On-line embossed high-strength antiskid plastic-wood composite material plate and preparation method thereof
A wood-plastic composite material and high-strength technology, applied in the field of wood-plastic composite materials, can solve the problems of high production cost of pressing rollers and their brackets, high material performance requirements, loss of decoration and anti-slip, etc. Strong modification, not easy to aging and discoloration
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Embodiment 1
[0023] A method for preparing an online embossed high-strength non-slip plastic-wood composite material plate, comprising the following steps:
[0024] (1) Weigh graphene, dimethylformamide, triethylenetetramine, dicyclohexylcarboimide and ethanol respectively according to the weight ratio of 1:15:0.3:0.3:4, and add graphene to dimethyl In formamide, ultrasonically disperse for 1.5h, then add triethylenetetramine and dicyclohexylcarboimide, ultrasonicate again for 15min, react at 125°C for 45h, add ethanol, stand still for 54h, filter, and wash the resulting precipitate Afterwards, at 60 DEG C, vacuum dry 42h, sieve, obtain modified graphene (average specific surface area is 230m 2 / g);
[0025] (2) Weigh wood powder, styrene, acrylic acid, methyl methacrylate, sodium bisulfite, azobisisobutyronitrile and tetrahydrofuran respectively according to the weight ratio of 100:13:3.5:5:0.6:0.8:18, After mixing styrene, acrylic acid, methyl methacrylate, sodium bisulfite, azobisisob...
Embodiment 2
[0032] A method for preparing an online embossed high-strength non-slip plastic-wood composite material plate, comprising the following steps:
[0033] (1) Weigh graphene, dimethylformamide, triethylenetetramine, dicyclohexylcarboimide and ethanol respectively according to the weight ratio of 1:10:0.2:0.1:3, and add graphene to dimethyl In formamide, ultrasonically disperse for 1 hour, then add triethylenetetramine and dicyclohexylcarboimide, and then ultrasonically treat for 10 minutes. After reacting at 120°C for 40 hours, add ethanol, let stand for 48 hours, filter, and wash the resulting precipitate , dried in vacuum at 55°C for 36h, and sieved to obtain modified graphene (the average specific surface area is 180m 2 / g);
[0034] (2) Weigh wood powder, styrene, acrylic acid, methyl methacrylate, sodium bisulfite, azobisisobutyronitrile and tetrahydrofuran respectively according to the weight ratio of 100:10:3:4:0.5:0.6:16, After mixing styrene, acrylic acid, methyl metha...
Embodiment 3
[0041] A method for preparing an online embossed high-strength non-slip plastic-wood composite material plate, comprising the following steps:
[0042] (1) Weigh graphene, dimethylformamide, triethylenetetramine, dicyclohexylcarboimide and ethanol respectively according to the weight ratio of 1:20:0.4:0.5:5, and add graphene to dimethyl In formamide, ultrasonically disperse for 2 hours, then add triethylenetetramine and dicyclohexylcarboimide, and then ultrasonically treat for 20 minutes. After reacting at 130°C for 50 hours, add ethanol, stand still for 60 hours, filter, and wash the obtained precipitate , dried in vacuum at 65°C for 48h, and sieved to obtain modified graphene (the average specific surface area is 280m 2 / g);
[0043] (2) Weigh wood powder, styrene, acrylic acid, methyl methacrylate, sodium bisulfite, azobisisobutyronitrile and tetrahydrofuran respectively according to the weight ratio of 100:16:4:6:0.7:1:20, After mixing styrene, acrylic acid, methyl metha...
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