Silicon-carbon composite material, preparation method and application thereof, electrode and lithium ion battery,
A silicon-carbon composite material, lithium carbonate technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of the cycle performance and rate performance of silicon-based anode materials
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Embodiment 1
[0081] A method for preparing a silicon-carbon composite material, comprising the steps of:
[0082] S1. The solvent is NMP-ethanol mixed solvent with a ratio of 10:90. According to 900 parts of solvents, 100 parts of silicon, 3 parts of lithium carbonate, 0.03 parts of single-walled carbon nanotube-NMP slurry (calculated by carbon nanotubes) and 50 parts of flake graphite powder, stir in a high-speed disperser for 0.5 hours;
[0083] Then transfer to the pin-rod type dynamic separation high-energy sand mill for sand grinding. The sand mill adopts yttrium oxide stabilized zirconia balls with a diameter of 0.5mm, and the speed adopts 98% of the design speed of the equipment, and the sand mill is continuous for 2 hours;
[0084] Then add 100 parts of novolac resin, 9 parts of hexamethylenetetramine, 8 parts of PVA 1788, 5 parts of PVP K30, and sand again for 2 hours to obtain a sand-milled homogeneous slurry;
[0085] Finally, the slurry was transferred to an ultrasonic machine...
Embodiment 2
[0090] Except adding 5 parts of lithium carbonate and 0.1 part of single-walled carbon nanotube-NMP slurry (calculated as carbon nanotubes) in step S1, other steps and conditions were the same as in Example 1.
Embodiment 3
[0092] A method for preparing a silicon-carbon composite material, comprising the steps of:
[0093] S1. The solvent is NMP-ethanol mixed solvent with a ratio of 10:90. According to 900 parts of solvents, 100 parts of silicon, 5 parts of lithium carbonate, 0.03 parts of single-walled carbon nanotube-NMP slurry (in terms of carbon nanotubes) and 10 parts of flake graphite powder, stir in a high-speed disperser for 0.5 hours;
[0094] Then transfer to the pin-rod type dynamic separation high-energy sand mill for sand grinding. The sand mill adopts yttrium oxide stabilized zirconia balls with a diameter of 0.5mm, and the speed adopts 98% of the design speed of the equipment, and the sand mill is continuous for 2 hours;
[0095] Then add 40 parts of flake graphite powder, 100 parts of novolac resin, 9 parts of hexamethylenetetramine, 8 parts of PVA 1788, 5 parts of PVP K30, and sand mill for 1 hour to obtain sand mill homogeneous slurry;
[0096] Finally, the slurry was transferr...
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