High-water-stability inorganic-organic multifunctional hybrid material with blue-green light emission, antibiosis and photoelectric response and preparation method thereof
A photoelectric response, hybrid material technology, applied in luminescent materials, organic chemistry, organic chemistry methods, etc., can solve the problems of loss of performance, high pollution, high toxicity, etc., and achieve mild reaction, high product purity, and good inhibition rate. Effect
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[0029] A highly water-stable inorganic-organic functional hybrid material with blue-green light emission, antibacterial and photoelectric response, the molecular formula is C 80 h 73 Ag 7 Br 11 NOP 4 , whose structure contains the organic quaternary phosphonium salt propane-1,3-diylbistriphenylphosphonium bromide [(1,3-DBTPP) 2+ ] and one-dimensional silver bromide polyanion [(Ag 7 Br 11 )] n 4n- , there is a hydrogen bond between them.
[0030] The multifunctional hybrid material exhibits blue-green light emission (λ ex =513nm), good inhibitory rate against Streptococcus mutans (0ug / ul concentration, showing nearly 100% inhibitory rate), photoelectric responsiveness (photocurrent 0.15uA), and good water stability, soaked in water for 5 Days later, all diffraction peaks remained unchanged.
[0031] The synthetic method comprises the steps:
[0032] Dissolve 1,3-DBTPP·2Br (0.0710g, 0.1mmol) and AgBr (0.0188g, 0.1mmol) in 20mL of acetonitrile, stir at 45°C for 3 hours...
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