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Optical adhesive for explosion-proof membrane and preparation method thereof

An adhesive and explosion-proof film technology, applied in the direction of adhesives, non-polymer adhesive additives, non-polymer organic compound adhesives, etc. Swelling and other problems, to achieve the effect of improving mechanical and mechanical properties and performance stability, good bonding performance, and good bonding performance

Active Publication Date: 2022-03-01
江西塔益莱高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its performance stability is not good. During long-term use, it is still prone to defects such as swelling of the adhesive layer, decrease in mechanical properties and light transmittance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] An optical adhesive for an explosion-proof film, characterized in that it comprises the following components in parts by weight: 80 parts of acrylate adhesive, 10 parts of rosin modified silicone resin, isocyanoethyl methacrylate 3 parts, 2-[3-(2H-benzotriazol-2-yl)-4-hydroxyphenyl]ethyl 2-methacrylate 3 parts, 7-fluoro-5-oxo-8-( 1 part of 4-(2-propenyl)-1-piperazinyl)-5H-thiazolo[3,2-a]quinoline-4-carboxylic acid, 0.3 part of diallyl sulfide, 10 parts of solvent, 0.6 parts of photoinitiator, 0.1 part of allyltrimethoxysilane, and 0.1 part of organic bismuth catalyst. The solvent is ethyl acetate; the photoinitiator is benzoin dimethyl ether.

[0021] A method for preparing the optical adhesive for the explosion-proof film, characterized in that it comprises the following steps: mixing the components by weight, keeping at 45°C and stirring for 1 hour, vacuuming and removing air bubbles, and obtaining the explosion-proof film after cooling Finished Optical Adhesives. ...

Embodiment 2

[0023] An optical adhesive for an explosion-proof film, characterized in that it comprises the following components in parts by weight: 85 parts of acrylate adhesive, 12 parts of rosin modified silicone resin, isocyanoethyl methacrylate 3.5 parts, 2-[3-(2H-benzotriazol-2-yl)-4-hydroxyphenyl]ethyl 2-methacrylate 4 parts, 7-fluoro-5-oxo-8-( 1.5 parts of 4-(2-propenyl)-1-piperazinyl)-5H-thiazolo[3,2-a]quinoline-4-carboxylic acid, 0.35 parts of diallyl sulfide, 12 parts of solvent, 0.65 parts of photoinitiator, 0.15 parts of allyltrimethoxysilane, and 0.15 parts of organic bismuth catalyst. The solvent is toluene; the photoinitiator is benzoin ethyl ether.

[0024] A preparation method of the optical adhesive for the explosion-proof film, characterized in that it comprises the following steps: mixing the components by weight, keeping at 50°C and stirring for 1.2h, vacuuming to remove air bubbles, and obtaining the explosion-proof film after cooling Finished with optical adhesive...

Embodiment 3

[0026] An optical adhesive for an explosion-proof film, characterized in that it comprises the following components in parts by weight: 90 parts of acrylate adhesive, 15 parts of rosin modified silicone resin, isocyanoethyl methacrylate 4 parts, 2-[3-(2H-benzotriazol-2-yl)-4-hydroxyphenyl] ethyl 2-methacrylate 4.5 parts, 7-fluoro-5-oxo-8-( 2 parts of 4-(2-propenyl)-1-piperazinyl)-5H-thiazolo[3,2-a]quinoline-4-carboxylic acid, 0.4 parts of diallyl sulfide, 13 parts of solvent, 0.7 parts of photoinitiator, 0.2 parts of allyltrimethoxysilane, and 0.2 parts of organic bismuth catalyst. The solvent is methyl ethyl ketone; the photoinitiator is benzoin isopropyl ether.

[0027] A preparation method of the optical adhesive for the explosion-proof film, characterized in that it comprises the following steps: mixing the components by weight, keeping at 55°C and stirring for 1.5 hours, vacuuming to remove air bubbles, and obtaining the explosion-proof film after cooling Finished with ...

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Abstract

The invention discloses an optical adhesive for an explosion-proof membrane. The adhesive is prepared from the following components in parts by weight: 80 to 100 parts of acrylate adhesive, 10 to 20 parts of rosin modified organic silicon resin, 3 to 5 parts of isocyano ethyl methacrylate, 3 to 6 parts of 2-[3-(2H-benzotriazole-2-yl)-4-hydroxyphenyl] ethyl 2-methacrylate, 7-fluoro-5-oxo-8-(4-(2-allyl)-1-piperazinyl)-5H-thiazolo [3, 2-b] pyrimidine-2-ketone, 3 to 6 parts of 2-(2-fluorophenyl)-2-(4-fluorophenyl)-1-piperazinyl]-1, 2, 3-triazole-2-yl)-4-(2-fluorophenyl)-1, 2, 3-triazole-2-yl)-1, 2, 3-triazole-2-yl) The invention relates to a photocurable coating which is prepared from the following components in parts by weight: 1 to 3 parts of 2, 2-a] quinoline-4-carboxylic acid, 0.3 to 0.5 part of diallyl sulfide, 10 to 15 parts of solvent, 0.6 to 0.8 part of photoinitiator, 0.1 to 0.3 part of allyl trimethoxy silane and 0.1 to 0.3 part of organic bismuth catalyst. The invention also discloses a preparation method of the optical adhesive for the explosion-proof membrane. The optical adhesive for the explosion-proof membrane, disclosed by the invention, is good in adhesive property, aging resistance, yellowing resistance, performance stability and mechanical property and long in service life.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to an optical adhesive for an explosion-proof film and a preparation method thereof. Background technique [0002] Explosion-proof film is widely used in the fields of automobiles, photovoltaics, and electronic equipment because it can prevent glass from splashing and improve safety when the glass cover plate is broken. Rupture films typically include a hardcoat / substrate / adhesive layer structure. The adhesive layer is usually made of optical adhesive, and its performance directly affects the explosion-proof effect, safety and service life of the explosion-proof membrane. [0003] The existing optical adhesives for explosion-proof membranes have the advantages of high light transmittance, low haze, UV resistance, high adhesion, high temperature resistance, and no yellowing after long-term use. The market application potential is expected to become the "new darling" of the film c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J4/06C09J4/02C09J11/06
CPCC09J4/06C09J11/06Y02E60/10
Inventor 金勇彪蒋明杰胡开许
Owner 江西塔益莱高分子材料有限公司
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