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Coking wastewater advanced treatment composite reagent and application thereof

A technology for coking wastewater and advanced treatment, which is applied in water/sewage treatment, natural water treatment, water/sewage multi-stage treatment, etc. It can solve the problems of membrane system pollution, restricting the application of membrane separation technology, and high pollution of coking wastewater. Achieve the effect of reducing suspended solids, COD and turbidity stabilization, and improving the phenomenon of membrane fouling

Pending Publication Date: 2022-03-08
CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high pollution of coking wastewater, the membrane system is seriously polluted, which seriously restricts the application of membrane separation technology in the field of coking wastewater treatment.

Method used

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  • Coking wastewater advanced treatment composite reagent and application thereof
  • Coking wastewater advanced treatment composite reagent and application thereof
  • Coking wastewater advanced treatment composite reagent and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] (1) Configuration of composite drugs:

[0035] Decarbon softener: mixed from powder activated carbon with the quality ratio of 1.5: 1;

[0036] Combined concrete: Aluminum chloride and polymeric sulfate is mixed according to the mass ratio of 30: 1.

[0037] (II) Application: This implementation case is the implementation of engineering directly, and the dicycle water is sequentially entered into a decarbon-carbon softener contact reaction unit, a combination of a coagulant reaction unit, a flocculation unit, a sludge precipitation unit, and a pool. Among them, the residence time of the decarbon softener contact reaction unit is 0.45 h, the residence time of the combined concrete reaction unit is 0.15 h, the residence time of the flocculation unit and the sludge precipitation unit is 0.25 h and 0.85 h, respectively.

[0038] The decarbon softener investment is 600 mg / L, the combined concrete dosage is 420 mg / L, the anionic polyacrylamide (PAM-) is 1.2 mg / L, the formed...

Embodiment 2

[0043] (1) Configuration of composite drugs:

[0044] Decarbon softener: mixed from powder activated carbon with cooked lime in accordance with 1: 1 mass ratio;

[0045] Combined concrete: Based on the mass ratio of polymerized chloride and polymer sulfate according to 6: 1.

[0046] (II) Application: This implementation case is the implementation of engineering directly, and the dicycle water is sequentially entered into a decarbon-carbon softener contact reaction unit, a combination of a coagulant reaction unit, a flocculation unit, a sludge precipitation unit, and a pool. Among them, the residence time of the decarbon softening agent in contact reaction unit is 0.4 h, the residence time of the combined concrete reaction unit is 0.15 h, the residence time of the flocculation unit and the sludge precipitate unit is 0.25 h and 0.85 h, respectively.

[0047] The decarbel softener investment is 1200 mg / L, the combined concrete dosage is 1200 mg / L, the anionic polyacrylamide (PAM-)...

Embodiment 3

[0052] (1) Configuration of composite drugs:

[0053] Decarbon softener: mixed by powder activated carbon with the quality ratio of 5: 1;

[0054] Combined concrete: Based on polymerized aluminum chloride and polymeric sulfate in accordance with the mass ratio of 50: 1.

[0055] (II) Application: This implementation case is the implementation of engineering directly, and the dicycle water is sequentially entered into a decarbon-carbon softener contact reaction unit, a combination of a coagulant reaction unit, a flocculation unit, a sludge precipitation unit, and a pool. Among them, the residence time of the decarbon softener contact reaction unit is 2 h, the residence time of the combined concrete reaction unit is 0.5 h, the residence time of the flocculation unit and the sludge precipitate unit is 0.25 h and 0.85 h, respectively.

[0056] The decarbon softener investment is 800 mg / L, the combined concrete dosage is 960 mg / L, the anionic polyacrylamide (PAM-) investment is 1.2...

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Abstract

The invention provides a composite reagent for advanced treatment of coking wastewater. The composite reagent comprises a decarburization softener and a combined coagulant. Wherein the decarburization softening agent is formed by mixing powdered activated carbon and slaked lime according to the mass ratio of (1-5): 1, and the combined coagulant is formed by mixing aluminum salt and ferric salt according to the mass ratio of (6-50): 1. When the composite agent is used for treating the coking wastewater, the synergistic effect of the decarburization softener and the combined coagulant can be exerted, a better flocculation effect is obtained on the premise of low agent proportioning amount, and the stability of COD and turbidity of effluent is ensured. When the composite agent is used for treating the coking wastewater membrane system front-end inlet water, the water quality can reach the following indexes: the COD is stably less than 100mg / L, the hardness is stably less than 100mg / L, and the turbidity is stably less than 1NTU. Besides, the actual operation condition of engineering shows that the membrane pollution and blockage phenomenon is obviously improved, the membrane pollution cleaning period is prolonged to more than 3 months, the cleaning frequency is reduced by 90%, the service life of a membrane system is prolonged, and the operation cost of the membrane system is reduced.

Description

Technical field [0001] The present invention belongs to the technical field of industrial wastewater treatment, and in particular to a coking wastewater depth treatment composite agent and its application thereof. Background technique [0002] Coking wastewater is a complicated, poisonous, poisonous toxicity, poor canxicity, poor water quality fluctuations, high-concentration phenolic, heterocyclic compound, polycyclic compound, etc., etc. , High-amamine nitrogen industrial wastewater. With the increasing importance of the country's water resources in the coking industry, the increase in coking wastewater has become a key link to prevent depth resource utilization of wastewater in steel coke joint enterprises. [0003] In recent years, with the continuous development of membrane separation technology and the continuous development of manufacturing, membrane separation technology has been widely used in seawater, food processing, urban water supply and urban sewage, and so on. Sep...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F103/34
CPCC02F9/00C02F1/283C02F1/5236C02F1/441C02F1/444C02F1/56C02F5/06C02F2103/34
Inventor 冯驰孙勇高智荣吴朝阳龚浩陈涛胡正茂张春杰
Owner CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY