Benzoate-based burning rate catalyst containing dinuclear ferrocene group and preparation method of benzoate-based burning rate catalyst
A burning rate catalyst, ferrocene-based technology, applied in chemical instruments and methods, metallocene, organic chemistry, etc., can solve problems such as complex synthesis process, achieve simple operation, good thermal stability, and improve thermal stability. Effect
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Embodiment 1
[0025] Preparation of bis-(ferrocenylmethyl-1,2,3-triazolylmethyl) terephthalate with the following structural formula
[0026]
[0027] Add 0.2230g (1mmol) di-2-ynylpropyl terephthalate and 0.4931g (2.05mmol) azidomethylferrocene to a 250mL round bottom flask, 2 Add 30mL of methanol under the atmosphere, stir evenly, then add dropwise 15mL of an aqueous solution containing 0.077g (0.3mmol) copper sulfate pentahydrate and 15mL of an aqueous solution containing 0.0604g (0.3mmol) of sodium ascorbate, stir at room temperature for 24h, and filter to obtain a crude product. The crude product was separated by column chromatography to obtain bis-(ferrocenylmethyl-1,2,3-triazolylmethyl) terephthalate, the yield was 82%, and the structural characterization data was: FT-IR (cm -1 ):3431m, 3155m, 2955w, 1715vs, 1626m, 1383m, 1335m, 1265vs, 1106vs, 1044m, 933m, 801s, 718m, 490s; 1 H NMR (400MHz, CDCl 3 ):δ8.04(s,4H),7.59(s,2H),5.43(s,4H),5.30(s,4H),4.29(s,4H),4.23(s,4H),4.18(vs, 10...
Embodiment 2
[0029] Preparation of bis-(ferrocenylmethyl-123-triazolylmethyl) phthalate of following structural formula
[0030]
[0031]In this embodiment, the di-2-ynylpropyl terephthalate in Example 1 is replaced with equimolar di-2-ynylpropyl phthalate, and the other steps are the same as in Example 1. Bis-(ferrocenylmethyl-1,2,3-triazolylmethyl) formate, the yield is 79%, and the structural characterization data is: FT-IR (cm -1 ):3427m, 3094m, 2955w, 1723vs, 1626w, 1445m, 1383m, 1272vs, 1120vs, 1058s, 940m, 822s, 753m, 635w, 490s; 1 H NMR (400MHz, CDCl 3 ): δ7.68(s,2H),7.62(s,2H),7.51(s,2H),5.30(s,8H),4.31(s,4H),4.19(s,14H).
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