A kind of surface electroplating solution and electroplating process for alloy

An electroplating solution and alloy technology, applied in the field of electroplating, can solve problems such as tediousness, affecting the function of the film layer, and the coating is not environmentally friendly

Active Publication Date: 2021-04-23
杭州云会五金电镀有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the coatings used include hexavalent chromium, copper-tin alloy, silver, gold, etc., but the sewage generated by the electroplating process of hexavalent chromium is difficult to treat, which seriously pollutes the environment and the coating is not environmentally friendly; the white copper-tin coating can only withstand 80-100 °C , exceeding this temperature, the coating will turn black and blue, and cannot maintain the silvery white color; the most commonly used silver plating solution in the silver plating process is the silver plating solution containing cyanide, because cyanide is a highly toxic substance , this silver plating solution containing cyanide will greatly endanger the health of silver plating workers
[0004] Pure gold electroplating film is widely used in the surface treatment of alloy parts due to its good conductivity, weldability, ductility and excellent corrosion resistance. However, in recent years, the price of gold has continued to rise, resulting in gold plating The cost rises, therefore, the improvement of the gold plating process mostly starts from saving the amount of gold used
Among them, the thinning of the gold coating is to compensate for the rising cost of raw materials. However, if the coating is too thin, it is easy to cause pinholes on the coating, which will affect a series of functions of the coating. If the sealing operation is added, the process will be more efficient. Complicated and cumbersome, and the quality of electroplating is poor, and the phenomenon of uneven distribution of electroplating layer often occurs

Method used

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  • A kind of surface electroplating solution and electroplating process for alloy

Examples

Experimental program
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Effect test

Embodiment 1

[0037] The manufacturers, CAS numbers or models of the materials used in this example are as follows: palladium chloride is produced by Suzhou Jinwo Chemical Co., Ltd., and the CAS number is 7647-10-1; potassium chloroplatinate is produced by Suzhou Jinwo Chemical Co., Ltd. Production, CAS No. 16921-30-5; Dimethylthiourea is produced by Shanghai Tebo Chemical Technology Co., Ltd., CAS No. 6972-05-0; Aluminum Potassium Sulfate is produced by Zibo Dazhong Edible Chemical Co., Ltd., CAS No. It is 7784-24-9; citrate is produced by Hefei Sifeng Biotechnology Co., Ltd.; antimony potassium tartrate is produced by Anhui Aibo Biotechnology Co., Ltd., CAS number is 11071-15-1; fatty amine is produced by Zibo Yingzhao Chemical Produced by Science and Technology Co., Ltd.; Polyethylene Glycol is produced by Shanghai Macklin Biochemical Technology Co., Ltd., CAS No. 25322-68-3; Sodium Lauryl Sulfate is produced by Suzhou Dongbai Chemical Co., Ltd., CAS No. 151-21- 3.

[0038] A surface el...

Embodiment 2

[0048] The manufacturers, CAS numbers or models of the substances used in this example are as follows: palladium sulfate is produced by Wuhan Fengzhulin Chemical Technology Co., Ltd., and the CAS number is 13566-03-5; sodium chloroplatinate is produced by Shaanxi Ruike New Materials Co., Ltd. Co., Ltd., CAS No. 19583-77-8; dithioethylene glycol is produced by Shanghai Xinyu Biotechnology Co., Ltd.; magnesium chloride is produced by Shandong Shouguang Jinxing Chemical Co., Ltd., CAS No. 7786-30-3; ammonia Butanetriol is produced by Shanghai Wodian Chemical Co., Ltd., with a CAS number of 77-86-1; trioctyl phosphite is produced by Guangzhou Wengjiang Chemical Reagent Co., Ltd., with a CAS number of 3028-88-4.

[0049] A surface electroplating solution for alloys, the electroplating solution is composed of the following components: palladium sulfate 8g / L, sodium chloroplatinate 5g / L, dithioethylene glycol 12g / L, magnesium chloride 35g / L, ambutene Triol 15g / L, brightener 2g / L, tri...

Embodiment 3

[0059] The manufacturers, CAS numbers or models of the substances used in this example are as follows: palladium acetylacetonate is produced by Shaanxi Ruike New Materials Co., Ltd., and the CAS number is 14024-61-4; chloroplatinic acid is produced by Shanghai Tuosi Chemical Co., Ltd. Produced by the company, CAS number is 16941-12-1; Guanidinoacetic acid is produced by Jinan Nengwei Biotechnology Co., Ltd., CAS number is 352-97-6; Magnesium sulfate is produced by Zibo Hongkun Chemical Co., Ltd., CAS number is 7487- 88-9; 2-amino-2-methyl-1-propanol was produced by Shanghai Merrill Chemical Technology Co., Ltd., CAS No. 124-68-5; trioctyl phosphite was produced by Shanghai Yuanye Biotechnology Co., Ltd. , CAS No. 3028-88-4.

[0060] A surface electroplating solution for alloys, the electroplating solution is composed of the following components: palladium acetylacetonate 10g / L, chloroplatinic acid 7g / L, guanidinoacetic acid 14g / L, magnesium sulfate 40g / L, 2-amino- 2-methyl-1-...

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Abstract

The invention discloses a surface electroplating solution and an electroplating process for alloys. The electroplating solution consists of the following components: soluble palladium salt, soluble platinum salt, complexing agent, conductive salt, buffer, brightener, stabilizer and Anti-pinhole agent, the balance is solvent, and the solvent is deionized water. The electroplating process is: preparation of electroplating solution; pre-plating treatment includes degreasing, grinding, polishing, activation; electroplating; the electroplating solution has good stability and environmental protection; The platinum-palladium plating layer obtained by electroplating with the electroplating solution of the present invention is uniform and compact, has high hardness, good corrosion resistance, good adhesion with alloy parts substrate, bright plating layer, no peeling and bubbling phenomenon of the plating layer; the electroplating process is simple to operate, The conditions are controllable. By controlling the process parameters in the electroplating process and evenly distributing the electroplating anodes around the cathodes, the composition of the coating layer is controllable, the electroplating efficiency is high, the environment is friendly, and it is suitable for promotion.

Description

technical field [0001] The invention relates to the technical field of electroplating, in particular to a surface electroplating solution and an electroplating process for alloys. Background technique [0002] An alloy is a solid product with metallic properties obtained after mixing and melting one metal with another or several metals or nonmetals, and cooling and solidifying. The surface of the alloy is exposed to rainwater, seawater or chemical substances for a long time, and the surface will be relatively easy to corrode. In order to protect the surface of the alloy well, a thin coating is often electroplated on the surface of the alloy. Electroplating is a traditional method for preparing coatings. The properties of coatings can be strictly controlled by controlling parameters and other conditions. The preparation cost is low, and it can adapt to the shape of complex substrates, so it is widely used. [0003] At present, the coatings used include hexavalent chromium, c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D3/56
CPCC25D3/567
Inventor 楼卡高强
Owner 杭州云会五金电镀有限公司
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