921 results about "Coke wastewater" patented technology

The invention discloses a method for treating coking wastewater, which relates to the method for treating wastewater and aims to solve the problems that an activated sludge method for treating the coking wastewater has the disadvantage of relatively poorer effect on the removal of organic substances and the treated water is difficult to reach the secondary discharge standard of the Integrated Wastewater Discharge Standard (GB8978-96). The method comprises that: the coking wastewater is discharged after passing through an oil separation tank, an adjusting tank, an iron carbon-Fenton oxidation pond, an up-flow anaerobic sludge bed reactor, a multifunctional hydrolyzing pond, an anaerobic tank, a composite active sludge tank and a secondary sedimentation tank, wherein the coking wastewater can also pass through a floatation tank. The coking wastewater treated by the method of the invention has a pH value of 5 to 8 and the rate of removal of Cu2+ from the coking wastewater of 69 to 85 percent, contains 300 to 450mg/L phenol and less than 15mg/L cyanide and therefore reaches the secondary discharge standard of the Integrated Wastewater Discharge Standard (GB8978-96).

The invention discloses a rhodococcus erythropolis (rhodococcus sp.) BZ-9 which is preserved in the China General Microbiological Culture Collection Center with the accession number of CGMCC No.3695. The invention also discloses a microbial inoculum, the active component of which is the rhodococcus erythropolis BZ-9. The rhodococcus erythropolis BZ-9 and the microbial inoculum thereof have high-efficient degradation performance on various toxic organic substances as well as high degradation ability even under the condition of chromium (VI), and are applicable to treatment on coking wastewater, tanning wastewater, printing and dying wastewater and other organic wastewater containing phenol, pyridine and other toxic organic substances produced in the process of the production of the petrochemical industry.

The invention relates to a process by adopting supercritical water oxidation technology to treat coking wastewater or organic wastewater. The invention is that: coking wastewater or organic wastewater is pretreated to obtain wastewater without solid granules; the wastewater is heated to 380-450 DEG C with a first interchanger and/or a supercritical boiler, and then enters demineralizing equipment to remove the salt in the wastewater by taking advantage of the property that supercritical inorganic matter is indissoluble; the wastewater after desalting is put in a reaction kettle to generate autothermal reaction with an heated and pressurized oxidant to obtain high-temperature gas-liquid mixture with higher temperature; the high-temperature gas-liquid mixture enters the first interchanger and acts as thermal medium to exchange heat with new coming coking wastewater or organic wastewater and then goes through a secondary interchanger to enter a cooler and is cooled to normal temperature, after pressure thereof is adjusted by a pressure regulation device, the high-temperature gas-liquid mixture enters a gas-liquid separator for separation, and then the air is discharged, while the liquid, namely the treated water is recycled. The organic contamination and oxidant are all dissolved in the wastewater; oxidation reaction is generated in homogeneous phase, in short reaction time, oxygenolysis of organic contamination is carried out quickly.

The invention discloses a technique of biological treatment for coking wastewater. The filter chamber is composed of a preprocessing part, a biological treatment part and a physical treatment part, wherein the biological treatment part is composed of an anaerobic ceramsite filter chamber, an anoxia ceramsite filter chamber and an aerobic ceramsite filter chamber which are connected in series, spherical ceramsite filtering materials or irregular-shape ceramsite filtering materials are all filled in the anaerobic ceramsite filter chamber, the anoxia ceramsite filter chamber and the aerobic ceramsite filter chamber as biofilm culturing filling and filtrating precoats, the anaerobic ceramsite filter chamber employs an internal reflux mode, a reversed flow mode is employed between the anoxia ceramsite filter chamber and the aerobic ceramsite filter chamber, the precoats in the filter chambers are respectively formed by ceramsite filtering materials with different thickness, the filter chambers employs backwash to exclude accumulated sludge and suspended substance in the filter chambers into flotation tanks of the preprocessing part, the anaerobic ceramsite filter chamber, an anoxia ceramsite filter chamber employs regular water scrubbing to drive macro-gas-bubble in the chambers. Compared with the prior art, the technique has the advantages of prolonging sluicing periodic time, stabilizing operational effect, improving treatment loading, thereby reducing retention time of waterpower, decreasing accommodation area and investment of pile plant.

The utility model discloses a technology for treating coking wastewater by using a novel feeding activated sludge method, which comprises the following steps: biochemical treatment process is carried out on the pretreated wastewater, the coking wastewater first enters an A-grade biochemical pond to provide carbon sources for denitrification, and then the coking wastewater enters a 0-grade biochemical pond for carrying out oxidation and nitration under aerobic environment, the effluent water of the 0-grade biochemical pond enters a secondary sedimentation tank; the supernatant from the secondary sedimentation tank enters a subsequent-stage treatment system and one part of settling sludge refluxes and enters the A-grade biochemical pond and 0-grade biochemical pond; the other part of the settling sludge enters a sludge thickener. As flocculants are added into the biochemical pond, the ability of tolerating loads is greatly improved, and shock resistance is also greatly enhanced; the area of the biochemical reaction pond is reduced to 70 percent of the area of the reaction pond of traditional feeding activated sludge method, so investment costs are saved and operation costs are decreased; while the decolorizing ratio of the technology to coking wastewater, black liquor and chloromycetin wastewater can reach to more than 80 percent.

The invention discloses a method for treating coking wastewater, which belongs to the field of wastewater treatment. The method comprises the following steps that: wastewater of a coking plant enters a regulating reservoir for the adjustment of water quality and water amount, and orderly enters a hydrolytic tank, an anaerobic tank, a preaeration tank, a preliminary sedimentation tank, an aerobic tank, a secondary sedimentation tank and a coagulation reaction tank for treatment, wherein the hydrolytic tank and the preaeration tank are filled with a bio-cord filler; the sludge of the preliminary sedimentation tank refluxes into the hydrolytic tank and the anaerobic tank respectively; a clarifying solution of the secondary sedimentation tank refluxes into the anaerobic tank; and the aerobic tank adopts a moving bed bio-film reactor. The bio-cord filler adopted in the invention has short film formation time and high biomass, does not need repeated washing, and has strong shock resistance; and the moving bed bio-film reactor can fix a large amount of nitrobacteria with long generation time, and has no the problem of blocking. The method can remove high-concentration ammonia nitrogen and organic substances in the coking wastewater, and the COD and the ammonia nitrogen of treated effluent can synchronously achieve the primary standard of the national integrated wastewater discharge standard (GB9878-1996).

The invention relates to a biofilm full-rang autotrophic nitrogen removal device of digested sludge dehydrolysis liquid and a method thereof; wherein, the device is provided with a digested sludge dehydrolysis liquid pool, a pre-hypoxia denitrification pool, a short-range biofilm nitrification pool, a sedimentation pool, an intermediate pool and a biofilm anaerobic ammonia oxidation pool; the method consists of the following steps: 1. the pre-hypoxia denitrification pool and the short-range biofilm nitrification pool are started to operate; 2. the biofilm anaerobic ammonia oxidation pool is started; 3. the biofilm full-rang autotrophic nitrogen removal system of the digested sludge dehydrolysis liquid is operated in series. The device is suitable for biological nitrogen removal of wastewater containing high ammonia nitrogen, such as the digested sludge dehydrolysis liquid, late landfill percolate, coking wastewater, monosodium glutamate wastewater, etc. The device realizes efficient biological nitrogen removal of wastewater with high NH4<+>-N and low ratio of C/N, greatly decreases the construction and operation cost of nitrogen removal of wastewater, reduces alkalinity demand of the nitrification, runs stably, operates easily and has stronger shock resistance loading capability; meanwhile, the device is strongly adaptable to temperature fluctuation and toxic substances, which is easy to recover after being restrained.

The invention discloses a coking wastewater deep treatment and reuse process and equipment thereof, belonging to the technical field of environmental protection, and the main steps are as follows: dosing a coagulant in biochemical treatment water, then leading the biochemical treatment water to enter into a sedimentation tank, discharging sludge from a sludge hopper, leading treated water to enter into a three-dimensional electrode reactor, leading the outlet water after electro-oxidation treatment to enter into a biological filter tank, and leading the water after the treatment of the biological filter tank to enter into a follow-up ultrafiltration treatment; the ultrafiltration outlet water has two selections, one is to reuse the outlet water as the process water directly, the other one is to continuously pass through a reverse osmosis membrane system for treatment; and the coagulation and sedimentation tank, the process equipment of the three-dimensional electrode reactor, the biological filter tank, the ultrafiltration system and the reverse osmosis desalination system are adopted during the treatment process, thereby achieving the purposes of removing residual refractory organic matters, suspended impurities and salt in the waste water, reusing the outlet water, simultaneously leading the content of the organic matters in the reverse osmosis concentrated water not to exceed the national environmental protection standard, also reusing the concentrated water in occasions with less stringent requirements on the water quality and achieving the purpose of zero emission of the wastewater.

The invention discloses a device for deep treatment and complete recovery of coking wastewater and an application method thereof. The device comprises a pretreatment system and a biochemical treatment system and is characterized in that an outlet of coking wastewater after pretreatment and biochemical treatment is connected with a membrane bioreactor; the water outlet of the membrane bioreactor is connected with an oxidation treatment component; the water outlet of the oxidation treatment system is connected with a reverse osmosis membrane treatment component; one water outlet of the reverse osmosis membrane treatment component is connected with a concentrated water evaporation and crystallization system; and the other water outlet of the reverse osmosis membrane treatment component is connected with a recycling water tank. The invention combines the technologies of biochemical treatment, oxidation, membrane separation and evaporation for deep treatment of the coking wastewater and realizes zero emissions. Therefore, the device and the application method are a novel treatment device and a novel application method for degradation of various pollutants in the coking wastewater and complete recovery of water after treatment.

The invention belongs to the technical field of water treatment, and particularly relates to a coking wastewater membrane concentration salt separation zero-emission treatment system and a coking wastewater membrane concentration salt separation zero-emission treatment method. The method comprises: coking wastewater pretreatment, wherein the coking wastewater pretreatment comprises full-automaticsand filtration, active carbon adsorption regeneration, ultra-filtration and softening; membrane salt separation and concentration treatment, wherein the membrane salt separation and concentration treatment comprises low-pressure nano-filtration, high-pressure nano-filtration, purification nano-filtration and reverse osmosis treatment; and concentration treatment, fluorine and silicon removal, electrodialysis concentration and evaporative crystallization, wherein an industrial-grade sodium chloride product with a purity of more than 92% is obtained, a sodium sulfate concentrated solution enters a freezing crystallization device to generate mirabilite, the mirabilite is heated and melted and then enters an evaporation crystallization, centrifugation and drying system, and an industrial-grade sodium sulfate product with a purity of more than 95% is obtained. According to the invention, with the system and the method, the zero discharge of coking wastewater is achieved, and the process technology is an innovative coking wastewater zero discharge process at home and abroad.

The invention discloses a method for removing cyanides in coking wastewater, which effectively removes cyanides at various forms in wastewater mainly based on the oxidation of Fenton. The method also combines the adsorption of activated carbon and causes the concentration of the water to be lowered by the function of catalyzed oxidation available in the existence of hydrogen peroxide. The method has the advantages of low cost and can discharge water in accordance with the first grade discharge standard of China (less than 0.5mg/L).

The invention relates to a coking wastewater biological denitrificaion treatment process, belonging to the technical field of environmental protection and wastewater processing, which is characterized in that the biological denitrificaion treatment process with A/O/A/O, namely, anoxia/oxic/ anoxia/oxic as the core is adopted. The pretreated coking wastewater sequentially enters into a first-level anoxic tank, a first-level oxic tank, a reflow sedimentation tank, a second-level anoxic tank, a second-level oxic tank, a second-level sedimentation tank, short-range nitrification and denitrification biological denitrificaion treatment are carried out on the coking wastewater in the first-level anoxic tank and the first-level oxic tank, hydrolysis acidification and fine denitrification treatment are carried out on the coking wastewater in the second-level anoxic tank, and the second-level oxic tank realizes the full nitration reaction. The process method has stable operational effect, low operational cost, high denitrification percent, water-quality indexes such as CODCr, NH3-N and the like of water from the second-level sedimentation tank can simultaneously reach a first-level discharge standard in Integrated Wastewater Discharge Standard (GB8978-1996), and can be recycled and used by other users after advanced treatment, thus realizing the zero discharge of the coking wastewater.

The invention discloses a method for preparing an ozone catalytic oxidation catalyst for treating coking wastewater, which is characterized in that: amorphous alumina is taken as carrier powder; and in the rolling granulating process, active ingredients, namely vanadium, iron and manganese are sprayed in a solution mode and are granulated, cured, dried and roasted to prepare a finished product catalyst. The catalyst is mainly used for removing nonbiodegradable organic pollutants from the coking wastewater. The amorphous alumina is prepared by quickly dehydrating industrial aluminum hydroxide at a high temperature, and has the specific surface area of 150 to 350m<2>/g, the total pore volume of 0.20 to 0.45ml/g and the average particle size of 1 to 80mu m. The active ingredients, namely the iron and the manganese in the mode of nitrate and the vanadium in the mode of ammonium metavanadate are added with water to be prepared into solution, and the spray amount of the solution is 2 to 50 percent based on the total mass of the amorphous alumina. The load capacity of the active ingredients, namely the iron, the manganese and the vanadium is 0.1 to 20.0 weight percent based on the total mass of the amorphous alumina.

The invention discloses a deep purification method of coking wastewater based on advanced ozone oxidation, belonging to the field of wastewater treatment, and particularly relating to a deep purification method for the effluent of the biochemical treatment facilities of coking plants. Aiming at the problem in the prior art, the invention provides a method for coupling homogeneous catalysis and non-homogeneous catalysis for ozone so as to realize deep purification of the effluent of the biochemical treatment facilities of coking wastewater. In the deep purification method, wastewater of which the pH value is 8-12 is subjected to homogeneous catalysis reaction in the presence of ozone and hydrogen peroxide; non-homogeneous catalysis is carried out in the presence of the non-homogeneous catalyst; thus, processed effluent COD (Chemical Oxygen Demand) is less than 100mg/L; and thus the processed effluent does not cause secondary pollution to environment.

The invention discloses an advanced treatment method of biochemical tail water of coking wastewater. The method is characterized by regulating pH of the biochemical tail water of the coking wastewater in a regulation tank to 9-12 by alkaline matters, then adding high-efficiency oxidizing agent for oxidation treatment, precipitating and separating mixed solution, adsorbing filtrate; adsorbing trace organic matters in the wastewater on resin, reclaiming by water at normal temperature; COD of the wastewater reduces from 200mg/L to below 100mg/L after the treatment, chromaticity reduces from 100 folds to almost achromaticity, and other indexes meet Grade 1 standard of the national integrated sewage discharge standard.

The invention discloses an advanced treatment system of coking wastewater. The system mainly comprises an ozone generator, a catalytic ozonation reactor, a gas-liquid separation device, a bumper post, a biological activated carbon reactor and a tail gas absorption device, wherein the catalytic ozonation reactor has a three-section repeating structure; and each repeating structure section is divided to three subsections from bottom to top, namely an ozone absorption section, a catalyst bed layer and a catalytic reaction section. The three-section superimposing mode is utilized to intensify themass transfer function of ozone in the solution and increase the utilization rate of ozone; and the catalytic ozonation technology is adopted to increase the biochemical quality of coking wastewater,increase the treatment efficiency of the subsequent biological activated carbon technology and realize the aim of the high-efficiency advanced treatment of coking wastewater.

The invention discloses a process method for treating coking wastewater. The process method solves the technical problems that a micro-electrolysis method has hardening, channeling and narrow applicability of a pH range and a biochemical treatment process has long flow, large occupied area, poor impact load resistance and high expense. The method comprises a physical-chemical treatment unit consisting of a micro-electrolysis reactor and a settling tank; in the micro-electrolysis reactor, scrap iron, scrap copper and a lightweight blocky material are used as fillers; the pH of inlet water is between 2.0 and 6.0; the waterpower retention time is between 20 and 60 minutes; the method adopts air aeration; the method also comprises a filtering type inner circulating three-phase fluidized bed reactor biochemical treatment unit, and immobilized activated sludge balls are utilized to realize simultaneous denitrification and decarburization; the pH of inlet water is between 7.2 and 8.5; the concentration of dissolved oxygen is between 2 and 6mg/L; the temperature is between 28 and 32 DEG C; the waterpower retention time is between 20 and 40h; the COD of outlet water reaches secondary standard of integrated wastewater discharge standard; and volatile phenol, ammonia nitrogen and chroma reach primary standard of integrated wastewater discharge standard.

The invention provides an artificial wetland with combined fillers for the advanced treatment of the effluent coking wastewater of iron and steel enterprises, which sequentially comprises a water inlet area, a wetland processing unit area and a water outlet area, wherein the wetland processing unit area sequentially comprises a gravel filler section, an iron carbon filler section and a manganese sand filler section; and a soil covering layer and wetland plants are arranged on the surface of the wetland. By using iron carbon, manganese sand and gravels as combined fillers and using emerging plants (such as cattail, Scirpus tabernaemontani, Thalia dealbata, reed and the like) having large biomass, salinization resistance and high metal and organic substance adsorptive power as a composite plant bed, the invention forms a horizontal subsurface flow artificial wetland. Thus, when industrial waste water moves into the artificial wetland, pollutants can be removed on the basis of a series of physical, chemical and biological interaction among the fillers, plants and microorganisms. The process provided by the invention has high pollutant shock load resistance and good treatment effect. Besides, the outlet water is stable, and main indexes of the outlet water can meet the Reuse of Urban Recycling Water-Water Quality Standard for Industrial Uses (GB/T 19923-2005). Thus, the outlet water can be recycled as circulating cooling water for steel enterprises.

A method for treatment of coke wastewater, including (1) introducing wastewater into a regulating reservoir into which an acid liquor is added until the pH value of the wastewater ranges between about 5.5 and about 6.5; (2) introducing the wastewater into a three-dimensional electrode treatment device for electrolysis treatment; and (3) introducing the wastewater into a coagulation reaction tank into which an alkali liquor is added until the pH value of the wastewater ranges between 8 and 10, and as a coagulant polysilicate ferric magnesium is added into the wastewater for a hybrid reaction of between 5 and 15 mins; allowing the wastewater to flow into a sedimentation basin for plain sedimentation of between 4 and 6 hrs; and extracting a supernatant liquor to yield a processed effluent.

The invention relates to a heterotrophic nitrifying and aerobic denitrifying bacterium for efficient denitrification, and the culture and application of the heterotrophic nitrifying and aerobic denitrifying bacterium. The bacterium belongs to an acinetobacter species (Acinetobacter), with the name of Acinetobacter sp.Y1, the preservation registration number of CGMCC NO.6563, the preservation institution of China Microorganism Culture Preservation Management Council General Microbiological Center and the preservation time of September 14th, 2012. The bacterium is separated from activated sludge of coking wastewater, can not only quickly remove ammonia nitrogen, but also grow under the condition that nitrite and nitrate are taken as sole nitrogen sources, and effectively removes nitrite nitrogen and nitrate nitrogen, and can be applied to nitrogen-containing wastewater treatment.

The invention discloses a coking wastewater comprehensive treatment method comprising the following steps of: pre-treatment, biochemical treatment and deep treatment. The deep treatment step comprises sequential steps of filtering, ultra-filtering, carrying out resin adsorption, re-filtering, and carrying out reverse osmosis. With the adoption of a coking wastewater comprehensive treatment system of the coking wastewater comprehensive treatment method, the pre-treatment step adopts a de-oiling pond, an adjusting pond and an air floating pond, which are connected in sequence; the biochemical treatment step adopts a primary aeration pond, a primary settling pond, an oxygen-poor pond, an aerobic pond and a secondary settling pond, which are connected in sequence; and the deep treatment step adopts a multi-medium filter, an ultra-filtering device, a resin adsorption column and a reverse osmosis device. The coking wastewater comprehensive treatment method has the beneficial effects that the method is stable to operate and has a simple process and good treating effects.