Rare earth steel and preparation method thereof

A rare earth and steel plate technology, applied in the field of iron and steel metallurgy, can solve the problems of difficult production of ODS-RAFM steel, easy oxidation and pollution of powder, and poor product reproducibility, so as to improve high temperature oxidation resistance, avoid macro segregation, The effect of less impurities

Active Publication Date: 2020-09-25
XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the main preparation method of ODS steel is powder metallurgy (Powder metallurgy, PM), but PM-ODS steel preparation technology has disadvantages such as complex process and low efficiency, powder is easily oxidized and polluted, poor economy and poor product reproducibility.
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  • Rare earth steel and preparation method thereof
  • Rare earth steel and preparation method thereof
  • Rare earth steel and preparation method thereof

Examples

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Example Embodiment

[0035] The preparation method of rare earth steel of the present invention comprises the steps:

[0036] (1) Metal mother liquor smelting

[0037] Put metal chromium, tungsten, tantalum and iron in the zirconia crucible in the vacuum induction furnace, turn on the vacuum pump, evacuate to 5-10Pa, and melt the alloy in the furnace under vacuum; after the alloy is melted, lower the temperature of the alloy liquid Adjust to 1650-1700°C, add deoxidizer (high-purity graphite carbon, its carbon content ≥ 99.99%) for deoxidation; after the oxygen mass fraction in the alloy liquid is removed below 10ppm, adjust the temperature of the alloy liquid to 1550-1600°C , add alloy silicon and alloy manganese; after alloy silicon and alloy manganese are melted, add rare earth yttrium; add rare earth yttrium and refine for 30 to 40 minutes, and carry out sufficient electromagnetic stirring to promote the comprehensive dissolution and homogenization of rare earth yttrium.

[0038] (2) rare eart...

Example Embodiment

[0046] Example 1

[0047] This embodiment takes the smelting of 100kg rare earth steel as an example. The chemical components and their mass percentages of rare earth steel are: C: 0.01%, Si: 0.2%, Mn: 0.5%, Cr: 8%, W: 2% , V: 0.23%, Ta: 0.1%, Zr: 0.001%, Y 2 o 3 : 0.3%, the rest is Fe.

[0048] The preparation method of the present embodiment rare earth steel comprises the steps:

[0049] (1) Metal mother liquor smelting

[0050] Put metal chromium, tungsten, tantalum and iron in the zirconia crucible in the vacuum induction furnace, turn on the vacuum pump, evacuate to 5-10Pa, and melt the alloy in the furnace under vacuum; after the alloy is melted, lower the temperature of the alloy liquid Adjust to 1650°C, add a deoxidizer (high-purity graphite carbon, its carbon content ≥ 99.99%) for deoxidation; after the oxygen mass fraction in the alloy liquid is removed below 10ppm, adjust the temperature of the alloy liquid to 1550°C, and add alloy silicon and alloy manganese; ...

Example Embodiment

[0059] Example 2

[0060] This embodiment takes the smelting of 100kg rare earth steel as an example. The chemical components and their mass percentages of rare earth steel are: C: 0.05%, Si: 0.15%, Mn: 0.45%, Cr: 9%, W: 2.3% , V: 0.25%, Ta: 0.08%, Zr: 0.05%, Y 2 o 3 : 0.3%, the rest is Fe.

[0061] The preparation method of the present embodiment rare earth steel comprises the steps:

[0062] (1) Metal mother liquor smelting

[0063] Put metal chromium, tungsten, tantalum and iron in the zirconia crucible in the vacuum induction furnace, turn on the vacuum pump, evacuate to 5-10Pa, and melt the alloy in the furnace under vacuum; after the alloy is melted, lower the temperature of the alloy liquid Adjust to 1670°C, add deoxidizer (high-purity graphite carbon, its carbon content ≥ 99.99%) for deoxidation; after the oxygen mass fraction in the alloy liquid is removed below 10ppm, adjust the temperature of the alloy liquid to 1570°C, add alloy silicon and alloy manganese; af...

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Abstract

The invention discloses rare earth steel and a preparation method of the rare earth steel. The rare earth steel comprises the following components of, in percentage by weight, 0.01%-0.05% of C, 0.15%-0.3% of Si, 0.4%-0.5% of Mn, 8%-10% of Cr, 2%-2.5% of W, 0.2%-0.25% of V, 0.05%-0.1% of Ta, 0.001%-0.01% of Zr, 0.3%-0.6% of Y<2>O<3> and the balance Fe; during preparation, Cr, W, Ta, Fe, Si, Mn andY are smelted into metal mother liquor, then mixed gas of CO<2> and Ar serving as an oxidizing agent is introduced into the alloy mother liquor, Y is oxidized into Y<2>O<3>, Zr, V and C are added, casting is performed after melting down; electroslag remelting is carried out on a cast ingot in a protective atmosphere, purifying is carried out; austenitizing is carried out on a purified steel ingot,then the steel ingot is subjected to pressure machining to form a steel plate, water cooling is carried out after pressure machining; and heat treatment is carried out on the steel plate obtained through pressure machining, a yttrium nanometer precipitated phase is precipitated from the steel plate, and the rare earth steel is obtained. According to the rare earth steel and the preparation methodof the rare earth steel, RAFM ( Reduced Activation Ferritic / Martensitic ) steel can be produced in a smelting and casting mode, the yield of the RAFM steel can be increased, and meanwhile the high-temperature mechanical property of the RAFM steel is improved.

Description

technical field [0001] The invention belongs to the field of iron and steel metallurgy, and in particular relates to a rare earth steel and a preparation method thereof. Background technique [0002] Low activation ferritic / martensitic steel (Reduced Activation Ferritic / Martensitic, RAFM) has the advantages of low activation, low radiation swelling rate, excellent mechanical properties, thermophysical properties and mature technical foundation, etc. The preferred structure of cladding structural materials for fusion reactors. The designed operating temperature range of RAFM steel is 325-550°C, which cannot meet the requirements of CFETR Phase II and future nuclear fusion reactors. In order to improve the high-temperature mechanical properties of RAFM steel, a high melting point rare earth oxide disperse phase (Y 2 o 3 ) to prepare ODS-RAFM steel has become a good solution. Y 2 o 3 The melting point of the oxide is 2417°C, which has good thermal stability and does not c...

Claims

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Application Information

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IPC IPC(8): C22C38/02C22C38/04C22C38/22C22C38/24C22C38/26C22C38/28C22C33/04C21C7/06C21C7/10C22B9/18C21D8/02C21D1/18
CPCC21C7/06C21C7/10C21D1/18C21D8/0226C21D2211/004C21D2211/008C22B9/18C22C32/0026C22C33/04C22C38/02C22C38/04C22C38/22C22C38/24C22C38/26C22C38/28
Inventor 邱国兴
Owner XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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