Inorganic penetration waterproof agent
A waterproofing, inorganic technology, applied in the field of building materials, can solve the problems of poor waterproof performance and poor self-repairing ability, and achieve the effect of increasing the load, good monodispersity, and improving self-compacting performance.
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[0025] The preparation method of the slow-osmosis self-healing active substance is as follows:
[0026] S1. Take the nano-ferric oxide powder and add ethanol with a mass fraction of 90% according to the mass ratio of 1~4:10~15, and then add methacrylic acid-3-(trimethacrylic acid) with a mass ratio of 10-20% of the nano-ferric oxide powder. Oxysilyl) propyl ester, ultrasonically dispersed for 20~30min to obtain an ultrasonic dispersion, heated to 65~70°C, added ammonia water with 5~10% of the mass of the ultrasonic dispersion, stirred and mixed for 12~15h, attracted by a magnet, and the attractant Wash with ultrapure water and absolute ethanol, and dry to obtain a dried product;
[0027] S2. Take the dry matter and add ultrapure water according to the mass ratio of 2~5:40~70, pass through nitrogen protection, add glycidyl methacrylate 2~5 times the amount of dry matter and 30~50% of the amount of dry matter Vinylbenzene, stir and mix at 70~75°C for 20~30min to obtain a stirre...
Embodiment 1
[0038] The preparation method of the slow-osmosis self-healing active substance is as follows:
[0039] S1. Take the nano-ferric oxide powder and add ethanol with a mass fraction of 90% at a mass ratio of 1:10, and then add methacrylic acid-3-(trimethoxysilyl)acrylic acid with a mass ratio of 10% of the nano-ferric oxide powder. Esters were ultrasonically dispersed for 20 minutes to obtain an ultrasonic dispersion, heated to 65°C, added ammonia water with 5% mass of the ultrasonic dispersion, stirred and mixed for 12 hours, attracted by a magnet, washed with ultrapure water and absolute ethanol, and dried to obtain a dry thing;
[0040] S2. Take the dry matter and add ultrapure water according to the mass ratio of 2:40, pass through nitrogen protection, add glycidyl methacrylate twice the amount of dry matter and divinylbenzene with 30% of the dry matter, and stir at 70°C Mix for 20 minutes to obtain a stirred mixture, take the stirred mixture and add potassium persulfate at ...
Embodiment 2
[0051] The preparation method of the slow-osmosis self-healing active substance is as follows:
[0052] S1. Take the nano-ferric oxide powder and add ethanol with a mass fraction of 90% at a mass ratio of 3:12, and then add methacrylic acid-3-(trimethoxysilyl)acrylic acid with a mass ratio of 15% of the nano-ferric oxide powder. Ester, ultrasonically dispersed for 25 minutes to obtain an ultrasonic dispersion, heated to 68°C, added ammonia water with 8% mass of the ultrasonic dispersion, stirred and mixed for 14 hours, attracted by a magnet, washed with ultrapure water and absolute ethanol, and dried to obtain a dry thing;
[0053] S2. Take the dry matter and add ultrapure water according to the mass ratio of 3:65, pass through nitrogen protection, add glycidyl methacrylate with 4 times the amount of dry matter and divinylbenzene with 40% of the dry matter, and stir at 73°C Mix for 25 minutes to obtain a stirred mixture. Take the stirred mixture and add potassium persulfate a...
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