A fluorescent immunochromatographic test strip prepared with aggregation-induced luminescent fluorescent microspheres as a beacon carrier
A technology of aggregation-induced luminescence and fluorescence immunochromatography, which is applied in the fields of medical inspection and food safety detection, can solve the problems of preparing fluorescent microspheres from materials such as tetramethyl styrene-acid, and achieve good fluorescence characteristics and fluorescence signals. Strong, high detection sensitivity effect
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Embodiment 1
[0036] Example 1: Preparation of aggregation-induced luminescent fluorescent microspheres (preparation of TCBPE dyes)
[0037] 1. Configure the dye prefabricated solution: weigh TCBPE (TCBPE synthesis method is from the literature RigidifyingFluorescent Linkers by Metal-Organic Framework Formation for FluorescenceBlue Shift and Quantum YieldEnhancement Journal of the American Chemical Society 2014 136(23), reported in 8269-8276), PMMA and PMAO, dissolved in chloroform, so that the final concentrations of TCBPE, PMMA, and PMAO dissolved in chloroform were 30, 50, and 25 mg / mL, respectively;
[0038] 2. Preparation of microemulsion: suck 2400 μL of the above pre-prepared solution, disperse it in 12 mL of 0.25% SDS solution, under ice bath conditions, sonicate for 3 min with a ultrasonic crusher, and the emulsification power is 600 W;
[0039] 3. Solidify into spheres: put the above emulsion in a rotary evaporation container, rotate until there is no chloroform, centrifuge the co...
Embodiment 2
[0040] Example 2: Preparation of a competitive immunochromatographic test strip for the detection of 25-hydroxyvitamin D (25-OH-VD) prepared by using aggregation-induced luminescent fluorescent microspheres as beacon carriers
[0041] 1. Preparation process of immunochromatographic test strips
[0042] 1. Preparation of nitrocellulose membrane;
[0043] (1) Preparation of 25-OH-VD artificial antigen (25-OH-VD-OVA):
[0044] The coupling method is mixed acid anhydride method, the coupling protein is ovalbumin (OVA), and the coupling ratio is 1:80. After coupling, dialysis and purification are performed to obtain 25-OH-VD-OVA.
[0045] (2) Preparation of test line and quality control line:
[0046] Coating of 25-OH-VD-OVA conjugate and anti-mouse antibody onto nitrocellulose membrane: Dilute the concentration of 25-OH-VD-OVA conjugate with 0.01 M PBS (phosphate buffered saline) pH 7.5 The concentration of the diluted anti-mouse antibody was 1 mg / mL, the obtained solution was ...
Embodiment 3
[0061] Example 3: Preparation of a competitive immunochromatographic test strip for the detection of zearalenone using aggregation-induced luminescent fluorescent microspheres as beacon carriers
[0062] 1. Preparation process of immunochromatographic test strips
[0063] 1. Preparation of nitrocellulose membrane;
[0064] (1) Preparation of ZEN artificial antigen (ZEN-BSA):
[0065] The coupling method is mixed acid anhydride method, the coupling protein is bovine serum albumin (BSA), and the coupling ratio is 1:100. After coupling, dialysis and purification are performed to obtain ZEN-BSA.
[0066] (2) Preparation of test line and quality control line:
[0067] Coating of ZEN-BSA conjugate and anti-mouse antibody onto nitrocellulose membrane: The ZEN-BSA conjugate was diluted to a concentration of 6 mg / mL with 0.01 M PBS (phosphate buffered saline) pH 7.0, and the resulting solution was Spray on the membrane as the detection line; the concentration of the diluted anti-mou...
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