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Preparation method of carbon fiber reinforced aluminum-based composite material

A technology for strengthening aluminum-based and composite materials, applied in the field of composite materials, can solve the problems of difficult industrialization, complicated preparation process, small thermal expansion coefficient, etc., and achieve the effects of avoiding black core phenomenon, simple preparation process and low production cost

Inactive Publication Date: 2019-11-19
XI'AN PETROLEUM UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the development of aerospace technology, traditional structural materials such as aluminum, magnesium, copper, and titanium alloys can no longer meet their latest application requirements. Metal matrix composites, which have been studied since the 1970s, have high temperature resistance , good wear resistance, generally higher mechanical properties than the base metal, smaller thermal expansion coefficient than the base metal, higher thermal conductivity, and all properties can be designed within a certain range, which has been favored by the aerospace sector. Among metals Adding an appropriate amount of high specific strength, high specific modulus, low density fibers, whiskers, particles and other reinforcements can significantly improve the specific strength and specific modulus of the composite material, but when preparing carbon fiber reinforced aluminum matrix composites, The wettability between carbon fiber and metal aluminum is poor, the preparation process is very complicated, and it is difficult to realize industrialization

Method used

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preparation example Construction

[0033] A method for preparing a carbon fiber reinforced aluminum matrix composite material of the present invention comprises the following steps:

[0034] S1. Put the carbon fiber in a muffle furnace and heat it up to 350-500°C for 10-80 minutes, then put the burned carbon fiber into ammonium persulfate with a concentration of 100-200g / L and a concentration of 50-200g / L at room temperature. 100ml / L H 2 SO 4 In the mixed solution, roughen treatment for 10-60 minutes;

[0035] S2. Add the roughened carbon fiber to 5-30g / L SnCl 2 Add a small amount of HCl at a concentration of 20-45g / L for sensitization treatment for 1-10min, then take it out and rinse it in still water for 3-20min, add the rinsed carbon fiber to 1-10g / L silver nitrate and 5-20ml / L Ammonia water mixture was activated at room temperature for 5-20 minutes;

[0036] S3. Put the activated carbon fiber into the chemical plating solution, control the temperature at 10-30°C and control the time for 10-60 minutes, a...

Embodiment 1

[0041] A method for preparing a carbon fiber reinforced aluminum matrix composite material of the present invention comprises the following steps:

[0042] S1. Put the carbon fiber in a muffle furnace and heat it up to 350°C for 10 minutes, then put the burned carbon fiber into ammonium persulfate with a concentration of 100g / L and H at a concentration of 50ml / L at room temperature. 2 SO4 In the mixed solution, roughen for 10 minutes;

[0043] S2, the carbon fiber of roughening treatment is added to the SnCl of 5g / L 2 Add a small amount of HCl at a concentration of 20g / L for sensitization treatment for 1min, then take it out and rinse it in still water for 3min, add the rinsed carbon fiber to a mixture of 1g / L silver nitrate and 5ml / L ammonia water for 5min at room temperature;

[0044] S3. Put the activated carbon fiber into the chemical plating solution, control the temperature at 10°C and control the time for 10 minutes, and keep stirring to complete the chemical plating. ...

Embodiment 2

[0048] A method for preparing a carbon fiber reinforced aluminum matrix composite material of the present invention comprises the following steps:

[0049] S1. Put the carbon fiber in a muffle furnace and heat it up to 400°C for 30 minutes, then put the burned carbon fiber into ammonium persulfate with a concentration of 140g / L and H with a concentration of 70ml / L at room temperature. 2 SO 4 In the mixed solution, roughen for 20 minutes;

[0050] S2, the carbon fiber of coarsening treatment is added to the SnCl of 10g / L 2 Add a small amount of HCl at a concentration of 25g / L for sensitization treatment for 4min, then take it out and rinse it in still water for 8min, add the rinsed carbon fiber to a mixture of 4g / L silver nitrate and 8ml / L ammonia water for 8min activation at room temperature;

[0051] S3. Put the activated carbon fiber into the chemical plating solution, control the temperature at 15°C and control the time for 20 minutes, and keep stirring to complete the ch...

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Abstract

The invention discloses a preparation method of a carbon fiber reinforced aluminum-based composite material. The preparation method comprises the following steps of firing carbon fibers, and then carrying out coarsening treatment at room temperature; then adding SnCl2, then adding HCl sensitized treatment, taking out, rinsing in static water, adding a mixed solution of silver nitrate and ammonia water, and carrying out room temperature activation treatment; continuously stirring the activated carbon fibers in a chemical plating solution to complete chemical plating; taking the carbon fibers subjected to chemical plating as a cathode, using metal copper as an anode to perform electroplating treatment in the electroplating solution, adding industrial raw aluminum into a smelting furnace, melting, refining and slagging off, stirring by adopting upper horizontal and lower inclined blades, adding 10%-30% of copper-plated carbon fibers while stirring, carrying out heat preservation treatment, and casting to form the high-strength carbon fiber reinforced aluminum-based composite material. According to the method, the binding force of the carbon fiber and the copper coating is improved, auniform and thick coating can be obtained, the black core phenomenon is avoided, the wettability of the carbon fiber and the aluminum liquid is improved, the material performance is excellent, and thepreparation process is simple and convenient.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to a method for preparing a carbon fiber reinforced aluminum-based composite material. Background technique [0002] With the development of aerospace technology, traditional structural materials such as aluminum, magnesium, copper, and titanium alloys can no longer meet their latest application requirements. Metal matrix composites, which have been studied since the 1970s, have high temperature resistance , good wear resistance, generally higher mechanical properties than the base metal, smaller thermal expansion coefficient than the base metal, higher thermal conductivity, and all properties can be designed within a certain range, which has been favored by the aerospace sector. Among metals Adding an appropriate amount of high specific strength, high specific modulus, low density fibers, whiskers, particles and other reinforcements can significantly improve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C49/06C22C49/14C22C47/04C22C47/08C23C28/02C23C18/40C23C18/18C25D3/38C22C101/10C22C121/02
CPCC22C47/04C22C47/08C22C49/06C22C49/14C23C18/1893C23C18/405C23C28/023C25D3/38
Inventor 黄剑雷哲周赛张倩苏碧云王文珍
Owner XI'AN PETROLEUM UNIVERSITY
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