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A comprehensive utilization method of granite cutting waste liquid

A technology of waste liquid and granite, which is applied in the field of utilization of waste liquid from granite cutting, can solve problems such as the difficulty in recycling artificial granite heavy calcium waste slag, solidification of limestone slurry and equipment blockage, cracking and agglomeration of calcium carbonate, and achieve high value Maximize utilization, improve application effect, and rapid separation effect

Active Publication Date: 2022-04-29
HEFEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These polymer residues have caused great difficulties in the recycling of artificial granite heavy calcium waste slag
For example, the use of heavy calcium waste slag containing unsaturated polyester residues as fillers in polymer materials such as plastics and rubber will lead to thermo-oxidative aging degradation of polymer materials; heavy calcium waste slag containing PAM is easy to use in flue gas wet desulfurization systems Lead to solidification of limestone slurry and blockage of equipment; heavy calcium waste slag containing polymer residues used for burning lime is easy to cause calcium carbonate to burst and agglomerate during high-temperature calcination, and block the kiln

Method used

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  • A comprehensive utilization method of granite cutting waste liquid
  • A comprehensive utilization method of granite cutting waste liquid
  • A comprehensive utilization method of granite cutting waste liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The flow rate of the waste slag of a stone company is 1 ton / hour, and the mass fraction of solid particles in the waste liquid is 48%. Relying on the FLUENT software (Mixture model and standard κ-ε floc model) to simulate with the PISO algorithm, it is obtained that the stone The flow field trace, suspended solids volume fraction, flow velocity and other data of the waste residue liquid in the advection tank are simulated at the same time the concentration field and flow field distribution in the sedimentation tank, and the shape of the sedimentation tank is designed as figure 1 shown. As shown in the figure, the width of the sedimentation tank I zone changes from narrow to wide, and then gradually widens (that is, narrow-wide-narrow structure), from narrow to wide, the flow rate of waste liquid slows down. The silicon surfactant is added at a rate of 10 kg / hour, and then the narrowing of the flow channel leads to a faster flow rate of the waste liquid, which is conduci...

Embodiment 2

[0045]The flow rate of the waste slag of a stone company is 2 tons / hour, and the mass fraction of solid particles in the waste liquid is 48%. Relying on the FLUENT software (Mixture model and standard κ-ε floc model) and using the PISO algorithm to simulate, it is obtained that the stone The flow field trace, suspended solids volume fraction, flow velocity and other data of the waste residue liquid in the advection tank are simulated at the same time the concentration field and flow field distribution in the sedimentation tank, and the shape of the sedimentation tank is designed (such as figure 2 shown). At the same time, add organic silicon surfactant at the inlet of the waste residue liquid at a rate of 20 kg / hour.

[0046] The waste residue liquid passes through the sedimentation tank to complete the precipitation of large particles; and then prepares the small particle waste residue slurry with a solid content of 30% through the concentration tank.

[0047] The large par...

Embodiment 3

[0049] The flow rate of the waste slag of a stone company is 5 tons / hour, and the mass fraction of solid particles in the waste liquid is 48%. Relying on the FLUENT software (Mixture model and standard κ-ε floc model) and using the PISO algorithm to simulate, it is obtained that the stone The flow field trace, suspended solids volume fraction, flow velocity and other data of the waste residue liquid in the advection tank are simulated at the same time the concentration field and flow field distribution in the sedimentation tank, and the shape of the sedimentation tank is designed. At the same time, organic silicon surfactant was added at the inlet of the waste residue liquid at a rate of 5 kg / hour.

[0050] The waste residue liquid passes through the sedimentation tank to complete the precipitation of large particles; and then prepares the small particle waste residue slurry with a solid content of 40% through the concentration tank.

[0051] The large particle calcium carbona...

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Abstract

The invention discloses a method for comprehensive utilization of waste liquid from granite cutting, which comprises the following steps: (1) adding low surface energy substances to the waste liquid from cutting stone; Large particles of waste residue with low saturated resin content; for solutions that are difficult to precipitate and have high unsaturated resin content, wet modification is used as a filler for water-based architectural coatings. The beneficial effect of the present invention is: on the basis of analyzing the composition of the granite cutting fluid, the sedimentation tank is used to separate the large particle calcium carbonate in the granite waste liquid, and then the unsaturated resin and the small particle calcium carbonate are separated by evaporation combined with membrane filtration. No flocculant is added in the separation process to achieve green separation; and according to the characteristics of the separated waste residue, differentiated application can improve the application effect of waste residue and realize high-value utilization of slag.

Description

technical field [0001] The invention relates to the technical field of utilization of waste liquid from granite cutting, in particular to a comprehensive utilization method of waste liquid from granite cutting. Background technique [0002] The artificial granite waste residue contains about 75% calcite, about 10% dolomite and about 15% unsaturated resin and impurity components. The particle distribution in the waste residue is uneven (as shown in Table 1) and the content of toxic and harmful substances is lower than that of the national Building standards (as shown in Table 2). In recent years, a series of new technologies for resource utilization of stone waste have been developed, but most of them are aimed at waste marble powder produced by natural stone processing. For example, Zheng Changji reported a method based on waste marble powder for flue gas desulfurization and waste treatment; Liu Yanming and Du Gaoxiang used industrial waste acid to react with stone waste re...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10C01F11/18C02F101/10
CPCC02F9/00C01F11/18C02F1/52C02F1/04C02F1/44C02F2101/10
Inventor 黄俊俊桂成梅赵娣芳秦广超陈珍明赵兴科陆国庆程兵
Owner HEFEI UNIV