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Hydrated crystal nucleus concrete coagulation accelerating early strength agent and preparation method thereof

A technology of accelerating early strength and concrete, which is applied in the field of concrete additives, can solve the problems of slow cement hydration rate, insufficient super early strength performance and accelerating effect, and crystal nucleus agglomeration, so as to promote cement hydration and shorten the mold Turnover period, effect of improving early strength

Active Publication Date: 2021-04-23
GUANGDONG REDWALL NEW MATERIALS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cost of calcium source and silicon source used in this kind of crystal nucleus early strength agent is high, and the particle size of the prepared crystal nucleus is relatively large (the particle size can only reach 100-500nm), and the number of crystal nucleus per unit volume is small, which promotes cement hydration The rate is slow, and the ultra-early strength performance and coagulation-accelerating effect are still insufficient. At the same time, the crystal nuclei are prone to agglomeration, and cannot be stored stably for a long time, which restricts its application in the concrete industry.

Method used

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  • Hydrated crystal nucleus concrete coagulation accelerating early strength agent and preparation method thereof
  • Hydrated crystal nucleus concrete coagulation accelerating early strength agent and preparation method thereof
  • Hydrated crystal nucleus concrete coagulation accelerating early strength agent and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0035] The preparation method of the water-soluble polymer dispersant of the present embodiment, described method comprises the following steps:

[0036] (1) Add glycidyl methacrylate and phosphoric acid with a molar mass ratio of 1:1 in the flask, under nitrogen protection, stir magnetically at room temperature until the acid value is constant, and obtain phosphonate monomer A; phosphonate monomer A The synthetic route of is shown in the following formula

[0037] (2) Add measured isobutenol polyoxyethylene ether (HPEG4000) and measured deionized water into the four-necked flask, stir, heat up to 35°C, when the isobutenol polyoxyethylene ether (HPEG4000) is completely dissolved, add Hydrogen peroxide, after 5 minutes, respectively dropwise add the aqueous solution of phosphonate monomer, the aqueous solution of vinyltriethoxysilane, the mixed aqueous solution of acrylic acid and mercaptopropionic acid, and the aqueous solution of sodium sulfite to the four-necked flask resp...

Embodiment 2

[0044] The preparation method of the water-soluble polymer dispersant of the present embodiment, described method comprises the following steps:

[0045] (1) Add glycidyl methacrylate and phosphoric acid with a molar mass ratio of 1:1 in the flask, under nitrogen protection, stir magnetically at room temperature until the acid value is constant, and obtain phosphonate monomer A; phosphonate monomer A The synthetic route of is shown in the following formula

[0046] (2) Add metered prenol polyoxyethylene ether (TPEG4000) and metered deionized water into the four-necked flask, stir, heat up to 35°C, when prenol polyoxyethylene ether (TPEG4000) dissolves After completion, add hydrogen peroxide, and add phosphonate monomer aqueous solution, vinyltriethoxysilane aqueous solution, acrylic acid and mercaptopropionic acid mixed aqueous solution, and sodium sulfite aqueous solution to the four-necked flask at the same time dropwise after 5 minutes, and control the dropping time 3h, ...

Embodiment 3

[0053] The preparation method of the water-soluble polymer dispersant of the present embodiment, described method comprises the following steps:

[0054] (1) Add glycidyl methacrylate and phosphoric acid with a molar mass ratio of 1:1 in the flask, under nitrogen protection, stir magnetically at room temperature until the acid value is constant, and obtain phosphonate monomer A; phosphonate monomer A The synthetic route of is shown in the following formula

[0055] (2) Add metered allyl polyoxyethylene ether (APEG2400) and metered deionized water into the four-necked flask, stir, heat up to 35°C, when allyl polyoxyethylene ether (APEG2400) is completely dissolved , adding hydrogen peroxide, and 5 minutes later, respectively dropwise adding aqueous solution of phosphonate monomer, aqueous solution of vinyltriethoxysilane, mixed aqueous solution of acrylic acid and mercaptopropionic acid, and aqueous solution of sodium sulfite to the four-necked flask respectively. Control th...

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Abstract

The invention relates to preparation and application of a hydrated crystal nucleus concrete coagulation accelerating early strength agent, which takes a water-soluble polymer dispersant as a template and ground Portland cement clinker as a nucleating substance to prepare a hydrated crystal nucleus suspension. Through the synergistic effect of different functional groups of the polymer dispersing agent and the special design of the molecular structure, the polymer dispersing agent can be quickly adsorbed to the surface of the instantly generated C-S-H crystal nucleus and has a stable dispersing effect, meanwhile, the C-S-H crystal nucleus is prevented from further growing and becoming larger, the size (30-120 nm) of the crystal nucleus is effectively controlled, and coagulation of crystal nucleus suspension liquid is avoided. The crystal nucleus suspension can significantly promote the hydration of cement, quickly improve the early strength of concrete, effectively shorten the initial and final setting time of concrete, meet the form removal strength requirements of prefabricated parts within 6-8 hours under natural conditions, and greatly shorten the mold turnover period.

Description

technical field [0001] The invention relates to the field of concrete additives, in particular to a hydration crystal nucleus concrete coagulation accelerator and early strength agent and a preparation method thereof. Background technique [0002] With the continuous development of modern concrete technology, the requirements for the early strength of concrete are getting higher and higher, and the demand for concrete prefabricated components is increasing sharply. One of the most important indicators for the production of prefabricated components is the development of early concrete strength, that is, rapid Reach the mold removal strength (≥15MPa), in order to facilitate the rapid turnover of molds, shorten the turnover period of molds, and save production costs. [0003] At present, the use of steam curing technology is a common method to improve the early strength of precast concrete components, but improper steam curing operation will cause quality defects in steam cured...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/32C08F283/06C08F230/02C08F230/08C08F220/06C04B103/10
CPCC04B40/0039C04B24/32C08F283/065C04B2103/10C04B22/08C08F230/02C08F230/085C08F220/06
Inventor 林永权王子儒张小富赵利华白淑英尹佳芝刘虎李宁
Owner GUANGDONG REDWALL NEW MATERIALS
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