The invention discloses a mold powder for continuous casting of high aluminium-titanium-rare earth steel, which comprises the following compositions in percentage by weight: 20 to 40 percent of CaO, 30 to 50 percent of SiO2, 3 to 8 percent of F, 5 to 9 percent of Na2O, 0 to 5 percent of Li, 0.5 to 5 percent of C, less than 8 percent of Al2O3, less than 5 percent of MgO and the balance of inevitable impurities; and the alkalinity range of CaO/SiO2 is R+/-0.05, wherein R is alkalinity and is equal to between 0.917 and 0.333M; and M is the sum of mass percent of Al, Ti and rare earth elements in molten steel. The mold powder improves the performance, can meet the requirement of the continuous casting of steel types such as Al, Ti, rare earth and the like, fully guarantees the thickness, lubrication and consumption of a melt cinder layer, avoids causing surface defects of casting blanks such as cinder inclusion, cracks and the like or causing steel leakage due to too big withdrawal resistance, and effectively guarantees smooth continuous casting process and the surface quality of the casting blanks so as to produce high-quality casting blanks.