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Production process of high-melt-index polypropylene melt-blown material

A polypropylene melt-blown and production process technology, which is applied in the production process of high-melt polypropylene melt-blown materials, can solve problems such as process instability, non-woven odor, additive loss, etc., and achieve good melt fluidity, No odor and yellowing, and the effect of stabilizing the degradation rate

Pending Publication Date: 2022-01-18
HUNAN SHENGJIN NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the methods for preparing high melting point polypropylene are as follows: one is to control the molecular weight and molecular weight distribution of polypropylene by controlling the polymerization process, such as reducing the molecular weight of the polymer by increasing the concentration of a polymerization inhibitor such as hydrogen, thereby increasing the melt index. However, this method is limited by the catalytic system, reaction conditions and other factors, and the stability of the melt index is difficult to control; the second is to control the degradation of polypropylene obtained by conventional polymerization, reduce its molecular weight, and increase the melt index. In the past, high-temperature degradation methods were commonly used To reduce the molecular weight of polypropylene, but this high-temperature mechanical degradation method has many disadvantages, such as additive loss, thermal decomposition, process instability and other unfavorable factors. In addition, there are methods such as ultrasonic degradation, but these methods often require the presence of solvents , which increases the difficulty and cost of the process, and the chemical degradation method widely used in recent years is to make polypropylene and chemical degradation agents such as organic peroxides react in the screw extruder, but peroxides can degrade low-melting It means that the polypropylene process is too late to degrade 100%, the degradation reaction cannot be completely completed, and the residual peroxide will stay in the high-melt polypropylene raw material, resulting in non-woven fabric odor, yellowing, unstable performance, and affecting non-woven fabrics. quality

Method used

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  • Production process of high-melt-index polypropylene melt-blown material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A production process for high melting point polypropylene melt-blown material, comprising the following steps:

[0023] a) Mix the polypropylene powder with the peroxide composite degradation agent, the amount of the polypropylene powder and the peroxide composite degradation agent added is calculated in parts by mass: 80 parts and 5 parts of the polypropylene powder, and the peroxide composite degradation The agent is mixed with dicumyl peroxide and phenol hydroxylase, the mass ratio of the dicumyl peroxide and phenol hydroxylase is 12:1, added in the twin-screw extruder, then added additives and mixed evenly, Additives are high temperature resistant stabilizer and lubricant, in parts by mass: 5 parts of high temperature resistant stabilizer, 2 parts of lubricant, react in the screw reaction section of twin-screw extruder, carry out melt extrusion, melting temperature is 270 ℃, and at the end of the screw of the twin-screw extruder, add a long-acting stabilizer and a s...

Embodiment 2

[0026] A production process for high melting point polypropylene melt-blown material, comprising the following steps:

[0027] a) Mix the polypropylene powder with the peroxide composite degradation agent, the amount of the polypropylene powder and the peroxide composite degradation agent added is calculated in parts by mass: 50 parts and 2 parts of the polypropylene powder, and the peroxide composite degradation agent The agent is mixed with dicumyl peroxide and phenol hydroxylase, the mass ratio of the dicumyl peroxide and phenol hydroxylase is 10:1, added in the twin-screw extruder, then added additives and mixed evenly, The additives are high temperature resistant stabilizer and lubricant, in parts by mass: 2 parts of high temperature resistant stabilizer and 1 part of lubricant, react in the screw reaction section of the twin-screw extruder, and carry out melt extrusion with a melting temperature of 250 ℃, and at the end of the screw of the twin-screw extruder, add a long...

Embodiment 3

[0030] A production process for high melting point polypropylene melt-blown material, comprising the following steps:

[0031] a) Mix the polypropylene powder with the peroxide composite degradation agent, the amount of the polypropylene powder and the peroxide composite degradation agent added is calculated in parts by mass: 100 parts and 10 parts of the polypropylene powder, and the peroxide composite degradation The agent is mixed with dicumyl peroxide and phenol hydroxylase, the mass ratio of the dicumyl peroxide and phenol hydroxylase is 15:1, added in the twin-screw extruder, then added additives and mixed evenly, Additives are high temperature resistant stabilizer and lubricant, in parts by mass: 4 parts of high temperature resistant stabilizer, 3 parts of lubricant, react in the screw reaction section of twin-screw extruder, carry out melt extrusion, melting temperature is 260 ℃, and at the end of the screw of the twin-screw extruder, add a long-acting stabilizer and a...

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Abstract

The invention discloses a production process of a high-melt-index polypropylene melt-blown material, and belongs to the technical field of respiratory protection material production. The production process comprises the following steps of mixing polypropylene powder and a peroxide composite degradation agent, adding into a twin-screw extruder, adding an additive, uniformly mixing, reacting in a screw reaction section of the twin-screw extruder, carrying out melt extrusion, and adding a long-acting stabilizer and a short-acting stabilizer at the tail end of a screw of the twin-screw extruder to obtain a material; and conveying the obtained material to a cooling water tank for cooling through an inclined water tank, air-drying through an air dryer, granulating in a granulator, and screening through a vibrating screen, so as to obtain the high-melt-index polypropylene melt-blown material. The high-melt-index polypropylene is obtained through a composite degradation method, no degradation agent is left in the melt-blowing production process, and the produced non-woven fabric is free of peculiar smell and yellowing.

Description

technical field [0001] The invention belongs to the technical field of respiratory protection material production, and in particular relates to a production process of high melting point polypropylene meltblown material. Background technique [0002] In recent years, with the rampant spread of respiratory infectious viruses (such as Ebola virus, SARS virus, etc.), public health issues have received attention from all walks of life. Especially in 2020, the new coronavirus spreads globally, posing a huge threat to human life. Medical masks and protective clothing have become important protective equipment to prevent the spread of the virus and protect the health of the population. The medical mask is composed of three layers of non-woven fabric, the finish and inner layer are made of spun-bonded non-woven fabric, the middle layer is made of melt-blown non-woven fabric, and polypropylene melt-blown material is used as the main material of melt-blown non-woven fabric The raw ma...

Claims

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Application Information

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IPC IPC(8): B29B9/06C08L23/12C08L79/00C08K5/14
CPCB29B9/06C08L23/12C08L79/00C08K5/14
Inventor 袁文陈邵安龚宇峰
Owner HUNAN SHENGJIN NEW MATERIAL
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