Process for reducing and extracting iron from high-iron red mud

A high-iron red mud and process technology, applied in the field of high-iron red mud reduction and iron extraction, can solve the problems of low recovery rate of iron concentrate in magnetic separation, high energy consumption, difficult separation of iron and aluminum, etc., and achieve multi-level utilization and saving Energy and production cost reduction effects

Inactive Publication Date: 2021-03-05
NORTHEASTERN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The technical task of the present invention is to provide a high-iron red mud reduction and iron extraction process aimed at the above deficiencies in the prior art, which solves the problems of high energy consumption and low recovery rate of magnetic iron concentrate in the existing iron recovery process from red mud. Low and iron-aluminum isomorphism and a large number of iron-aluminum oxide solid solutions exist, and iron-aluminum is not easy to separate, etc.

Method used

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  • Process for reducing and extracting iron from high-iron red mud

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] In terms of mass percentage, the high-iron red mud used in this embodiment contains: TFe 37.57%, FeO 0.24%, SiO 2 2.97%, Al 2 o 3 13.41%, TiO 2 5.24%, Na 2 O 1.22%, K 2 O 0.15%, CaO 0.28%, MgO 0.06%, P0.02%, S 0.02%; carry out reduction iron extraction process on it, the specific steps are as follows:

[0035] S1: First dry the high-iron red mud, crush it to -1mm, add coal powder, and mix evenly to obtain a mixed material. In the mixed material, the amount of carbon in the reducing agent and oxygen in the iron oxide in the high-iron red mud The ratio is 0.8, and the exhaust gas produced by the rotary kiln is used to preheat the mixed material to 450°C;

[0036] S2: The preheated mixed material is added to the hot-pressed pelletizing device, hot-pressed and pelletized under a pressure of 45MPa, and the pressure is maintained for 1min to obtain high-iron red mud hot-pressed carbon-containing pellets with a size of 16mm×12mm×10mm. Ball type, compressive strength 72...

Embodiment 2

[0043] In terms of mass percentage, the high-iron red mud used in this embodiment contains: TFe 41.57%, FeO 0.55%, SiO 2 3.12%, Al 2 o 3 14.55%, TiO 2 4.24%, Na 2 O 2.12%, K 2 O 0.05%, CaO 0.20%, MgO 0.22%, P0.02%, S 0.02%, carry out hot-press pelletizing-rotary kiln roasting-submerged arc furnace smelting reduction on it as figure 1 Shown, method differs from embodiment 1 in that:

[0044] S1: The amount of pulverized coal is added so that in the mixed material, the ratio of the amount of carbon in the reducing agent to the amount of oxygen in the iron oxide in the high-iron red mud is 0.9, and the tail gas produced by the rotary kiln preheats the mixed material to 470 °C;

[0045] S2: hot-press pelletizing under a pressure of 40MPa, maintain the pressure for 1.5min, and the compressive strength of hot-pressed carbon-containing pellets is 675N / piece;

[0046] S3: The amount of pulverized coal added is 10% of the mass of high-iron red mud, and the rotary kiln is roaste...

Embodiment 3

[0051] In terms of mass percentage, the high-iron red mud used in this embodiment contains: TFe 38.52%, FeO 0.48%, SiO 2 2.12%, Al 2 o 3 15.00%, TiO 2 3.24%, Na 2 O 1.45%, K 2 O 0.56%, CaO 0.33%, MgO 0.45%, P0.02%, S 0.02%, carry out hot-press pelletizing-rotary kiln roasting-submerged arc furnace smelting reduction on it as figure 1 Shown, method differs from embodiment 1 in that:

[0052] S1: The tail gas produced by the rotary kiln preheats the mixed material to 500°C;

[0053] S2: Hot-press pelletizing under a pressure of 35MPa, maintain the pressure for 2 minutes, and the compressive strength of hot-pressed carbon-containing pellets is 665N / piece;

[0054] S3: Calcium oxide and Al in high-iron red mud carbonaceous pellets 2 o 3 The content is based on n(CaO) / n(Al 2 o 3 ) is added at a ratio of 2.0;

[0055] S4: Obtain a pig iron product containing 93.55% iron by mass and a 93.10% iron recovery rate;

[0056] S5: Use a sodium carbonate solution with a concent...

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Abstract

The invention provides a process for reducing and extracting iron from high-iron red mud. The process comprises the following steps: drying the high-iron red mud, crushing the dried high-iron red mudinto particles with the particle size of less than 1 mm, and mixing the particles with a carbon-based reducing agent to prepare high-iron red mud carbon-containing pellets; adding the high-iron red mud carbon-containing pellets, pulverized coal/coke powder and calcium oxide into a rotary kiln to be subjected to reduction roasting, wherein the roasting temperature is controlled to range from 1,050DEG C to 1,250 DEG C, the roasting time is controlled to range from 90 min to 180 min, and obtaining a submerged arc furnace molten material after roasting; and adding the submerged arc furnace moltenmaterial into a submerged arc furnace to be heated, melted and reduced, wherein the melting reduction temperature is controlled to range from 1,350 DEG C to 1,550 DEG C, the time is controlled to range from 30 min to 80 min, and iron oxide in the molten material is completely reduced into metal iron. The process disclosed by the invention solves the problems of high energy consumption, low magnetic separation iron ore concentrate recovery rate, massive existence of iron-aluminum isomorphism and iron-aluminum oxide solid solutions, difficulty in iron-aluminum separation and the like in the existing red mud iron recovery process.

Description

technical field [0001] The invention belongs to the technical field of mineral processing and metallurgical engineering, and in particular relates to a process for reducing and extracting iron from high-iron red mud. Background technique [0002] my country is a big country in the aluminum industry. The output of alumina and electrolytic aluminum accounts for more than 50% of the world's total output. It produces 30-50 million tons of red mud every year, and the accumulated stockpile has reached 350 million tons. The comprehensive utilization rate is only 4%. At present, the main methods of dealing with red mud in the world are ocean discharge and land storage, while our country mainly adopts the method of open storage. The stockpiling of red mud not only occupies a large amount of land, but also pollutes the air and soil. The infiltration of attached liquid in red mud will also cause pollution of lakes, rivers and groundwater, and destroy the ecological environment. With t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21B13/00C22B1/216C22B1/24C22B1/248
CPCC21B13/0006C21B13/0046C22B1/2406C22B1/216C22B1/248Y02P10/20
Inventor 余建文高鹏安亚雄韩跃新李艳军孙永升
Owner NORTHEASTERN UNIV
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