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A kind of manufacturing method of compressible metal thermal interface material

A technology of interface material and manufacturing method, which is applied in heat exchange materials, chemical instruments and methods, semiconductor devices, etc., can solve the problems of high cost of metal phase change materials, complicated welding process, and virtual welding.

Active Publication Date: 2021-11-05
上海仅博激光技术有限公司
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Problems solved by technology

Due to the restrictions on the use of lead, the commonly used solders are tin-silver and tin-copper alloys. As thermal interface materials, their disadvantages are that the soldering process is complicated and requires a reflow soldering process. Thermal stress is likely to occur during the soldering process and heat the components. Shock, in addition, because it is a solid-state connection, during use, due to the thermal expansion coefficient mismatch, it will generate a large thermal stress, which cannot be released through the adaptive compression or relaxation of the thermal interface material, in the chip and heat dissipation Large thermal stress on the surface of the device may cause fatigue cracks. On the other hand, welding defects such as virtual welding and bridging are prone to occur during the welding process, and the cost is high
[0012] In summary, the existing thermal interface materials, except metal phase change materials and brazing materials, have thermal conductivity less than 5W / (m·K), and metal phase change materials have high cost and serious problems. The pumping effect of the brazing material, the welding process of the brazing material is complicated, the cost is high, and the thermal stress caused by the mismatch of the thermal expansion coefficient cannot be relaxed
[0013] In view of the fact that the thermal conductivity of metal materials is much greater than that of other thermal interface materials, some researchers have tried to use copper foil and aluminum foil as thermal interface materials, but the effect is not good. The reason is that although copper foil and aluminum foil have high thermal conductivity, they have poor flexibility. Under the action of slight packaging pressure, there is no compressibility, and it cannot adapt to the uneven installation gap between the chip and the heat sink, and cannot closely fit the surface of the chip and the heat sink, resulting in large thermal resistance and low thermal conductivity. There are no metal-based thermal interface materials on the market (except for liquid metals and solders)
[0014] The above-mentioned problems of commonly used thermal interface materials are as follows: 1. Low thermal conductivity and large interface thermal resistance. Liquid metal and brazing material have the highest thermal conductivity, but both are expensive and inconvenient to use. The thermal conductivity of commonly used thermal paste is only between 0.4 and 4W / (m·K), and it is difficult to dissipate the heat generated by the chip in time. 2. There is a pump-out effect, and thermal paste, phase-change polymer materials, and liquid metals There is a pump-out effect, and with the prolongation of the use time, the thermal conductivity and reliability drop significantly; 3. There are aging problems, thermal paste, thermal pad, thermal gel, thermal adhesive, phase change polymer materials, etc. Polymer materials such as resins or polymers are used as the matrix, which will age under the action of long-term temperature cycle thermal stress, resulting in a decrease in thermal conductivity and reduced reliability; Add high thermal conductivity fillers to the polymer. If there are more thermal conductivity fillers, the softness and compressibility will be reduced, and the thermal conductivity will be low, only 0.3~3W / (m K); 6. Poor usability, thermal paste, thermal conductivity Adhesive and thermal conductive gel are coated on the surface of components when used, but once these materials are coated, they are not easy to clean up and cannot be reused. For the soldering method, the shapes and specifications of heating components are various, and reflow soldering and other complex processes, high cost
7. There is a contradiction between cost and thermal conductivity that is difficult to reconcile. Liquid metal and soldering with high thermal conductivity have high cost, while low-cost thermal conductive paste and thermal gel have low thermal conductivity.
Metal filaments do have some thermal conductivity, but they are not compressible
In addition, the Chinese patent ZL201210169313.8 requires a surface protection material layer, an adhesive material layer and a matrix material layer in addition to the heat conduction and heat dissipation layer. Although it has a certain thermal conductivity, its compressibility is low
[0017] To sum up, metal materials have high thermal conductivity, but they cannot solve the problem of compressibility of metal materials. Most of the thermal interface materials in the prior art are made of metal materials or carbon fiber materials with high thermal conductivity and certain compressibility. It is made of compressible polymer materials. The processing technology adopted is to use metal particles or metal wires as fillers and fill them into rubber, resin and other compressible materials. The thermal conductivity is provided by the metal material, and the rubber , resin, etc. provide compressibility

Method used

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  • A kind of manufacturing method of compressible metal thermal interface material

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Comparison scheme
Effect test

Embodiment 1

[0068] Red copper long fibers with a diameter of 0.06 mm were prepared by monofilament drawing method, and the long fibers were spun into red copper filament yarns with 16 cross-section fibers by spinning process, and red copper long fibers were spun by weaving process Yarn weaving forms the compressible metal woven cloth thermal interface material with a thickness of 0.6mm and a maximum compression of 50%. The metal cloth is seamed according to the size of the chip, and the metal cloth is cut into a compressible metal pad along the seam line. The thermal conductivity of the prepared thermal pad was finally measured to be 96W / (m·K)).

Embodiment 2

[0070] The pure aluminum long fiber with a diameter of 0.05 mm is prepared by the monofilament drawing method, and the pure aluminum long fiber is spun into a pure aluminum long fiber yarn with a cross-section of 5 fibers by the spinning process, and the weaving process is adopted. The compressible metal woven cloth thermal interface material is formed by weaving pure aluminum yarns, with a thickness of 0.2mm and a maximum compression of 30%. The thermal conductivity of the prepared thermal pad was finally measured to be 46W / (m·K)).

Embodiment 3

[0072] The 316L stainless steel long fiber with a diameter of 0.04mm was prepared by the monofilament drawing method, and the stainless steel long fiber was spun into a filament yarn with a cross-section of 32 fibers by the spinning process, and the filament yarn was woven to form the The above-mentioned compressible metal woven cloth thermal interface material has a thickness of 1.2mm and a maximum compression of 40%. The thermal conductivity of the prepared thermal pad was finally measured to be 5.2 W / (m·K)).

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Abstract

The present application discloses a method for making a compressible metal thermal interface material, wherein the method for making a compressible metal thermal interface material includes the following steps: firstly process metal fibers with a diameter of 0.005-0.1mm, and then spin the metal fiber The fiber is spun into a metal yarn with a cross-section of 5 to 40 fibers, and the metal yarn is woven into a metal woven thermal interface material with a thickness of 0.2 to 1.6 mm by weaving or knitting technology, or air-laid, The acupuncture reinforcement process processes short metal fibers with a length of 30-80 mm and a diameter of 0.005-0.05 mm into a non-woven metal cloth thermal interface material with a thickness of 0.05-2.0 mm, wherein the metal woven cloth and non-woven thermal interface material The number of metal fibers included in the cross-sectional direction of the interface material is 5-40.

Description

technical field [0001] The invention relates to a thermal interface material used for electronic packaging, in particular to a method for making a metal thermal interface material. Background technique [0002] 5G networks refer to the fifth generation of wireless networks. At present, the transmission rate of 5G network has successfully reached 1Gbps in the 28GHz band. In the future, the transmission rate of 5G network will even reach 10Gbps, and its data processing capacity is 10 to 100 times that of 4G. Chips, baseband chips, CPUs, GPUs, neural network chips, and other types of chips have a sharp increase in computation, resulting in a sharp increase in chip power consumption. The sharp increase in chip power consumption directly leads to a sharp increase in its calorific value, which requires higher and higher heat dissipation performance of chip packaging thermal management materials. It can be said that thermal management materials are one of the bottlenecks restricti...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/14H01L23/42
CPCC09K5/14H01L23/42
Inventor 李雷
Owner 上海仅博激光技术有限公司