A grinding preparation method of copper (i)-bromine hybrid fluorescent material
A fluorescent material, mixed grinding technology, applied in luminescent materials, chemical instruments and methods, etc., can solve the problems of cumbersome reaction steps, difficult to find a solvent, production of divalent copper by-products, etc., and achieves a simple preparation method and fluorescence stability. The effect of good and large application potential
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0020] Weigh 0.308 g of tetramethylammonium bromide and 0.572 g of cuprous bromide, place them in a mortar, expose to air at room temperature 25° C., and grind for 30 min. The mixture after the grinding reaction was dissolved in 20ml of boiling isopropanol, filtered while it was hot, the filtrate was left to stand and cooled to precipitate a solid, and the resulting solid was dried in vacuo to obtain the product [N(CH 3 ) 4 ] 3 [Cu 2 Br 5 ]. The obtained [N(CH 3 ) 4 ] 3 [Cu 2 Br 5 ] clusters emit yellow-green fluorescence under 254nm ultraviolet excitation, and the maximum emission wavelength is around 510nm. The fluorescence spectrum data are as follows: Figure 1 Show. Its X-ray powder diffraction pattern of the prepared copper (I) halogen cluster compound is as follows figure 2 As shown, the positions of the diffraction peaks are consistent with the theoretical simulation spectrum.
Embodiment 2
[0022] Weigh 0.82 g of tetraethylammonium bromide and 0.28 g of cuprous bromide, place them in a mortar, expose to air at room temperature 25°C, and grind for 30 min. The mixture after the grinding reaction was dissolved in 20ml of boiling ethanol, filtered while hot, and the filtrate was left to cool to precipitate a solid, and the gained solid was dried in vacuo to obtain the product [N(C 2 h 5 ) 4 ] 2 [Cu 2 Br 4 ]. The obtained [N(C 2 h 5 ) 4 ] 2 [Cu 2 Br 4 ] clusters emit blue fluorescence under 254nm ultraviolet excitation, and the maximum emission wavelength is around 460nm. The fluorescence spectrum data are as follows: Figure 1 Show. Its X-ray powder diffraction pattern of the prepared copper (I) halogen cluster compound is as follows figure 2 As shown, the positions of the diffraction peaks are consistent with the theoretical simulation spectrum.
Embodiment 3
[0024] Weigh 0.80 g of tetrapropylammonium bromide and 0.28 g of cuprous bromide, place them in a mortar, expose them to air at room temperature 25° C., and grind for 30 min. The mixture after the grinding reaction was dissolved in 20ml of boiling ethanol, filtered while hot, and the filtrate was left to cool to precipitate a solid, and the gained solid was dried in vacuo to obtain the product [N(C 3 h 7 ) 4 ] 2 [Cu 4 Br 6 ]. The obtained [N(C 3 h 7 ) 4 ] 2 [Cu 4 Br 6 ] clusters emit orange-red fluorescence under 254nm ultraviolet excitation, and the maximum emission wavelength is around 660nm. The fluorescence spectrum data are as follows: Figure 1 Show. Its X-ray powder diffraction pattern of the prepared copper (I) halogen cluster compound is as follows figure 2 As shown, the positions of the diffraction peaks are consistent with the theoretical simulation spectrum.
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More