as solar cells, electrode materials, and displays. At present, inorganic oxide thin films are widely used. Good chemical resistance, low resistivity, good chemical temperature resistance, but as an inorganic filler, its film has high brittleness, poor toughness, and high synthesis temperature, all of which limit their further development. Therefore, polymers gradually appear in the market Conductive materials, including polyaniline, polypyridine, etc., polyaniline is widely used due to its good stability in the air, easy access to raw materials, cheap monomers, simple synthesis methods, and easy adjustme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B5/00H01B1/24H01B13/00
CPCH01B5/00H01B1/24H01B13/0016H01B13/0026
Inventor 不公告发明人
Owner 繁昌县盛民机械制造有限公司