Production and processing process of environment-friendly leather

A processing technology and leather technology, applied in the field of environmental protection leather production and processing technology, can solve the problems of resource shortage, low shrinkage temperature, etc., and achieve the effects of reducing chromium pollution, less pollution, and shortening soaking time.

Active Publication Date: 2018-12-18
广西钦州中港皮业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Tanning is one of the key processes in leather making. Chrome tanning has been dominant in the tanning field since its wide application, but due to chromium pollution and resource shortage, chrome tanning will be replaced. However, other inorganic tanning agents tanning It cannot be compared with chrome tanned leather in terms of shrinkage temperature, and the leather tanned by synthetic organic tanning agents has good plumpness, but the shrinkage temperature is also lower, so the leather industry urgently needs to develop and develop new tanning agents.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The weight of each raw material of the soaking agent is: tetrabutylammonium bisulfate 5g, hyaluronic acid 10g, polydimethylsiloxane 2g, hydroxyethyl acrylate 4g, 5% sodium chloride solution 1.5g, propylene glycol 25g, the balance It is deionized water; add tetrabutylammonium bisulfate, hyaluronic acid, 5% sodium chloride solution and deionized water into the stirrer, heat to 65g°C, stir for 2h, let stand and cool to 45°C, add poly Dimethylsiloxane, hydroxyethyl acrylate and propylene glycol were stirred at a constant temperature for emulsification for 20 minutes to obtain a water soaking agent;

[0036] Styrene-maleic anhydride copolymer / diatomite nano composite tanning agent, its preparation method specifically comprises the following steps:

[0037](1) Activation of diatomite: 500g of diatomite is added to a ball mill to grind and pulverize, add water to adjust to a diatomite solution with a concentration of 30%, add 45% concentrated sulfuric acid solution while stirr...

Embodiment 2

[0044] Soaking agent and styrene-maleic anhydride copolymer / diatomaceous earth nano compound tanning agent are with embodiment 1;

[0045] An environmentally friendly leather production and processing process specifically includes the following processes:

[0046] S1. Preparation of leather collagen fibers: Mix 20g of soaking agent into 2kg of warm water at 45°C to form a soaking solution. Wash 100g of dry skin or salt skin with running water and put it into the soaking solution. Keep submerged and soak at a constant temperature for 3 hours. The raw hides are peeled, degreased, softened and pickled in sequence to obtain hide collagen fibers;

[0047] S2. Tanning: Add 100g of skin collagen fibers into the tanning cylinder, then add 6g of nano-composite tanning agent and 300g of deionized water at a temperature of 35°C, add 1% formic acid aqueous solution, adjust the pH of the solution in the tanning cylinder to 4.0, and rotate for 10 hours ;

[0048] S3. Finishing: Add sodium...

Embodiment 3

[0050] Soaking agent and styrene-maleic anhydride copolymer / diatomaceous earth nano compound tanning agent are with embodiment 1;

[0051] An environmentally friendly leather production and processing process specifically includes the following processes:

[0052] S1. Preparation of leather collagen fibers: Mix 15g of soaking agent into 1kg of warm water at 40°C to form a soaking solution. Wash 100g of dry or salted skin with running water and put it into the soaking solution. Keep submerged and soak at a constant temperature for 3.5 hours. After the raw hide is peeled, degreased, softened and pickled in turn to obtain the collagen fiber;

[0053] S2. Tanning: Add 100g of skin collagen fibers into the tanning cylinder, then add 6g of nano-composite tanning agent and 250g of deionized water at a temperature of 40°C, add 1% formic acid aqueous solution, adjust the pH of the solution in the tanning cylinder to 3.8, and rotate for 8 hours ;

[0054] S3. Finishing: add sodium bic...

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Abstract

The invention discloses a production and processing process of environment-friendly leather. The production and processing process includes the steps of S1, preparation of leather collagenous fibers,wherein a soaking agent is mixed evenly in warm water at the temperature of 35-45 DEG C, soaking liquid is formed, dry leather or salted leather is washed with running water and then put in the soaking liquid, inundation is kept, constant-temperature soaking is carried out for 3-4 h, soaked raw leather is sequentially shaved, degreased, softened and pickled, and the leather collagenous fibers areobtained; S2, tanning, wherein the leather collagenous fibers are added into a tanning barrel, a nano-composite tanning agent and deionized water at the temperature of 35-45 DEG C are added, 1% of formic acid water solution is added, the pH value of the solution is adjusted to be 3.5-4.0, and rotation is carried out for 7-10 h; and S3, finishing, wherein a sodium bicarbonate solution is added intoa rotary drum, the pH value is adjusted to be 5.0-5.5, rotation is carried out for 20-30 min, dyestuff is added for dyeing treatment, grease added, rotation is carried out for 1 h, and then the environment-friendly leather is obtained after fixing, washing, drum delivering, stacking, vacuum drying and wetting-back and vibrating to be soft are completed. Environmental pollution can be effectivelyreduced in the processing process, and good application prospects are achieved.

Description

technical field [0001] The invention belongs to the technical field of leather manufacturing, and in particular relates to an environment-friendly leather production and processing technology. Background technique [0002] The animal skins used for tanning industry processing are called raw hides, which are traditionally called raw hides. It is a natural polymer material with extremely complex fiber weaving structure. Leather is a fixed and durable substance transformed from animal skin (ie raw hide) through a series of physical and chemical treatments, referred to as leather for short; tanning is actually the transformation of raw hide into leather through a series of physical and chemical treatments After the process of tanning, the leather has the properties of softness, toughness, not easy to deform when exposed to water, not easy to shrink when dry, resistant to heat and humidity, and resistant to chemical agents. It also has special advantages such as air permeability,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C14C1/04C14C1/08C14C3/04C14C3/22C14C9/02C14C11/00D06P3/32
Inventor 林小芳洪丽璇许娟丽
Owner 广西钦州中港皮业有限公司
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