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A kind of wear-resistant milk protein fiber and its fabric preparation method and application

A milk protein fiber and casein technology, applied in the field of textiles, can solve the problems of local skin wrinkles, difficult to penetrate the adhesive tape, poor air permeability of the adhesive tape, etc. Effect

Active Publication Date: 2022-04-01
湖州草本源新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the current conventional band-aid has poor air permeability of the adhesive tape, and the water vapor and sweat normally secreted by the human body cannot penetrate the adhesive tape, so it has a soaking effect on the local skin, and the specific performance is that the local skin is wrinkled.
At present, hydrogel dressings have attracted people's attention because they can automatically adjust the humidity of the wound, have the ability to absorb a small amount of exudate, and have the advantages of not sticking to the wound. However, hydrogel dressings have the disadvantage of being easy to erase
[0004] Milk protein fiber is white and is a composite fiber of regenerated protein. It is a new type of textile fiber made from casein separated from milk and polymer compound acrylonitrile through graft copolymerization to form polymer, and then wet spinning process. , it not only has a silky soft luster, soft, slippery and high strength, but also has excellent anti-mildew performance and natural antibacterial function. Using milk protein fiber to prepare wound dressings can not only overcome the existence of hydrogel dressings, which are easy to rub In addition to the disadvantages, it has a certain air permeability, but the milk white fiber has longitudinal hidden stripes, resulting in a high friction coefficient, poor wear resistance, and easy to break. It is easy to break when used to prepare ultra-thin band-aids.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • A kind of wear-resistant milk protein fiber and its fabric preparation method and application
  • A kind of wear-resistant milk protein fiber and its fabric preparation method and application
  • A kind of wear-resistant milk protein fiber and its fabric preparation method and application

Examples

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Effect test

Embodiment 1

[0037] A preparation method of wear-resistant milk protein fiber, comprising the steps of:

[0038] a. Add 20kg of polyacrylonitrile fibers into ammonia water and stir for 16min at a stirring temperature of 80°C, filter, wash until neutral, and dry, then add 2kg of bromoacetyl bromide, 3kg of phosphorus oxychloride, and 5kg of phenylphosphonic dichloride, Raise the temperature to 120°C, keep it warm for 30 minutes, wash until neutral, and dry to obtain acid halide polyacrylonitrile;

[0039] b. Add 2kg of casein and 0.2kg of acid halide polyacrylonitrile into 4kg of water, grind for 14min, the grinding temperature is 50°C, the grinding pressure is 0.16MPa, add water until the water content is 65wt%; adjust the pH to 8.5-9.5 under nitrogen protection , stirred for 8 minutes, and the stirring temperature was 80°C; then, 0.18kg of ethylene glycol diglycidyl ether was added under oxygenated state, ultrasonically treated for 4 minutes, then adjusted to 120°C and stirred for 10 minu...

Embodiment 2

[0041] A preparation method of wear-resistant milk protein fiber, comprising the steps of:

[0042] a. Add 30kg of polyacrylonitrile fibers to 4mol / L sodium carbonate aqueous solution and stir for 10min at a stirring temperature of 90°C, filter, wash until neutral, dry, then add 2kg of propionyl bromide, heat up to 128°C, and keep warm for 20min , washed to neutrality, and dried to obtain acid halide polyacrylonitrile;

[0043]b. Add 10kg of casein and 0.1kg of acid halide polyacrylonitrile into 10kg of water, grind for 10min, the grinding temperature is 60°C, the grinding pressure is 0.12MPa, add water until the water content is 75wt%; adjust the pH to 8.5-9.5 under nitrogen protection , stirred for 4 minutes, and the stirring temperature was 90°C; then 0.1kg of ethylene glycol diglycidyl ether was added under oxygenated state, ultrasonically treated for 12 minutes, then adjusted to 110°C and stirred for 18 minutes, filtered, washed, and dried at 40°C to constant weight, Wea...

Embodiment 3

[0045] A preparation method of wear-resistant milk protein fiber, comprising the steps of:

[0046] a. Add 21kg of polyacrylonitrile fibers into triethylamine and stir for 15min at a stirring temperature of 81°C, filter, wash until neutral, and dry, then add 2kg of thionyl chloride, 3kg of oxalyl chloride, 1kg of chloroacetyl chloride, 3kg of 2- Bromoisobutyryl bromide, heat up to 121°C, keep warm for 29 minutes, wash until neutral, and dry to obtain acid halide polyacrylonitrile;

[0047] b. Add 3kg of casein and 0.19kg of acid halide polyacrylonitrile into 5kg of water, grind for 13.5min, the grinding temperature is 51°C, the grinding pressure is 0.155MPa, add water until the water content is 66wt%; adjust the pH to 8.5- 9.5, stirring for 7 minutes, the stirring temperature is 81°C; then add 0.17kg of ethylene glycol diglycidyl ether under oxygenated state, ultrasonic treatment for 5 minutes, then adjust the temperature to 119°C and stir for 12 minutes, filter, wash, and dry...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a wear-resistant milk protein fiber, in which casein is grafted on the surface of the polyacrylonitrile fiber, and the casein covers the polyacrylonitrile fiber. The invention discloses a preparation method of the wear-resistant milk protein fiber, which comprises the following steps: adding polyacrylonitrile fiber to an alkaline solution, stirring, filtering, washing until neutral, drying, adding acid halide, heating, keeping warm, washing until Neutral, dry to obtain acid halide polyacrylonitrile; add casein and acid halide polyacrylonitrile into water, grind, add water; adjust pH to 8.5‑9.5 under nitrogen protection and stir; then add ethylene glycol dihydrate under oxygenation state Glycerin ether, ultrasonic treatment, followed by adjusting temperature and stirring, filtering, washing, drying to constant weight, and wet spinning to obtain wear-resistant milk protein fiber. The invention discloses a wear-resistant milk protein fiber fabric. The invention discloses the application of the wear-resistant milk protein fiber fabric as a wound dressing.

Description

technical field [0001] The invention relates to the technical field of textiles, in particular to a wear-resistant milk protein fiber and a preparation method thereof, a wear-resistant milk protein fiber fabric, a preparation method and an application thereof. Background technique [0002] Band-aid is the most commonly used surgical drug in people's life. Band-aid, also known as "hemostatic plaster", has the functions of hemostasis and skin protection. It is composed of a long adhesive plaster with a small piece of gauze soaked in medicine attached in the middle. An excellent band-aid should have the advantages of compressing hemostasis, protecting the wound, preventing infection, and promoting healing, and has good mechanical properties. It can be applied to wounds of different shapes to protect the wound from mechanical damage. It should also have good anti-infection ability to reduce wound wounds. Invasion of microorganisms, reducing inflammatory response, non-cytotoxic ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/08D01F8/02D03D15/292D03D13/00A41B17/00A61F13/00A61F13/02D03D15/233D03D15/283
Inventor 董波严春兰
Owner 湖州草本源新材料有限公司
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