Graphene natural rubber polymer anti-slip mixed foaming material on ice and preparation method of mixed foaming material

A technology of natural rubber and foaming materials, applied in applications, soles, clothing, etc., can solve the problem of poor anti-slip effect, poor mechanical properties such as tensile strength and elongation at break, comprehensive use of wear resistance and appearance properties Poor performance and other problems, achieve good anti-slip effect, good anti-slip effect, save manpower and equipment costs

Active Publication Date: 2020-01-17
FUJIAN WUCHIHENG TECH DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] 1. The anti-slip effect is poor, especially when used on ice, the requirements for dry anti-slip and wet anti-slip are high, and good low temperature resistance is also requi

Method used

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  • Graphene natural rubber polymer anti-slip mixed foaming material on ice and preparation method of mixed foaming material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A kind of graphene natural rubber macromolecule anti-slip mixed foaming material on ice, made of raw materials comprising the following parts by weight:

[0042] 50-60 parts of natural rubber, 32-37 parts of butyl rubber, 8-12 parts of butadiene rubber, 4-6 parts of white carbon black, 2.4-2.8 parts of basalt fiber, 2-3 parts of nano-silica, 2.2 parts of graphene ~2.6 parts, silicone oil 1.4~1.7 parts, zinc oxide 1.2~1.5 parts, zinc stearate 1.5~2.0 parts, stearic acid 1.8~2.4 parts, crosslinking agent 1.6~1.9 parts, flow aid 4.5~5.5 parts part, foaming agent 1.5~2.0 parts; the graphene is a multilayer graphene microsheet; the crosslinking agent is a mixture of sulfur, dicumyl peroxide and zinc dimethacrylate.

[0043] Preferably, the graphene natural rubber polymer ice anti-slip mixed foaming material is made of raw materials comprising the following parts by weight: 55 parts of natural rubber, 35 parts of butyl rubber, 10 parts of butadiene rubber, 5 parts of white ca...

Embodiment 2

[0058] A kind of graphene natural rubber macromolecule anti-slip mixed foaming material on ice, made of raw materials comprising the following parts by weight:

[0059] 50 parts of natural rubber, 32 parts of butyl rubber, 8 parts of butadiene rubber, 4 parts of white carbon black, 2.4 parts of basalt fiber, 2 parts of nano-silica, 2.2 parts of graphene, 1.4 parts of silicone oil, 1.2 parts of zinc oxide , 1.5 parts of zinc stearate, 1.8 parts of stearic acid, 1.6 parts of crosslinking agent, 4.5 parts of flow aid, 1.5 parts of blowing agent; Described graphene is multilayer graphene microchip; Described crosslinking agent is A mixture of sulfur, dicumyl peroxide and zinc dimethacrylate.

[0060] In this embodiment, the number of layers of the multilayer graphene microsheets is 5-8 layers.

[0061] In the present embodiment, the mass ratio of sulfur, dicumyl peroxide and zinc dimethacrylate in the mixture of sulfur, dicumyl peroxide and zinc dimethacrylate is 10: 5:2.

[00...

Embodiment 3

[0074] A kind of graphene natural rubber macromolecule anti-slip mixed foaming material on ice, made of raw materials comprising the following parts by weight:

[0075] 60 parts of natural rubber, 37 parts of butyl rubber, 12 parts of butadiene rubber, 6 parts of white carbon black, 2.8 parts of basalt fiber, 3 parts of nano-silica, 2.6 parts of graphene, 1.7 parts of silicone oil, 1.5 parts of zinc oxide , 2.0 parts of zinc stearate, 2.4 parts of stearic acid, 1.9 parts of crosslinking agent, 5.5 parts of flow aid, 2.0 parts of blowing agent; Described graphene is multilayer graphene microchip; Described crosslinking agent is A mixture of sulfur, dicumyl peroxide and zinc dimethacrylate.

[0076] In this embodiment, the number of layers of the multilayer graphene microsheets is 8-10 layers.

[0077] In the present embodiment, the mass ratio of sulfur, dicumyl peroxide and zinc dimethacrylate in the mixture of sulfur, dicumyl peroxide and zinc dimethacrylate is 10: 7:3.

[...

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Abstract

The invention discloses a graphene natural rubber polymer anti-slip mixed foaming material on ice and a preparation method of the mixed foaming material. The mixed foaming material is prepared from the following raw materials in parts by weight: 50-60 parts of natural rubber, 32-37 parts of butyl rubber, 8-12 parts of cis-polybutadiene, 4-6 parts of white carbon black, 2.4-2.8 parts of basalt fibers, 2-3 parts of nano silicon dioxide, 2.2-2.6 parts of graphene, 1.4-1.7 parts of silicone oil, 1.2-1.5 parts of zinc oxide, 1.5-2.0 parts of zinc stearate, 1.8-2.4 parts of stearic acid, 1.6-1.9 parts of a cross-linking agent, 4.5-5.5 parts of a flow promoting agent, and 1.5-2.0 parts of a foaming agent. The graphene natural rubber polymer anti-slip mixed foaming material on the ice provided bythe invention has a high anti-slip coefficient, a good anti-slip effect, good low-temperature resistance, a good low-temperature anti-slip effect, high tensile strength, good mechanical properties, low abrasion, good wear resistance and long service life.

Description

technical field [0001] The invention relates to the technical field of rubber products, in particular to a graphene natural rubber polymer anti-slip mixed foam material on ice and a preparation method thereof. Background technique [0002] Natural rubber (NR) is a natural polymer compound with cis-1,4-polyisoprene as the main component, and 91% to 94% of its components are rubber hydrocarbons (cis-1,4-polyisoprene Diene), and the rest are non-rubber substances such as protein, fatty acid, ash, sugar, etc. It is generally flake solid, relative density 0.94, refractive index 1.522, elastic modulus 2-4MPa, softens at 130-140°C, sticky and soft at 150-160°C, and begins to degrade at 200°C. It has high elasticity at room temperature, slightly plastic, and crystallizes and hardens at low temperature. It has good alkali resistance, but not strong acid resistance. Insoluble in water, lower ketones and alcohols, can swell in non-polar solvents such as chloroform, carbon tetrachlor...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L23/22C08L9/00C08L83/04C08L23/06C08K13/06C08K9/06C08K7/10C08K3/36C08K3/04C08K3/22C08K3/06C08K5/14C08K5/098C08K5/09C08J9/10A43B13/04
CPCA43B13/04C08J9/0023C08J9/0061C08J9/0066C08J9/0071C08J9/0085C08J9/009C08J9/103C08J2203/04C08J2307/00C08J2409/00C08J2423/06C08J2423/22C08J2483/04C08K3/06C08K3/36C08K5/09C08K5/098C08K5/14C08K7/10C08K9/06C08K13/06C08K2003/2296C08K2201/011C08K3/042
Inventor 丁天宁丁德材丁幼丝
Owner FUJIAN WUCHIHENG TECH DEV CO LTD
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