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Nano cellulose glass fiber composite filter material as well as preparation method and application thereof

A technology of nano-cellulose and glass fiber, which is applied in the direction of synthetic cellulose/non-cellulose material pulp/paper, fiber raw material treatment, filtration and separation, etc. Flocculation and other problems, achieve simple manufacturing process, solve the effect of weak bonding strength and low resistance

Inactive Publication Date: 2020-07-31
NANJING FIBERGLASS RES & DESIGN INST CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But there are following problems in this method: the organic polymers such as polyacrylonitrile, polytetrafluoroethylene, polyurethane that adopt also use a large amount of such as tetrahydrofuran, N dimethyl formamide, N in the spinning process, Organic reagents such as N-dimethylacetamide, dimethyl sulfoxide, and acetone are very unfriendly to the environment, and the efficiency of electrospinning is low, which is not suitable for industrial production, etc.
However, a large amount of chemicals are also added in the preparation process of the cellulose nanofibers of the above method, and in the process of making the cellulose nanofiber slurry and other substances into pulp, the cellulose nanofiber slurry is difficult to disperse and flocculates. problems such as poly, making the performance of the final product poor

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0044] A preparation method of novel nanocellulose / glass fiber composite filter material, comprising the steps of:

[0045] (1) After immersing the fibrillable plant fiber pulp board in water for a certain period of time, it is dispersed in water by a decomposer to obtain a uniform fiber suspension, which is then filtered, wrung out and balanced for later use.

[0046] (2) Obtaining nanocellulose by physical or chemical treatment, by washing, quantifying, and ultrasonically obtaining nanocellulose solution;

[0047] (3) Add water and a dispersant to the glass fiber raw material to uniformly disperse the slurry to obtain a slurry, which is sequentially deslagged, diluted, formed, and dehydrated to form a wet paper sheet with uniform thickness.

[0048] (4) The nanocellulose solution is coated on the surface of the glass fiber paper by coating to form a nanocellulose coating.

[0049] (5) Drying and molding.

[0050] In the step (1), the fibrillable plant fiber pulp board is o...

Embodiment 1

[0070] (1) Soak the coniferous wood commercial pulp board in deionized water for 4 hours to obtain a slurry with a pulp concentration of 1%; then put the soaked slurry into a deflagger for 20 minutes, and the speed of the demineralizer is 1000 rpm / min , wring out after dissolving, and equilibrate the moisture at 4°C for 24 hours before use.

[0071] (2) Prepare nanocellulose by chemical method TEMPO oxidation method, then wash, and vibrate by ultrasonic wave under 200KW power, obtain the clear and transparent solution that nanocellulose concentration is 0.1%wt.

[0072] (3) Add water and sulfuric acid after the microfiber glass wool and glass fiber chopped strands are proportioned according to the set ratio, and evenly obtain a slurry with a concentration of 1.5wt% and a pH of 3.2 through a high-frequency disintegrator; After deslagging, it is diluted to a pulp suspension with a concentration of 0.45 wt%, formed by a fourdrinier machine, dehydrated to form a wet paper sheet, a...

Embodiment 2

[0077] (1) Soak the hardwood commercial pulp board in deionized water for 6 hours to obtain a slurry with a pulp concentration of 5%; then put the soaked slurry into a deflagger for 30 minutes, and the speed of the demineralizer is 2000 rpm / min , wring out after dissolving, and equilibrate the moisture at 4°C for 24 hours before use.

[0078] (2) The nanocellulose was prepared by chemical acid hydrolysis, then washed, and oscillated by ultrasound at a power of 1000KW to obtain a clear and transparent solution with a nanocellulose concentration of 1.5%wt.

[0079] (3) Add water and sulfuric acid after the microfiber glass wool and glass fiber chopped strands are proportioned according to the set ratio, and stir to obtain a slurry with a concentration of 1.0wt% and a pH of 3.0 through a high-frequency disintegrator; After deslagging, it is diluted to a pulp suspension with a concentration of 0.35wt%, formed by a fourdrinier machine, dehydrated to form a wet paper sheet, and drie...

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Abstract

The invention belongs to the field of filtration, and particularly relates to a nano cellulose glass fiber composite filter material and a preparation method and application thereof. The method comprises the following steps: (1) defibering fibrillable plant fibers by a defibering machine, and dispersing in water to obtain slurry; (2) performing treatment by a physical or chemical method to obtainnanocellulose, and washing and ultrasonically treating to obtain a nanocellulose solution; (3) adding water and a dispersing agent into the glass fiber raw material, uniformly dispersing to obtain slurry, and sequentially deslagging, diluting, forming and dehydrating to form wet paper sheets with uniform thickness; (4) coating the surface of glass fiber paper with the nano-cellulose solution in acoating manner to form a nano-fiber coating; (5) drying and forming. The nano cellulose solution prepared from the plant fibers is compounded with the glass fiber base material in a coating manner, sothat the obtained fiber material has the advantages of high precision, high air permeability, low resistance, long service lifetime and the like, and is particularly suitable for the field of filtering of air, water and the like.

Description

technical field [0001] The invention belongs to the field of filtration, in particular to a nano-cellulose glass fiber composite filter material and its preparation method and application. Background technique [0002] Although traditional glass fiber filter materials can effectively filter pollutant particles, it usually needs to sacrifice air permeability to achieve higher filtration efficiency, resulting in a larger pressure drop. Therefore, it is difficult to achieve an effective balance between filtration efficiency and piezoresistance only by the structural characteristics of the glass fiber itself. [0003] In recent years, more and more researches have been focusing on the preparation of composite filter materials of nanofibers and glass fibers, which on the one hand can make the filter material have ultra-high filtration accuracy, and on the other hand can retain the characteristics of glass fiber deep filtration. The existing method for preparing the composite fil...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/00D21H19/34D21H13/40
CPCB01D39/00B01D2239/10D21H13/40D21H19/34
Inventor 石玉强李建杨超吴耀春钱慧姚嘉兰
Owner NANJING FIBERGLASS RES & DESIGN INST CO LTD
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