Modified filtrate reducer for petroleum drilling fluid
A technology of oil drilling and fluid loss reducer, which is applied in the field of oil drilling, can solve the problems of limited temperature resistance and salt resistance, and achieve the effect of improving high temperature resistance
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Embodiment 1
[0031] 1) Preparation of amino-terminated hyperbranched polymer: add diethylenetriamine in the reaction flask and place it in an ice-water bath environment, continuously feed nitrogen into the reaction flask, and mix equimolar methyl acrylate with methanol dropwise. added to the reaction, after the dropwise addition was completed, stirred at room temperature for 4 h, rotary-evaporated to remove methanol, and then the reaction flask was placed in an oil bath for polycondensation to obtain an amino-terminated hyperbranched polymer;
[0032] 2) Preparation of carboxylated cellulose: add the alkalized cellulose with sodium hydroxide into the reaction flask, add the prepared chlorosulfonic acid and chloroform (m:m=2.5:1) under the condition of a constant temperature water bath at 40° C. Sulfonation reaction to obtain sodium cellulose sulfonate; catalyst perchloric acid (10ml) and the sodium cellulose sulfonate (100mg) and maleic anhydride (1g) were added to the reaction flask, and e...
Embodiment 2
[0034] Example 2: Preparation of modified humic acid
[0035] A 4% potassium persulfate aqueous solution was added to the reaction flask containing 10 g of humic acid, the reaction flask was placed in an environment of 80 °C, and 5 g of sodium p-styrenesulfonate and 5 g of 2-acrylamide-2-methyl were slowly added dropwise under stirring conditions. The mixed monomer aqueous solution of propyl propanesulfonic acid is added dropwise, and the reaction is kept for 3 hours after the completion of the dropwise addition to obtain the modified humic acid.
Embodiment 3
[0036] Example 3: Preparation of quaternized chitosan
[0037]Add 5g of chitosan and 50ml of isopropanol into the reaction flask, stir at 65°C for 15min, then heat up to 85°C, slowly add 60ml of glycidyl trimethylammonium chloride solution (mass fraction is 40%) dropwise, The reaction was performed at a constant temperature for 12 h, and after the reaction was completed, it was filtered, washed and dried to obtain quaternized chitosan;
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