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A flexible multi-layer wave absorbing material with adjustable frequency band and preparation method thereof

A wave-absorbing material and flexible technology, applied in antennas, electrical components, magnetic field/electric field shielding, etc., can solve the problems of narrow wave-absorbing frequency band, poor impedance matching, lack of wave-absorbing frequency band, etc., achieve broadband high-strength absorption, and improve work efficiency Effect

Active Publication Date: 2022-07-19
THE QUARTERMASTER RES INST OF THE GENERAL LOGISTICS DEPT OF THE CPLA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] A single absorbing material often has the disadvantages of poor impedance matching, limited absorption performance, and narrow absorbing frequency band.
Multi-layer composite absorbing material is an important means to achieve high-strength and broadband absorption. Patent application (CN 106469858A) discloses a absorber structure, which is multi-layered with metal plates, honeycomb layers, and resistor sheets to obtain broadband, Strong absorbing wave-absorbing material, but the weight of the metal plate is heavy, and the total thickness of the composite material exceeds 20cm. Patent application (CN10983029A) discloses a wave-absorbing composite material and its preparation method, specifically impedance matching layer / three-dimensional graphene layer / The preparation method of the low-frequency electromagnetic loss layer has a wide absorbing frequency band at low frequencies; the patent application (CN 108092006 A) discloses a layered broadband radar absorbing sheet and its preparation method, and the patent application (CN 105744816 B) discloses an electromagnetic wave Shielding composite film, the above two patent applications disclose the preparation method of multi-layer wave-absorbing film, the layer composite materials in the above patents can improve the absorption of electromagnetic waves, but cannot realize the selective transmission of electromagnetic waves in a specific frequency band However, it does not have the unique softness and breathability of fabrics
[0005] At present, there is a lack of multi-layer composite materials that can efficiently control the absorbing frequency band of absorbing materials and meet the needs of absorbing materials with soft and breathable properties.

Method used

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  • A flexible multi-layer wave absorbing material with adjustable frequency band and preparation method thereof
  • A flexible multi-layer wave absorbing material with adjustable frequency band and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Example 1, double-layer composite wave-absorbing fabric

[0046] The shape of the FSF resonance unit is selected as a cross, the distance between the resonance units is 30mm, and the resonance frequency is 3.96GHz. The conductive silver paste is coated on the polyester woven fabric by screen printing according to the periodic arrangement and size of the simulation design to make a patch type FSF. ,like figure 1 As shown; mix barium titanate and water-based polyurethane in a mass ratio of 3:1, stir mechanically for 5 minutes, and then scrape and coat on cotton woven fabric as a wave-absorbing fabric with an areal density of 625g / m 2 . According to the frequency, the fabric is selected on the top, and the wave-absorbing fabric is laminated on the bottom to obtain a double-layer composite wave-absorbing fabric with a thickness of 0.66 mm.

[0047]In the test range of 2-18GHz, the peak reflectivity is -17.3dB, the bandwidth less than -5dB is 9.4GHz, and the bandwidth les...

Embodiment 2

[0048] Example 2, three-layer wave-absorbing fabric

[0049] The shape of the FSF resonant unit is U-shaped, the spacing of the resonant unit is 20mm, and the resonant frequency is 4.78GHz. The conductive copper paste is coated on the cotton knitted fabric by screen printing according to the periodic arrangement and size of the simulation design to make a patch-type FSF. ,like figure 1 Zinc oxide and polyvinyl alcohol (molecular weight: 1000) were mixed in a mass ratio of 1:1, mechanically stirred for 5 minutes, and after mixing uniformly, the polyester three-dimensional spacer fabric was soaked in it for 15 minutes, and dried at room temperature as a wave-absorbing fabric. 714g / m 2 . The copper-nickel mixed slurry was coated on polyester knitted fabric as electromagnetic wave reflecting fabric by means of chemical plating. Three layers of absorbing fabrics are obtained by stacking the absorbing layer on top, the FSF on the middle, and the electromagnetic wave reflective f...

Embodiment 3

[0051] Example 3, three-layer wave-absorbing fabric

[0052] The shape of the FSF resonant unit is selected as a circular ring, the spacing of the resonant unit is 20mm, and the resonant frequency is 6GHz. The conductive copper paste is coated on the polyester woven fabric by screen printing, and then according to the periodic arrangement and size of the simulation design, the laser is used. Burn and tear off the part of the resonant unit to make a porous FSF, such as figure 1 Graphite and oil-based polyurethane were mixed in a mass ratio of 11:20, mechanically stirred for 5 minutes, and after mixing evenly, the polyester three-dimensional spacer fabric was soaked in it for 20 minutes, and dried at room temperature as a wave-absorbing layer, with an areal density of 1250g / m2 2 . Using silver yarn as raw material to weave woven fabric as electromagnetic wave reflecting fabric. Then, three layers of wave-absorbing fabrics with a thickness of 0.91 mm are obtained by laminating...

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Abstract

The invention discloses a flexible multi-layer wave absorbing material with adjustable frequency band and a preparation method thereof. The flexible multi-layer wave absorbing material is the following 1) or 2): 1) a double-layer wave absorbing material composed of a wave absorbing fabric layer and a frequency selective fabric layer or an electromagnetic wave reflecting fabric layer stacked in any order; 2) A multi-layer wave absorbing material composed of a frequency selective fabric layer, a wave absorbing fabric layer and an electromagnetic wave reflecting fabric layer stacked in any order. Fabric; the wave-absorbing fabric layer is made of a wave-absorbing fabric, and the wave-absorbing fabric is a fabric containing a wave-absorbing agent. The invention efficiently designs the periodic arrangement and size of the FSF units required for different frequency bands through simulation, and stacks the FSF with filtering effect, the wave absorbing fabric and the electromagnetic wave reflecting fabric in different stacking sequences and layer combinations, which can be adjusted and controlled. The layered composite material achieves broadband and high-strength absorption in different working frequency bands, improving work efficiency.

Description

technical field [0001] The invention relates to a flexible multilayer wave absorbing material with adjustable frequency band and a preparation method thereof, belonging to the technical field of microwave absorbing materials. Background technique [0002] The absorbing material needs to meet two conditions, one is that the impedance of the material and the free space are as equal as possible, and the other is that it has high electromagnetic wave loss ability, so as to convert electromagnetic wave energy into heat energy or other forms of energy to the greatest extent, without being like electromagnetic shielding. The material produces secondary pollution. Commonly used absorbers are carbonyl iron, ferrite, etc. For example, carbonyl iron is a high permeability absorbing material that relies on hysteresis loss and eddy current loss to attenuate electromagnetic waves. [0003] Different devices have different working frequency bands. In order to ensure the normal operation ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01Q15/00H01Q17/00H05K9/00
CPCH01Q15/0026H01Q15/0046H01Q17/005H05K9/0088
Inventor 张恒宇肖红陈剑英王焰梁高勇冯硕季惠孟令卿施楣梧
Owner THE QUARTERMASTER RES INST OF THE GENERAL LOGISTICS DEPT OF THE CPLA