A kind of self-healing superhydrophobic nano anticorrosion coating and preparation method thereof
An anti-corrosion coating and super-hydrophobic technology, applied in anti-corrosion coatings, microsphere preparation, coating, etc., can solve the problems of single composition of microcapsule cores and poor mechanical properties, achieve good anti-corrosion effect, realize self-healing, mechanical properties good performance effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0042] (1) Preparation of organofluorine silicon modified acrylic resin
[0043] Add 200g of xylene and 8g of emulsifier sodium lauryl sulfate into the reactor, heat to 70°C, and fully stir to dissolve. In another flask, pre-mix 200g methyl methacrylate, 150g butyl acrylate, and 70g α-methacrylic acid, take out 1 / 10 of the acrylate monomer mixture, add it to the reactor for pre-emulsification for 0.5h, and add 3g potassium persulfate , stirred for 5min, after the seed emulsion was formed, began to drop the remaining acrylate monomer mixture, 50g vinyltriethoxysilane and 25g trifluoropropylmethylcyclotrisiloxane, and then added 1g hydrogen peroxide tert-butanol and 1g of Diabalin, heat preservation and continue to react for 1h, after cooling, organofluorosilicon-modified acrylic resin is obtained.
[0044] (2) Preparation of microcapsules
[0045] At room temperature, add 50g of urea and 100g of formaldehyde solution into a four-necked flask, stir to dissolve, adjust the pH o...
Embodiment 2
[0049] (1) Preparation of organofluorine silicon modified acrylic resin
[0050] Add 250g of xylene and 10g of emulsifier sodium lauryl sulfate into the reactor, heat to 70°C, stir and dissolve fully; in another flask, put 200g of methyl methacrylate, 150g of butyl acrylate, 70g of α-methyl Pre-mix acrylic acid, take out 1 / 10 of the acrylate monomer mixture, put it into the reactor for pre-emulsification for 1 hour, add 5g of potassium persulfate, stir for 10 minutes, after the seed emulsion is formed, start to drop the remaining acrylate monomer mixture, 50g Vinyltriethoxysilane and 50g of trifluoropropylmethylcyclotrisiloxane were added, 2g of tert-butanol hydroperoxide and 2g of diabolite were added, and the reaction was continued for 1 hour at heat preservation. After cooling, an organofluorosilicon-modified acrylic resin was obtained.
[0051] (2) Preparation of microcapsules
[0052] At room temperature, add 70g of urea and 140g of formaldehyde solution into a four-neck...
Embodiment 3
[0056] (1) Preparation of organofluorine silicon modified acrylic resin
[0057] Add 200g of xylene and 6g of emulsifier sodium lauryl sulfate into the reactor, heat to 70°C, and fully stir to dissolve; in another flask, put 200g of methyl methacrylate, 100g of butyl acrylate, and 80g of α-methacrylic acid Pre-mixing, take out 1 / 10 of the acrylate monomer mixture, put it into the reactor for pre-emulsification for 2 hours, add 4g of potassium persulfate, stir for 10min, after the seed emulsion is formed, start to drop the remaining acrylate monomer mixture, 30g of ethylene triethoxysilane and 30g of trifluoropropylmethylcyclotrisiloxane, then 1g of tert-butanol hydroperoxide and 2g of diabolite were added, and the reaction was continued for 1h at heat preservation. After cooling, an organofluorosilicon-modified acrylic resin was obtained.
[0058] (2) Preparation of microcapsules
[0059] At room temperature, add 50g of urea and 100g of formaldehyde solution into a four-necke...
PUM
| Property | Measurement | Unit |
|---|---|---|
| particle diameter | aaaaa | aaaaa |
| adhesivity | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More