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Rubber hose inner rubber layer for ethanol resistant gasoline oiling machine and preparation method of rubber hose inner rubber layer

A technology for a rubber hose and a fuel dispenser, which is applied in the field of rubber hose preparation, can solve the problems of poor processing technology of chloroether rubber, high price of chloroether rubber, and high requirements for flame retardancy, and achieves shortening of mixing time and compatibility. Good, improved calendering and extrusion efficiency

Pending Publication Date: 2019-10-25
漯河市久隆液压科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation method is simple, the operation is easy, and the equipment investment is small; the filling reinforcing agent is fast pressing furnace black, high wear-resistant furnace black, semi-reinforcing furnace black and medium particle thermal cracking carbon black, white carbon black, clay, One or two or more of calcium carbonate are used in combination; the vulcanization system is accelerator NA-22, tetramethylthiuram disulfide TMTD, sulfenamide, 2,4,6-trithiol thiotriazine One or more of them are used in combination; the protection system is one or more of anti-aging agent MBI, anti-aging agent RD, anti-aging agent D, and anti-aging agent NBC; the activator is zinc oxide, trilead tetraoxide, and magnesium oxide One or two or more of them are used in combination; the plasticizer is one or two of dibutyl phthalate DBP, dioctyl phthalate DOP, dioctyl sebacate DOS, tricresyl phosphate TCP More than one kind are used in combination; the epichlorohydrin rubber is a ternary copolymerized polychloroether rubber, which is expensive and cannot be popularized on fuel dispenser pipes; the epichlorohydrin rubber molecules contain a large amount of oxygen atoms, which are flammable and easy to burn. High requirements for flame retardancy; epichlorohydrin rubber has poor processing technology and is easy to scorch, so it is suitable for molded products, while rubber hoses are extruded products. Therefore, the products obtained by the technical solution disclosed in this patent application cannot be used for fuel dispensers Inner rubber layer with rubber hose

Method used

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  • Rubber hose inner rubber layer for ethanol resistant gasoline oiling machine and preparation method of rubber hose inner rubber layer
  • Rubber hose inner rubber layer for ethanol resistant gasoline oiling machine and preparation method of rubber hose inner rubber layer
  • Rubber hose inner rubber layer for ethanol resistant gasoline oiling machine and preparation method of rubber hose inner rubber layer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] An inner rubber layer of a rubber hose for an ethanol-resistant gasoline fuel dispenser is made of the following raw materials in parts by weight: 65Kg of nitrile rubber, 26Kg of chlorosulfonated polyethylene rubber, 8Kg of leveling agent, 3Kg of zinc oxide, and stearic acid 1.5Kg, antioxidant 2Kg, carbon black 9.2Kg, white carbon black 8Kg, silica powder 17Kg, light calcium carbonate 10Kg, dioctyl ester 7Kg, sulfur 1.2Kg, accelerator 0.7Kg, vulcanization accelerator 0.9Kg, viscose Mixture 5.5Kg.

[0053] The preparation method comprises the following steps,

[0054] Step 1, masticating, add nitrile rubber, chlorosulfonated polyethylene rubber, and leveling agent in sequence to the internal mixer, control the speed of the internal mixer to 33r / min, and discharge the glue when the temperature of the internal mixer rises to 100°C, and obtain Mixed glue;

[0055] Step 2, thin pass, the temperature of the front roller and the rear roller of the open mill is raised to 58 °...

Embodiment 2

[0063] An inner rubber layer of a rubber hose for an ethanol-resistant gasoline fuel dispenser is made of the following raw materials in parts by weight: nitrile rubber 72Kg, chlorosulfonated polyethylene rubber 31Kg, leveling agent 11Kg, zinc oxide 3.5Kg, stearin Acid 1.2Kg, antioxidant 3.1Kg, carbon black 8.9Kg, white carbon black 10Kg, silica powder 18Kg, light calcium carbonate 11Kg, dioctyl fat 9Kg, sulfur 1.5Kg, accelerator 0.6Kg, vulcanization accelerator 0.8Kg , Adhesive 6.2Kg.

[0064] The preparation method comprises the following steps,

[0065] Step 1, masticating, add nitrile rubber, chlorosulfonated polyethylene rubber, and leveling agent in sequence to the internal mixer, control the speed of the internal mixer to 33r / min, and discharge the glue when the temperature of the internal mixer rises to 100°C, and obtain Mixed glue;

[0066] Step 2, thin pass, the temperature of the front roller and the rear roller of the open mill is raised to 56°C, the gap between ...

Embodiment 3

[0073] An inner rubber layer of a rubber hose for an ethanol-resistant gasoline fuel dispenser is made of the following raw materials in parts by weight: nitrile rubber 75Kg, chlorosulfonated polyethylene rubber 33Kg, leveling agent 12Kg, zinc oxide 3.8Kg, stearin Acid 1.5Kg, antioxidant 3.6Kg, carbon black 8Kg, white carbon black 11Kg, silica powder 23Kg, light calcium carbonate 12.5Kg, dioctyl fat 10Kg, sulfur 1.3Kg, accelerator 0.8Kg, vulcanization accelerator 1.0 Kg , Adhesive 6.8Kg.

[0074] The preparation method comprises the following steps,

[0075] Step 1, masticating, add nitrile rubber, chlorosulfonated polyethylene rubber, and leveling agent in sequence to the internal mixer, control the speed of the internal mixer to 33r / min, and discharge the glue when the temperature of the internal mixer rises to 100°C, and obtain Mixed glue;

[0076] Step 2, thin pass, the temperature of the front roller and the rear roller of the open mill is raised to 58 ° C, the gap betw...

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Abstract

The invention relates to the field of rubber hose preparation, in particular to a rubber hose inner rubber layer for ethanol resistant gasoline oiling machine and a preparation method of the rubber hose inner rubber layer. The rubber hose inner rubber layer is prepared from the following raw materials in parts by weight: 60-76 parts of nitrile rubber, 24-35 parts of chlorosulfonated polyethylene rubber, 8-13 parts of a homogenizer, 2.7-4.2 parts of zinc oxide, 1.1-1.8 parts of stearic acid, and 2-4 parts of an anti-aging agent, 8.9-10 parts of carbon black, 7-12 parts of white carbon black, 17-25 parts of silica micro powder, 8-13 parts of light calcium carbonate, 7-12 parts of dioctyl ester, 1.2-1.7 parts of sulfur, 0.6-1.1 parts of an accelerant, 0.8-1.3 parts of a vulcanization accelerant and 4.6-7.3 parts of an adhesive. The rubber hose inner rubber layer has good vapor oil resistance and ethanol resistance.

Description

technical field [0001] The invention relates to the field of rubber hose preparation, in particular to an inner rubber layer of a rubber hose for an ethanol-resistant gasoline fuel dispenser and a preparation method thereof. Background technique [0002] Currently, gasoline for vehicles on the market generally uses gasoline with 10% to 20% ethanol added. Gasoline added with ethanol has been widely used as automobile fuel because of its good antiknock performance, high oxygen content, ability to improve the quality of automobile exhaust emissions, and the sustainable regeneration of ethanol. But as we all know, although ethanol is an excellent fuel, it is also an excellent solvent. It is easy to corrode, soften, swell or crack rubber parts and synthetic non-metallic materials. The inner rubber layer of the traditional rubber hose for fuel dispensers is generally made of nitrile rubber composite material. It basically does not have any problems in transporting traditional eth...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/02C08L23/34C08K13/02C08K3/22C08K5/09C08K3/04C08K3/36C08K3/26
CPCC08K2003/2296C08K2003/265C08K2201/014C08L9/02C08L2201/08C08L2203/18C08L23/34C08K13/02C08K3/22C08K5/09C08K3/04C08K3/36C08K3/26
Inventor 刘庆国蒋利辉
Owner 漯河市久隆液压科技有限公司
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