Titanium-magnesium aluminate spinel-brown fused alumina composite sliding plate and production method thereof

A magnesia-aluminum spinel and production method technology, which is applied in the field of refractory materials, can solve the problems of declining service life and safety factor of sliding bricks, high production cost and energy consumption, and damage to the structure of sliding bricks, so as to shorten the production cycle and produce The effect of low cost and strong liquidity

Active Publication Date: 2021-04-13
HENAN RONGJIN HIGH TEMPERATRUE MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the mainstream products of sliding bricks are aluminum carbon and aluminum zirconium carbon sliding plates, which are divided into two preparation processes: non-burning and high-temperature firing. Non-burning sliding bricks are mainly used for small and medium-sized ladles, used for smelting ordinary steel types, and high-temperature firing Due to the pre-reaction of sliding bricks, the performance of sliding bricks is better, suitable for use in large ladles, converters, etc., and is also the preferred choice for smelting steel varieties, etc., but its production process requires high-temperature firing and asphalt impregnation processes, and the production cost and energy consumption are relatively high. high
Traditional skateboard bricks are all carbon-containing refractory materials. There is a problem of carbon oxidation in the use of skateboard bricks. Carbon oxidation causes the structure of the skateboard to be loose, allowing oxides such as iron, manganese, and calcium to penetrate into the substrate of the skateboard and react with the alumina in the skateboard. And generate low melting material, cause the destruction of the structure of the skateboard brick, and accelerate the oxidation of carbon at the same time
The service life and safety factor of the skateboard tiles are reduced

Method used

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  • Titanium-magnesium aluminate spinel-brown fused alumina composite sliding plate and production method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A titanium-magnesium aluminum spinel-brown corundum composite slide plate, the raw materials are composed of 50% brown corundum, 32% magnesium aluminum spinel, 8% activated alumina micropowder, 5% Metal titanium, 5% metal aluminum, plus 3% thermosetting phenolic resin.

[0036] The weight ratio of different particle sizes is: particle size 1: particle size 2: particle size 3: particle size 5: particle size 6 = 15:25:10:18:14;

[0037] Among them, the model of activated alumina micropowder is RG4000; the model of binder phenolic resin is PF5323;

[0038] The production method of this composite slide plate comprises the following steps:

[0039] (1) Weigh various raw materials according to the proportion, first put metal titanium, activated alumina micropowder, metal aluminum, brown corundum and magnesium aluminum spinel with a particle size of ≤0.2mm into the mixer, and mix for 15 to 30 minutes to obtain mixed powder, spare;

[0040] (2) Then add brown corundum and ma...

Embodiment 2

[0046] A titanium-magnesium-aluminum spinel-brown corundum composite slide plate, the raw materials are composed of 65% brown corundum, 10% magnesium-aluminum spinel, 7% active alumina micropowder, 8% Metal titanium, 10% aluminum metal, plus 4% thermosetting phenolic resin.

[0047] The weight ratio of different particle sizes is: particle size 1: particle size 2: particle size 3: particle size 6=20:25:20:10.

[0048] The production method of this composite slide plate is the same as that of Example 1, and the performance index of the product obtained is: apparent porosity 4.1%, bulk density 3.20g / cm 3 , Normal temperature compressive strength 168MPa, high temperature flexural strength (buried carbon 1450℃×0.5h) 52.8MPa.

Embodiment 3

[0050] A titanium-magnesium-aluminum spinel-brown corundum composite slide plate, the raw materials are composed of 53% brown corundum, 23% magnesia spinel, 4% active alumina micropowder, 12% Metal titanium, 8% metal aluminum, plus 4% thermosetting phenolic resin.

[0051] The weight ratio of different particle sizes is: particle size 1: particle size 2: particle size 3: particle size 4: particle size 5, particle size 6=18:20:15:5:10:8.

[0052] The production method of this composite slide plate is the same as that of Example 1, and the performance index of the product obtained is: apparent porosity 5.9%, bulk density 3.16g / cm 3 , Normal temperature compressive strength 142MPa, high temperature flexural strength (buried carbon 1450℃×0.5h) 43.5MPa.

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Abstract

The invention particularly relates to a titanium-magnesium-aluminum spinel brown fused alumina composite sliding plate and a production method thereof. The titanium-magnesium-aluminum spinel brown fused alumina composite sliding plate comprises the following raw materials in percentage by weight: 35-65% of brown fused alumina, 4-8% of activated alumina micro-powder, 10-38% of magnesium-aluminum spinel, 5-15% of metallic titanium, 5-10% of metallic aluminum and 3-5% of phenolic resin as a binding agent; and the production method comprises the following steps: weighing various raw materials in proportion during production, uniformly mixing, mixing to obtain pug, carrying out mechanical pressing for forming, drying at 180-250 DEG C for 24-48 hours, hooping, grinding, and coating to obtain the product. According to the production method, high-temperature firing and asphalt dipping are not needed, energy conservation and environmental protection are achieved, the production cost is lower, the prepared product is good in oxidation resistance, thermal shock stability and erosion resistance, the apparent porosity is 3%-8%, the volume density is 3.05 g/cm < 3 >-3.20 g/cm < 3 >, the normal-temperature compressive strength is 120-200 MPa, and the high-temperature breaking strength (carbon burying 1450 DEG C * 0.5 h) is 25-60MPa.

Description

technical field [0001] The invention relates to a Ti-magnesium aluminum spinel-brown corundum composite sliding plate and a production method thereof, belonging to the technical field of refractory materials. Background technique [0002] At present, the mainstream products of sliding bricks are aluminum carbon and aluminum zirconium carbon sliding plates, which are divided into two preparation processes: non-burning and high-temperature firing. Non-burning sliding bricks are mainly used for small and medium-sized ladles, used for smelting ordinary steel types, and high-temperature firing Due to the pre-reaction of sliding bricks, the performance of sliding bricks is better, suitable for use in large ladles, converters, etc., and is also the preferred choice for smelting steel varieties, etc., but its production process requires high-temperature firing and asphalt impregnation processes, and the production cost and energy consumption are relatively high. high. Traditional s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C29/12C22C1/05B22D41/32
CPCC22C29/12C22C1/053B22D41/32
Inventor 赵臣瑞孙洋徐跃庆李宏宇牛智旺梁保青关斌斌尚俊利韩彦锋来丽苹
Owner HENAN RONGJIN HIGH TEMPERATRUE MATERIALS CO LTD
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