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Fiber-modified soybean protein-based adhesive for wood-based panels and preparation method thereof

A soybean protein and modifier technology, applied in the preparation of protein adhesives, animal glue or gelatin, adhesives, etc., can solve the problems of poor dispersibility and low reactivity, and achieve good water resistance, excellent fiber dispersion effect, close-knit effect

Active Publication Date: 2021-01-26
BEIJING FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, when natural fibers are used in soybean protein-based adhesives, there are often problems such as poor dispersibility and low reactivity.

Method used

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  • Fiber-modified soybean protein-based adhesive for wood-based panels and preparation method thereof
  • Fiber-modified soybean protein-based adhesive for wood-based panels and preparation method thereof
  • Fiber-modified soybean protein-based adhesive for wood-based panels and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A preparation of soybean protein-based adhesive, comprising:

[0035] (1) Prepare materials according to the following weight ratio (Kg):

[0036]

[0037] (2) Disperse 2Kg of kenaf fibers into a solution containing 0.2Kg of alkali lignin, disperse the kenaf fibers evenly, stir, rinse and dry at a rotating speed of 900 rpm, and obtain dispersible, highly reactive Kenaf fiber.

[0038] (3) Disperse 5Kg of sodium hydroxide and 10Kg of urea in water, and stir evenly at a rotating speed of 900 rpm to obtain a mixed solution of sodium hydroxide and urea.

[0039] (4) Disperse the modified kenaf fibers into a mixed solution of sodium hydroxide and urea, and stir evenly at a rotating speed of 900 rpm to obtain a mixed solution of sodium hydroxide and urea containing kenaf fibers.

[0040] (5) Add the mixed solution of sodium hydroxide and urea containing kenaf fiber to 25Kg soybean meal under the stirring condition of rotating speed 900 rev / min, obtain the soybean meal de...

Embodiment 2

[0046] A preparation of soybean protein-based adhesive, comprising:

[0047] (1) Prepare materials according to the following weight ratio (Kg):

[0048]

[0049](2) Disperse 3Kg of silk fibers into a solution containing 0.3Kg of alkali lignin to disperse the silk fibers evenly. After stirring, rinsing and drying at a speed of 1000 rpm, silk fibers with excellent dispersibility and high reactivity are obtained .

[0050] (3) Disperse 10Kg of potassium hydroxide and 15Kg of urea in water, and stir evenly at a rotating speed of 1000 rpm to obtain a mixed solution of potassium hydroxide and urea.

[0051] (4) Disperse the modified silk fibers into a mixed solution of potassium hydroxide and urea, and stir evenly at a rotating speed of 1000 rpm to obtain a mixed solution of potassium hydroxide and urea containing silk fibers.

[0052] (5) Add the mixed solution of potassium hydroxide and urea containing silk fiber to 20Kg soybean meal under the stirring condition of rotating ...

Embodiment 3

[0058] A preparation of soybean protein-based adhesive, comprising:

[0059] (1) Prepare materials according to the following weight ratio (Kg):

[0060]

[0061] (2) Disperse 2.5Kg of wood fibers into a solution containing 0.3Kg of tannic acid to disperse the wood fibers evenly. After stirring, rinsing and drying at a rotating speed of 1100 rpm, wood fibers with excellent dispersibility and high reactivity are obtained. fiber.

[0062] (3) Disperse 8Kg of calcium hydroxide and 15Kg of urea in water, and stir evenly at a rotating speed of 1100 rpm to obtain a mixed solution of calcium hydroxide and urea.

[0063] (4) Disperse the modified wood fiber into a mixed solution of calcium hydroxide and urea, and stir evenly at a rotating speed of 1000 rpm to obtain a mixed solution of calcium hydroxide and urea containing wood fiber.

[0064] (5) Add the mixed solution of calcium hydroxide containing wood fiber and urea to 20Kg soybean meal under the stirring condition of rotati...

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Abstract

The invention relates to a fiber modified soybean protein-based adhesive for an artificial board and a preparation method of the fiber modified soybean protein-based adhesive. The fiber modified soybean protein-based adhesive is prepared from raw materials comprising a soybean protein base material, natural fibers, a fiber surface modifier, urea, alkali, a cross-linking agent and water; the fibersurface modifier comprises alkali lignin and / or tannic acid; and the mass ratio of the fiber surface modifier to the soybean protein base material to the natural fibers is (0.1-0.5): (15-60): (1-4). By selecting and adding a specific modifier, the reaction activity of the natural fibers is enhanced, so that the modification effect of the modifier on the soybean protein base material is fully exerted, meanwhile, the dispersity of the modifier in a preparation system is improved, and the improvement capability of the modifier is further improved; and the finally obtained adhesive has higher bonding strength, better water resistance and no formaldehyde release. The solid content of the soybean protein-based adhesive is 25-45%wt, the viscosity is 200-2000 mPa.s, the bonding strength is up to 1.54 MPa, and the activity period is 15-30 days.

Description

technical field [0001] The invention relates to an adhesive and a preparation method, in particular to a soybean protein-based adhesive for wood-based panels and a preparation method thereof. Background technique [0002] my country is the world's largest producer and consumer of wood-based panels. In 2017, my country's wood-based panel production accounted for 50%-60% of the world's total wood-based panel production, including 171.95 million cubic meters of plywood, 62.97 million cubic meters of fiberboard, and 27.78 million cubic meters of particleboard. Other wood-based panels are 32.16 million cubic meters (blockboard accounts for 53%). The continuous and rapid development of the wood processing industry has gradually increased the amount of three-aldehyde adhesives (urea-formaldehyde resin, phenolic resin and melamine resin), accounting for more than 95% of the amount of wood adhesives, resulting in environmental pollution and resource shortages. The problem is also get...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J189/00C09J11/08C09J11/06C09J11/04
CPCC08K2003/2206C09J11/04C09J11/06C09J11/08C09J189/00C08L89/00C08L97/02C08L1/02C08K5/21C08K3/22
Inventor 张世锋庞惠文李建章
Owner BEIJING FORESTRY UNIVERSITY
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