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Biomass solid clean fuel as well as preparation method and application thereof

A technology for clean fuels and biomass raw materials, applied in solid fuels, biofuels, waste fuels, etc., can solve the problems of no solid clean fuels, insignificant economic benefits, increased processing costs, etc., and achieves simple and feasible preparation. Low content and low cost effect

Inactive Publication Date: 2018-12-04
湖南大学深圳研究院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hydrothermal gasification and hydrothermal liquefaction need to be carried out under high temperature and high pressure conditions. If it is used for sludge treatment, the energy consumption is high and the economic benefits are not significant
However, the research on the preparation of solid fuel by hydrothermal carbonization of biomass is still in the initial stage in my country, and the reaction parameters used in the hydrothermal carbonization are different for different types of organic solid wastes with high moisture content in the existing research. At the same time, the liquid product produced after hydrothermal carbonization treatment still needs to be treated twice, which will not only increase the treatment cost, but also increase the risk of secondary pollution
In addition, there are very few studies on the hydrothermal carbonization of sludge combined with biomass waste, and no method has been found that can effectively use sludge combined with biomass waste to produce solid clean fuels.

Method used

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  • Biomass solid clean fuel as well as preparation method and application thereof
  • Biomass solid clean fuel as well as preparation method and application thereof
  • Biomass solid clean fuel as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0038] A kind of biomass solid clean fuel, which is made of sludge (residual dewatered sludge of urban sewage treatment plant) and biomass waste (sawdust) as raw materials, after pretreatment, acid-base treatment and hydrothermal carbonization After treatment, it is made by hot pressing. The atomic percentage of carbon in the prepared biomass solid clean fuel is 41.70%, and the atomic percentage of nitrogen is 2.09%. The high calorific value of the biomass solid clean fuel can reach 17.70MJ / kg .

[0039] A preparation method of the biomass solid clean fuel in the above-mentioned present embodiment, comprising the following steps:

[0040] (1) Pretreatment of sludge and biomass waste:

[0041] (1.1) Wash and dry the sawdust, specifically at 40°C for 24 hours; crush the dried sawdust through a 1mm sieve.

[0042] (1.2) Mix 10g of sawdust sieved in step (1.1) with 100g of sludge with a water content of 90% (residual dewatered sludge from urban sewage treatment plants), and stir...

Embodiment 2

[0054] A kind of biomass solid clean fuel, the biomass solid clean fuel is made of sludge (residual dewatered sludge of urban sewage treatment plant) and biomass waste (corncob) as raw materials, after pretreatment, acid-base treatment and hydrothermal It is produced by hot pressing after carbonization treatment, and the atomic percentage of carbon in the prepared biomass solid clean fuel is 50.13%; the higher calorific value of the biomass solid clean fuel is 22.22MJ / kg.

[0055] A preparation method of the above-mentioned biomass solid clean fuel in this embodiment, compared with the preparation method in Embodiment 1, the difference is that: in step (1), the biomass waste is corn cobs; in step (2) , the pH value was adjusted to 7; in step (3), the temperature in the reactor was 260°C.

[0056] The biomass solid clean fuel prepared in Example 2 of the present invention is coded as SS-CC.

Embodiment 3

[0058] A kind of biomass solid clean fuel, the biomass solid clean fuel is made of sludge (residual dewatered sludge of urban sewage treatment plant) and biomass waste (corn straw) as raw materials, after pretreatment, acid-base treatment and hydrothermal It is produced by hot pressing after carbonization treatment, and the carbon content in the prepared biomass solid clean fuel is 37.45%; the higher heat value of the biomass solid clean fuel is 15.92MJ / kg.

[0059] A preparation method of biomass solid clean fuel in the above-mentioned embodiment, compared with the preparation method in embodiment 1, the difference is that: in step (1), the biomass waste is corn stalks; in step (2) , the pH value was adjusted to 7; in step (3), the temperature in the reactor was 260°C.

[0060] The biomass solid clean fuel prepared in Example 3 of the present invention is coded as SS-CS.

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Abstract

The invention discloses a biomass solid clean fuel as well as a preparation method and application thereof. A percentage of carbon atoms in the biomass solid clean fuel is 37.15%-50.24%, and the highcalorific value is 13.50 MJ / kg-22.22 MJ / kg; and the clean fuel is prepared by the following steps: sludge and biomass waste are used as raw materials, pre-treatment is performed, acid-base treatment is performed, hydrothermal carbonization treatment is performed, hot press molding is performed, and therefore the clean fuel is prepared. The biomass solid clean fuel disclosed by the invention has the advantages of a high carbon content, a low nitrogen content, a high calorific value, less pollution, simple and easy preparation and low costs, and is a novel clean material; the preparation methodhas the advantages of a simple and easy preparation process, low costs, less energy consumption, short consumed time and conditions easy to control; and the biomass solid clean fuel has the advantagesof simple operation, high energy conversion efficiency and less secondary pollution when being used for combustion to generate energy as a fuel, and the energy clean utilization of the biomass solidclean fuel can be realized.

Description

technical field [0001] The invention belongs to the field of solid fuels, and relates to a biomass solid clean fuel and a preparation method and application thereof. Background technique [0002] Municipal sewage sludge is a solid waste produced in the process of sewage treatment. It has the characteristics of high moisture content, high heavy metal content and high bacterial content, so it is difficult to treat. Today, more than 80% of sludge is still treated by the traditional method of compression dehydration-landfill, and these traditional treatment methods have caused serious secondary pollution and emitted a large amount of greenhouse gases, which greatly offset the emission reduction of sewage treatment As a result, sludge treatment and disposal are faced with the dual pressure of secondary pollution prevention and carbon emission reduction. Not only that, as more sewage treatment plants are built, the amount of sewage sludge produced will also increase day by day. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L5/44C10L5/46
CPCC10L5/46Y02E50/10Y02E50/30
Inventor 彭川翟云波朱云王腾飞王涛
Owner 湖南大学深圳研究院
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