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Graphene oxide reinforced waterproof polymer emulsion preparation method

A polymer emulsion and graphene technology, applied in the field of building waterproof materials, building surface waterproofing and adhesion coatings, can solve problems such as failure to meet waterproof requirements, achieve uniform and stable distribution of bonding force, good low temperature flexibility, and enhanced waterproofing. performance effect

Active Publication Date: 2019-12-20
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the waterproof coatings currently on the market have some defects that cannot meet the ideal waterproof requirements expected by people. The present invention designs and prepares a waterproof coating with excellent low temperature resistance and flexibility for low temperature environments, which is suitable for efficient and durable waterproofing in low temperature environments. Not only Suitable for flat construction, it has a very good effect on wall joints or the entire wall, and it is durable and does not crack or peel off

Method used

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  • Graphene oxide reinforced waterproof polymer emulsion preparation method
  • Graphene oxide reinforced waterproof polymer emulsion preparation method

Examples

Experimental program
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Effect test

example 1

[0055] The raw materials required for the preparation of graphene oxide reinforced waterproof polymer emulsion, in terms of total mass parts, include the following components:

[0056] N,N-dimethylacrylamide: 4.5 parts

[0057] Octadecyl vinyl ether: 13.5 parts

[0058] Dicyclohexyl peroxydicarbonate: 0.35 parts

[0059] Sodium hypophosphite: 0.50 parts

[0060] Cinnamamide: 11.0 parts

[0061] Octadecyl vinyl ether: 257 parts

[0062] Dicyclopentadiene ethoxy acrylate: 137 parts

[0063] Azobisisoheptanonitrile: 4.0 parts

[0064] Polyethylene glycol dimethacrylate: 3.0 parts

[0065] Ethanolamine: 1.6 parts

[0066] Sodium ethylate: 2.4 parts

[0067] Composition of diaminododecylbenzene and diaminooctadecylbenzene with a mass ratio of 1:1: 41 parts

[0068] Ethylene oxide and propylene oxide block polyether with a mass ratio of 2:1: 25 parts

[0069] Graphene oxide: 0.85 parts

[0070] The balance is deionized water.

[0071] The preparation method is as follows...

example 2

[0078] The raw materials required for the preparation of graphene oxide reinforced waterproof polymer emulsion, in terms of total mass parts, include the following components:

[0079] N,N-dimethylacrylamide: 4.5 parts

[0080] Octadecyl vinyl ether: 13.5 parts

[0081] Dicyclohexyl peroxydicarbonate: 0.35 parts

[0082] Sodium hypophosphite: 0.50 parts

[0083] 4-vinylbenzamide: 11.0 parts

[0084] Octadecyl vinyl ether: 257 parts

[0085] Dicyclopentadiene ethoxy acrylate: 137 parts

[0086] Azobisisoheptanonitrile: 4.0 parts

[0087] Polyethylene glycol dimethacrylate: 3.0 parts

[0088] Ethanolamine: 1.5 parts

[0089] Sodium ethylate: 2.5 parts

[0090] Composition of diaminododecylbenzene and diaminooctadecylbenzene with a mass ratio of 1:1: 41 parts

[0091] Ethylene oxide and propylene oxide block polyether with a mass ratio of 2:1: 25 parts

[0092] Graphene oxide: 0.9 parts

[0093] The balance is deionized water.

[0094] The preparation method is as fol...

example 3

[0101] The raw materials required for the preparation of graphene oxide reinforced waterproof polymer emulsion, in terms of total mass parts, include the following components:

[0102] N,N-dimethylacrylamide: 4.5 parts

[0103] Octadecyl vinyl ether: 13.5 parts

[0104] Dicyclohexyl peroxydicarbonate: 0.35 parts

[0105] Sodium hypophosphite: 0.50 parts

[0106] 4-vinylbenzamide: 10.5 parts

[0107] Octadecyl vinyl ether: 256 parts

[0108] Dicyclopentadiene ethoxy acrylate: 137 parts

[0109] Composition of azobisisobutyronitrile and azobisisoheptanonitrile with a mass ratio of 1:1: 4.5 parts

[0110] Polyethylene glycol dimethacrylate: 3.0 parts

[0111] Ethanolamine: 1.8 parts

[0112] Sodium ethylate: 2.7 parts

[0113] Composition of diaminododecylbenzene and diaminooctadecylbenzene with a mass ratio of 1:1: 41 parts

[0114] Ethylene oxide and propylene oxide block polyether with a mass ratio of 1:2: 26 parts

[0115] Graphene oxide: 0.9 parts

[0116] The bal...

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Abstract

The invention provides a graphene oxide reinforced waterproof polymer emulsion preparation method, wherein 1000 parts of the graphene oxide reinforced waterproof polymer emulsion comprise the following raw materials: 3.3-5.5 parts of an amide hydrophilic small monomer for emulsification, 6.5-15.0 parts of an alkyl hydrophobic small monomer for emulsification, 0.12-0.35 part of an emulsion initiator a, 0.24-0.56 part of a chain transfer agent, 8.3-13.5 parts of an amide hydrophilic small monomer, 35-46 parts of a flexible small monomer, 23-32 parts of an ether polymer, 2.5-6.0 parts of an initiator b, 200-280 parts of an alkyl hydrophobic small monomer, 100-160 parts of an acrylate-based hard monomer, 2.6-7.5 parts of a cross-linking agent, 1.2-2.6 parts of a neutralizer, 2.3-4.0 parts of apH regulator, 0.64-1.35 parts of a functional monomer, and the balance of deionized water. According to the invention, the polymer emulsion with advantages of good stability, strong adhesion, excellent tensile strength, excellent wear resistance and excellent water resistance is synthesized by using the amide-based strong hydrophilic monomer and the long alkyl chain hydrophobic monomer as the rawmaterials through dispersion pre-emulsification, constant-temperature polymerization, variable-speed stirring, pH adjustment and a series of processes, wherein the amide molecules can enhance the adhesion of the polymer, and the tensile strength, the water resistance and the wear resistance of the film formed by the emulsion are remarkably enhanced by graphene oxide.

Description

technical field [0001] The invention belongs to the technical field of building waterproof materials, relates to the field of building surface waterproofing and attached coatings, in particular to a preparation method of graphene oxide enhanced waterproofing polymer emulsion. Background technique [0002] Waterproof materials are an indispensable part of construction engineering structures, and are widely used in water conservancy projects, highway bridges and other fields. The durability of buildings is closely related to the quality of waterproof materials. With the rapid development of society and continuous innovation of technology, various new and efficient waterproof materials have begun to appear. However, most of the waterproof coatings currently on the market have some defects that cannot meet the ideal waterproof requirements expected by people. The present invention designs and prepares a waterproof coating with excellent low temperature resistance and flexibilit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F265/04C08F216/18C08F2/24C09D151/00C09D7/61C09D7/65
CPCC08F2/24C08F265/04C09D151/003C09D7/61C09D7/65C08F216/18C08L71/02C08K3/042
Inventor 王迎斌宋钰莹贺行洋苏英刘飞宏
Owner HUBEI UNIV OF TECH
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