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Method for strengthening welding performance of tungsten/molybdenum and alloy thereof through rhenium element

A welding performance, molybdenum-rhenium alloy technology, applied in the direction of welding equipment, welding medium, welding equipment, etc., can solve the problems of difficult precise control of cooling speed, difficulty in assembly of added materials, restrictions, etc., to achieve grain size reduction, toughness and brittleness The effect of reducing the transition temperature and strengthening the weld performance

Active Publication Date: 2021-12-03
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 2. The assembly of added materials is difficult, and tolerances and shapes need to be strictly controlled;
[0007] 3. The amount added is limited by its solid solubility in tungsten / molybdenum and its alloys;
[0008] 4. The method of accelerating the cooling rate after welding is adopted, and the cooling rate is not easy to control precisely
[0009] The work on adding alloying element rhenium to the welding seam to enhance the welding performance has not been reported yet

Method used

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  • Method for strengthening welding performance of tungsten/molybdenum and alloy thereof through rhenium element
  • Method for strengthening welding performance of tungsten/molybdenum and alloy thereof through rhenium element
  • Method for strengthening welding performance of tungsten/molybdenum and alloy thereof through rhenium element

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] 1) Fully grind the tungsten welding surface, and clean it until the contact surface is smooth and clean;

[0046] 2) Molybdenum-rhenium alloy wire is selected, and its surface is polished; the mass fraction of rhenium element in the molybdenum-rhenium alloy wire is 30%;

[0047] 3) The tungsten welding surface is connected, and the molybdenum-rhenium alloy wire is wound around the weld, and placed in a vacuum of 1×10 -3 In the Pa environment, the laser welding method is used to melt the molybdenum-rhenium alloy wire, and the welding seam forms a molten pool; the laser welding laser power is 1800w, the spot diameter of the laser beam on the area to be welded is 0.5mm, and the welding speed is 1.5m / min.

[0048] 4) Simultaneously perform ultrasonic oscillation on the molten pool, the ultrasonic oscillation frequency is 35kHz, and the ultrasonic oscillation time is 20min, so that the rhenium element is evenly mixed into the molten pool;

[0049] 5) Carry out heat treatmen...

Embodiment 2

[0051] 1) Fully grind the molybdenum welding surface, and clean it until the contact surface is smooth and clean;

[0052] 2) Molybdenum-rhenium alloy wire is selected, and its surface is polished; the mass fraction of rhenium element in the molybdenum-rhenium alloy wire is 10%;

[0053] 3) The molybdenum welding surface is connected, the molybdenum-rhenium alloy wire is wound around the weld, and the vacuum degree is 1×10 -4In the Pa environment, the laser welding method is used to melt the molybdenum-rhenium alloy wire, and the welding seam forms a molten pool; the laser welding laser power is 1500w, the spot diameter of the laser beam on the area to be welded is 0.6mm, and the welding speed is 1m / min.

[0054] 4) Simultaneously perform ultrasonic oscillation on the molten pool, the ultrasonic oscillation frequency is 30kHz, and the ultrasonic oscillation time is 30min, so that the rhenium element is evenly mixed into the molten pool;

[0055] 5) Carry out heat treatment on...

Embodiment 3

[0057] 1) Fully grind the tungsten alloy welding surface, and clean it until the contact surface is smooth and clean;

[0058] 2) Molybdenum-rhenium alloy wire is selected, and its surface is polished; the mass fraction of rhenium element in the molybdenum-rhenium alloy wire is 10-45%;

[0059] 3) The tungsten alloy welding surface is connected, the molybdenum-rhenium alloy wire is wound around the welding seam, and the vacuum degree is 1×10 -3 ~1×10 -4 In Pa or argon protection environment, use laser welding method to melt molybdenum-rhenium alloy wire, and the welding seam forms a molten pool; the laser welding laser power is 1600w, the spot diameter of the laser beam on the area to be welded is 0.8mm, and the welding speed is 1.2 m / min.

[0060] 4) Simultaneously perform ultrasonic oscillation on the molten pool, the ultrasonic oscillation frequency is 40kHz, and the ultrasonic oscillation time is 25min, so that the rhenium element is evenly mixed into the molten pool;

...

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Abstract

The invention discloses a method for strengthening the welding performance of tungsten / molybdenum and an alloy thereof through rhenium. The method comprises the following steps that 1, the welding face of the tungsten / the molybdenum and the alloy thereof is fully ground and cleaned till the contact faces are flat and smooth; 2, a molybdenum-rhenium wire is selected and ground; 3, materials to be welded are in butt joint, a molybdenum-rhenium wire is wound around a welding seam, and the materials are placed in a vacuum or gas protection environment; 2, laser or plasma beam welding is carried out, and the welding seam is melted; 3, ultrasonic oscillation is synchronously carried out on the molten pool, so that rhenium element is doped into the molten pool; and 4, heat treatment is performed on the welded materials, and a furnace is cooled to room temperature to obtain a welded product. According to the method, the rhenium element is used for strengthening the performance of the tungsten / the molybdenum and the alloy of the tungsten / the molybdenum, and the welding performance is effectively regulated and controlled by controlling the content of the alloying element rhenium. Gain boundary impurities are reduced, and the binding force between alloy grains is increased, and the mechanical property of the tungsten / the molybdenum is enhanced.

Description

technical field [0001] The invention relates to welding of tungsten / molybdenum and its alloys, in particular to a method for strengthening the welding performance of tungsten / molybdenum and its alloys with rhenium element. Background technique [0002] Tungsten / molybdenum has a high melting point, good high-temperature mechanical properties, and excellent corrosion resistance and ablation resistance, but it is difficult to weld. On the one hand, the temperature of the molten pool is high during welding, and recrystallization easily occurs during welding and cooling, forming coarse grains. On the other hand, tungsten / molybdenum is very sensitive to gas impurities such as nitrogen and oxygen. During the welding process, the addition of gas impurities will form defects such as pores and increase low-temperature brittleness. In order to ensure the welding performance of tungsten / molybdenum, it is necessary to avoid the influence of air during welding. It should be carried out i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K26/28B23K26/60B23K35/24
CPCB23K26/28B23K26/60B23K35/24Y02P10/20
Inventor 孙院军宋坤朋张林杰丁向东曾毅孙军孙博宇
Owner XI AN JIAOTONG UNIV