A kind of production method of quick-drying bible paper
A production method and technology of bible paper, applied in the field of paper manufacturing, can solve problems such as mutual adhesion or blooming, slow drying speed, and influence on printing effect, and achieve the effects of increasing the number of hydroxyl groups, improving paper strength, and improving water absorption capacity
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Embodiment 1
[0033] A production method of quick-drying bible paper, comprising the steps:
[0034] (1) Under the protection of nitrogen, the mixture of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate is added to ethanol at a molar ratio of 1:15 and stirred to form a mixed solution. The amount of the mixture of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate is 0.2g, the saponification degree of saponified polyvinyl acetate is 40%, and the weight average molecular weight is 5000; After reacting under reduced pressure for 20 hours, a kind of silane-based polymer was obtained after removing ethanol by distillation under reduced pressure;
[0035] (2) Under the protection of nitrogen, add methyl acrylate dropwise into the methanol solution of diethanolamine, wherein the molar ratio of methyl acrylate to diethanolamine is 1:1, react at 40°C for 3 hours to obtain a mixed solution; then add 1 % p-toluenesulfonamide, and trimethylolpropane was adde...
Embodiment 2
[0042] (1) Under the protection of nitrogen, add the mixture of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate in a molar ratio of 1:10 to ethanol and stir to form a mixed solution. The mixture amount of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate is 0.05g, the degree of saponification of saponified polyvinyl acetate is 60%, and the weight average molecular weight is 5000; After reacting under reduced pressure for 20 hours, a kind of silane-based polymer was obtained after removing ethanol by distillation under reduced pressure;
[0043] (2) Under the protection of nitrogen, add methyl acrylate dropwise into the methanol solution of diethanolamine, wherein the molar ratio of methyl acrylate to diethanolamine is 1:3, and react at 35°C for 4 hours to obtain a mixed solution; then add 3 % p-toluenesulfonamide, and trimethylolpropane was added dropwise into the mixed solution, methanol was distilled off under reduced pressure, t...
Embodiment 3
[0050] (1) Under the protection of nitrogen, add the mixture of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate in a molar ratio of 1:13 to ethanol and stir to form a mixed solution. The mixture amount of saponified polyvinyl acetate and dimethoxychlorosilyl propyl isocyanate is 0.1g, the saponification degree of saponified polyvinyl acetate is 50%, and the weight average molecular weight is 3000; After reacting under reduced pressure for 25 hours, a kind of silane-based polymer was obtained after removing ethanol by distillation under reduced pressure;
[0051] (2) Under the protection of nitrogen, add methyl acrylate dropwise into the methanol solution of diethanolamine, wherein the molar ratio of methyl acrylate to diethanolamine is 1:3, react at 38°C for 5 hours to obtain a mixed solution; then add 2 % p-toluenesulfonamide, and trimethylolpropane was added dropwise into the mixed solution, methanol was distilled off under reduced pressure, the tempe...
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