Preparation method of microbial coupling catalytic system for efficient catalytic conversion of CO2
A catalytic conversion and catalytic system technology, applied in the direction of using microorganisms, catalyst activation/preparation, preparation of organic compounds, etc., can solve the problems of slow speed and inability to meet the requirements of industrialization, and achieve the effect of efficient catalytic conversion of CO2
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Embodiment 1
[0063] One for high-efficiency catalytic conversion of CO 2 The preparation method of the microbial coupling catalytic system includes the following steps:
[0064] 1) The iron trioxide is dried at 120°C for 12 hours;
[0065] 2) Dissolve the auxiliary salt sodium nitrate in solvent methanol to obtain sodium nitrate methanol solution;
[0066] 3) Immerse the sodium nitrate methanol solution on the dried ferric oxide powder, stir evenly, and dry at 120°C for 12 hours to obtain the catalyst;
[0067] 4) The catalyst is tableted under 10MPa, and then granulated to 20-40 mesh to obtain the catalyst;
[0068] 5) Fill 3.0g of catalyst, first use pure H 2 Carry out reduction, where the specific reduction conditions are 350℃ and the gas velocity is 4500h -1 (V / V), the reduction time is 10h, after the reduction, the catalyst is used to lower the room temperature with nitrogen;
[0069] 6) Grind the reduced catalyst to 100 mesh and mix it with methanogenic microorganisms to obtain a coupled cataly...
Embodiment 2
[0074] Repeat Example 1, the only difference is: in step S12, the auxiliary salt is potassium nitrate and the solvent is ethanol; in step 5), the gas for reduction is pure CO gas. The selectivity results are shown in Table 2 below.
[0075] Table 2: Catalyst reaction results
[0076] Initial amount / mL Final state volume / mL Consumption (mL) / Output (mL) Raw material CO 2 Amount of
Embodiment 3
[0078] Repeat Example 1, the only difference is: in step S12, the auxiliary salt is lithium nitrate, and the solvent is acetone; in step 5), the reduction gas is synthesis gas (H 2 / CO). The selectivity results are shown in Table 3 below.
[0079] Table 3: Catalyst reaction results
[0080] Initial amount / mL Final state volume / mL Consumption (mL) / Output (mL) Raw material CO 2 Amount of
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