Method for preparing geopolymer rubber composite material by utilizing spent FCC (fluid catalytic cracking) catalyst

A technology of geopolymer and waste catalyst, applied in the field of solid waste resource utilization, can solve the problems of high brittleness, environmental pollution, energy waste, etc., and achieve the effect of improving toughness and strength

Inactive Publication Date: 2019-02-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent (such as CN104495924A, CN102586606) has introduced the method for reclaiming metal from FCC waste catalyst, yet the heavy metal content such as nickel, vanadium of FCC waste catalyst is low, as nickel element content is generally at 0.2-1.5%, therefore, extract economic value Low, and a large amount of acid and alkali solution is consumed in the recycling process, resulting in high cost and secondary pollution
However, geopolymers have problems such as poo

Method used

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  • Method for preparing geopolymer rubber composite material by utilizing spent FCC (fluid catalytic cracking) catalyst

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0036] Example 1:

[0037] The geopolymer rubber composite material is prepared from FCC waste catalyst. The mass ratio of ultrafine FCC waste catalyst powder, ultrafine fly ash, waste rubber powder, and sodium silicate is 40:20:15:30; among them, ultrafine FCC The waste catalyst powder is made by FCC waste catalyst ball milling, and its specific surface area is 325m 2 / kg, 28-day activity index 95%; ultra-fine fly ash is made by ball milling of fly ash, and its specific surface area is 550m 2 / kg, 28-day activity index 98%; waste rubber powder is mechanically processed and crushed from waste rubber tires, with a particle size of 30 mesh; add appropriate amount of water to the above mixture, and prepare a geopolymer rubber composite after stirring, molding and curing material.

[0038] The leaching concentration of nickel in the prepared geopolymer rubber composite material was reduced from 9.6 mg / L to 1.5 mg / L, the leaching toxicity of V element was reduced from 18.2 mg / L to 3.2 m...

Example Embodiment

[0039] Example 2:

[0040] The geopolymer rubber composite material is prepared from FCC waste catalyst. The mass ratio of ultrafine FCC waste catalyst powder, ultrafine fly ash, waste rubber powder, and sodium hydroxide is 60:10:10:20; among them, ultrafine FCC The waste catalyst powder is made by FCC waste catalyst ball milling, and its specific surface area is 425m 2 / kg, 28-day activity index 98%; ultra-fine fly ash is made by ball milling of fly ash, and its specific surface area is 600m 2 / kg, 28-day activity index 98%; waste rubber powder is mechanically processed and crushed from waste rubber tires, with a particle size of 40 mesh; add water with a mass of 0.4 of the total mass of the mixture to the above mixture, and stir, shape, The geopolymer rubber composite material is prepared by curing.

[0041] The leaching concentration of nickel in the prepared geopolymer rubber composite material is reduced from 9.6mg / L to 0.98mg / L, the leaching toxicity of V element is reduced f...

Example Embodiment

[0042] Example 3:

[0043] The geopolymer rubber composite material is prepared from FCC waste catalyst. The mass ratio of ultrafine FCC waste catalyst powder, ultrafine fly ash, waste rubber powder, and water glass is 50:15:10:30; among them, ultrafine FCC waste The catalyst powder is made by ball milling of spent FCC catalyst, with a specific surface area of ​​450m 2 / kg, 28-day activity index is 90%; ultra-fine fly ash is made by ball milling of fly ash, and its specific surface area is 600m 2 / kg, 28-day activity index 90%; waste rubber powder is mechanically processed and crushed from waste rubber tires, with a particle size of 50 mesh; the chemical formula of water glass is R 2 O·nSiO 2 , Where R is Na or K, and n is 0.8-2.0; adding water with a mass of 0.45 of the total mass of the above mixture to the above mixture, and preparing the geopolymer rubber composite material through stirring, molding and curing.

[0044] The leaching concentration of nickel in the prepared geopol...

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Abstract

The invention discloses a method for preparing a geopolymer rubber composite material by utilizing a spent FCC (fluid catalytic cracking) catalyst. According to the method, spent FCC catalyst powder and fly ash serve as raw materials, an alkali activator is added to stimulate the activity of the spent FCC catalyst powder and the fly ash, waste rubber powder serves as filler, a proper amount of water is added, and stirring, forming and curing are carried out so as to prepare the geopolymer rubber composite material. The prepared geopolymer rubber composite material has the advantages that toxicand harmful substances such as heavy metal ions can be efficiently cured, meanwhile, toughening materials such as waste rubber are added, so that the disposal amount of the spent FCC catalyst is increased, and the toughness and strength of geopolymer are improved. The method has the advantages that the spent FCC catalyst which pollutes the environment can be safely disposed, the waste rubber is fully utilized, and in addition, the toxic and harmful spent FCC catalyst and the waste rubber which pollutes the environment are turned into wealth.

Description

technical field [0001] The invention relates to the field of resource utilization of solid waste, in particular to a method for preparing geopolymer rubber composite materials by utilizing FCC waste catalysts. Background technique [0002] In the catalytic cracking unit, because the catalyst is contaminated by heavy metals, the catalytic activity of the catalyst decreases rapidly and the reaction selectivity deteriorates. It is necessary to periodically discharge part of the balance agent and add new agent to ensure the activity and selectivity of the catalyst in the device. The resulting balancer is called catalytic cracking spent catalyst (hereinafter referred to as FCC spent catalyst). FCC waste catalysts have low catalytic activity and contain a certain amount of heavy metals, which are highly polluting. Unregulated random disposal will pose a serious threat to the human living environment. [0003] At present, research institutions at home and abroad mainly conduct res...

Claims

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Application Information

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IPC IPC(8): C04B28/00C04B18/04C04B18/22
CPCC04B18/0481C04B18/22C04B28/006C04B2201/50C04B18/08C04B12/04C04B22/062Y02P40/10Y02W30/91
Inventor 房师平张宏哲刘政伟张志远牟桂芹郭磊
Owner CHINA PETROLEUM & CHEM CORP
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