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Photosensitive self-crosslinked EPDM waterproofing coiled material and preparation method thereof

A technology of EPDM and waterproof membrane, applied in the field of waterproof materials, can solve the problems of inability to realize hot air welding on the body, limited product application scope, lack of self-crosslinking ability, etc., so as to improve mechanical strength and chemical corrosion resistance. , Reduce equipment investment, good physical performance

Active Publication Date: 2019-05-07
SICHUAN WEIDUN JIANGXIN CONSTR CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This invention adopts cold feed extruder to extrude, and vulcanization tank vulcanizes, which increases equipment investment. At the same time, it does not have self-crosslinking ability, and cannot realize hot air welding of the body. It needs to increase welding rods, which increases the difficulty of construction and limits the scope of product application.

Method used

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  • Photosensitive self-crosslinked EPDM waterproofing coiled material and preparation method thereof
  • Photosensitive self-crosslinked EPDM waterproofing coiled material and preparation method thereof
  • Photosensitive self-crosslinked EPDM waterproofing coiled material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0030] The raw materials used in this embodiment and the usage amount of each raw material are as recorded in Table 1. Composition by mass ratio of 1:1.2; the inorganic fillers used are wet deposition clay and activated calcium carbonate, wherein wet deposition clay and activated calcium carbonate are configured in a mass ratio of 1:1;

[0031] The production process of the waterproof roll:

[0032] S1 rubber compounding: add EPDM rubber, stearic acid, carbon black, inorganic filler, compatibilizer and softener to the internal mixer in sequence according to the formula ratio, set the temperature of the internal mixer to 132°C, and perform internal mixing The time is 10 minutes, and after the specified time is reached, the evenly mixed rubber is discharged;

[0033] S2 Rubber material opening: put the evenly mixed rubber material into the double-roll mill, set the temperature of the rolling rolls to 80°C, and add zinc oxide, magnesium oxide, phthalic anhydride, sulfur, TMTD, 4...

Embodiment 2

[0037] The raw materials used in this embodiment and the usage amount of each raw material are as recorded in Table 1. The photoinitiator is composed of cationic initiator triarylsulfonium salt and alkylsulfonium salt, free radical type photoinitiator benzoin isopropyl ether and Composed of diphenyl ethyl ketone, wherein the mass ratio of triarylsulfonium salt, alkylsulfonium salt, benzoin isopropyl ether and diphenyl ethyl ketone is 1:1:1.2:1.2; the inorganic filler used is montmorillonite;

[0038] The production process of the waterproof roll:

[0039] S1 Compound mixing: Add EPDM rubber, stearic acid, carbon black, inorganic filler, compatibilizer and softener to the internal mixer in sequence according to the formula ratio. The temperature of the internal mixer is 142°C, and the internal mixing time is 8 minutes. , after reaching the specified time, discharge the evenly mixed rubber material;

[0040] S2 Rubber material opening: put the evenly mixed rubber material into th...

Embodiment 3

[0044] The raw materials used in this embodiment and the usage amount of each raw material are as recorded in Table 1. Ratio 1: 1.2 composition; the inorganic filler used is talc powder, and its particle size range is 200-800nm;

[0045] The production process of the waterproof roll:

[0046] S1 rubber compounding: add EPDM rubber, stearic acid, carbon black, inorganic filler, compatibilizer and softener to the internal mixer in sequence according to the formula ratio, the temperature of the internal mixer is 140°C, and the internal mixing time is 10 minutes , after reaching the specified time, discharge the evenly mixed rubber material;

[0047] S2 Rubber material opening: put the evenly mixed rubber material into the double-roll mill, set the temperature of the rolling roll to 90°C, and add zinc oxide, magnesium oxide, phthalic anhydride, sulfur, TMTD, 4-4 in sequence '-dimorpholine disulfide, in the mixing process, thin pass 5 times, pack triangle bag 4 times, and pull ou...

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Abstract

The invention relates to the field of waterproof materials, in particular to a photosensitive self-crosslinked EPDM waterproofing coiled material and a preparation method thereof. The photosensitive self-crosslinked EPDM waterproofing coiled material comprises the following raw material components: in parts by weight, 100 parts of ethylene propylene diene monomer, 30-50 parts of polyolefin elastomer, 1.8-2.6 parts of sulphur, 0.8-1.5 parts of zinc oxide, 0.8-1.5 parts of magnesium oxide, 1.2-1.6 parts of stearic acid, 1.0-2.0 parts of tetramethylthiuram disulfide, 0.4-1.0 part of 4-4'- dimorpholine disulfide, 1.4-2.0 parts of dicumyl peroxide, 0.6-1.0 part of phthalic anhydride, 60-85 parts of carbon black, 40-65 parts of inorganic filler, 10-15 parts of a compatibilizer, 8-18 parts of a softener and 1.8-3.6 parts of a photoinitiator. The preparation method has simple equipment and low investment; gradual crosslingking of the waterproof coiled material can be achieved in an applicationenvironment, the mechanical properties of the coiled material is increased with increase of the external exposure time, the service life is long, and the physical properties of the product are good;and the coiled material can be welded through hot air, aging resistance is achieved, and resistance to stress cracking is higher.

Description

technical field [0001] The invention belongs to the field of waterproof materials, and particularly provides a photosensitive self-crosslinking EPDM waterproof membrane and a preparation method thereof. Background technique [0002] EPDM is a copolymer of ethylene, propylene and a small amount of non-conjugated dienes. It is a kind of ethylene-propylene rubber, expressed in EPDM, because its main chain is composed of chemically stable saturated hydrocarbons, only in the side chain It contains unsaturated double bonds, so it has excellent aging resistance such as ozone resistance, heat resistance, and weather resistance. It can be widely used in automotive parts, waterproof materials for construction, wire and cable sheaths, heat-resistant hoses, tapes, automotive seals, etc. . [0003] In the field of building waterproof materials, EPDM waterproofing membranes are widely used in the waterproofing and anti-seepage of various industrial and civil buildings and structures, the...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/08C08L91/06C08K13/02C08K3/22C08K5/12C08K3/04C08J3/24C08J5/18
Inventor 郑贤方张宇金永峰刘勇丁海涛袁志涛夏亮亮郑伦刘亚妮徐伟王用才戴鸿基
Owner SICHUAN WEIDUN JIANGXIN CONSTR CO LTD