250 results about "Coke wastewater" patented technology

The utility model relates to a silicon and fluorine removal device for a coking wastewater zero-discharge membrane high-power concentrated solution. The silicon and fluorine removal device comprises a deep silicon removal unit, an alternate fluorine removal precipitation unit and an accurate fluorine removal unit which are sequentially connected in series, the deep silicon removal unit comprises a silicon removal reaction tank and a silicon removal sedimentation tank which are connected in series, a silicon removal stirrer is arranged in the silicon removal reaction tank, and a first flocculant adding device and a first liquid alkali adding device are arranged on the silicon removal reaction tank; the alternate defluorination sedimentation unit comprises a defluorination sedimentation tank, a defluorination stirrer is arranged in the defluorination sedimentation tank, effluent of the defluorination sedimentation tank is conveyed into the defluorination sedimentation tank, and a first sulfuric acid adding device is arranged on a pipeline between the defluorination sedimentation tank and the defluorination sedimentation tank; the precise defluorination unit comprises a second-stage defluorination reaction tank and a second-stage defluorination clarification tank which are connected in series, a water inlet pipeline of the second-stage defluorination reaction tank is provided with a second flocculant adding device and a second sodium hydroxide adding device, and effluent of the defluorination sedimentation tank is fed into the second-stage defluorination reaction tank.

The invention discloses a biomass-inorganic-organic ternary composite flocculant and a preparation method and application thereof, and belongs to the field of coking wastewater treatment.The preparation method comprises the steps that chitosan serves as a substrate material, glutaraldehyde serves as a cross-linking agent, and polyferric sulfate (PFS) and chitosan are subjected to chemical cross-linking to generate an intermediate product PFS and chitosan composite particles; then potassium persulfate is used as an initiator, graft copolymerization of acrylamide and methacryloyloxyethyl trimethyl ammonium chloride is initiated through hydroxyl on the surface of PFS-chitosan, a cationic branched chain is introduced, and a final product is obtained. Through multi-component cooperation and structural design, the defects that a traditional flocculating agent is not thorough in demulsification, large in sludge amount, unstable in floc combination and the like in coking wastewater treatment are overcome, and the flocculating agent is particularly suitable for treating oil pollutants in coking wastewater.

The utility model provides a coking wastewater outlet device, which relates to the technical field of coking wastewater treatment and comprises a treatment barrel, a fixing ring, supporting legs, a box cover, a partition plate, a filter plate and a flocculant adding component. Liquid flocculants are added into the feeding pipe and enter the storage box, liquid in the storage box is finally discharged into the treatment barrel through the multiple sets of water outlet pipes under the action of the pump body, the motor drives the rotating shaft and the driving wheel to rotate, the driven wheel and the feeding pipe are further driven to rotate, and the liquid flocculants are discharged into the treatment barrel through the multiple sets of water outlet pipes. A plurality of groups of water outlet pipes rotate along with the rotation of the fixed pipe, so that a liquid flocculant is uniformly sprayed out in the treatment barrel, and a scraper plate continuously cleans the outer surface of a filter plate along with the rotation of the fixed pipe, so as to keep the filter plate unobstructed. And the filter screen is not provided with an effective cleaning mechanism, so that the phenomenon of blockage is easily caused.

The invention discloses a method for preparing a porous carbon material by recycling coal gasification slag and semi-coke wastewater, which comprises the following steps: by taking coal gasification fine slag as a carrier and semi-coke wastewater as a phenol source, carrying out flotation-acid leaching modification on the fine slag to purify a carbon-rich component and optimize the surface adsorption activity of the carbon-rich component; then fully adsorbing phenolic substances in the wastewater by utilizing the modified slag body; introducing a composite aldehyde cross-linking agent, and initiating an in-situ phenolic aldehyde polymerization reaction to generate a composite precursor; the precursor is subjected to high-temperature carbonization and alkali activation pore forming, and finally the porous carbon material with the characteristics of high specific surface area, rich graded pores and low ash content is prepared. According to the process, full-amount collaborative recycling of the two wastes is achieved, and the process is green and free of secondary pollution. The obtained material is high in carbon content and rich in defect structure and surface functional groups, shows excellent adsorption capacity and catalytic carrier performance, can be widely applied to the fields of deep purification of water pollutants, adsorption of volatile organic compounds, energy catalysis and the like, and has remarkable environmental protection benefits and resource economic values.

The invention relates to a high-efficiency phenol degrading bacterium with an aerobic denitrification characteristic and application thereof, and belongs to the technical field of coking wastewater treatment and microorganisms. The strain is preserved in the China Center for Type Culture Collection, the preservation number is CCTCC NO: M20242868, and the preservation time is December 20, 2024. The strain can grow and breed by taking phenol as a unique carbon source, complete degradation of 1250mg / L phenol is realized, and phenol with the concentration range of 1000mg / L can be rapidly degraded within 36 hours. The strain PD-1 can also realize efficient and synchronous removal of phenol and a nitrogen source under the condition that NH4 < + >-N, NO2 <->-N or NO3 <->-N is used as the only nitrogen source. The strain PD-1 provided by the invention can quickly degrade high-concentration phenol in a water body, has the advantages of high efficiency, low energy consumption and no secondary pollution, and has important theoretical and application values.

The invention relates to the field of environmental engineering and technology, and discloses a coprocessing method for coking wastewater based on MBR (membrane bioreactor) technology, which sequentially comprises the steps of pretreatment, biological enhancement treatment, nitrogen and phosphorus removal treatment, sludge regulation and control treatment, membrane pollution control treatment and circular treatment, and comprises the following steps: introducing coking wastewater into a grating and a grit chamber; performing pretreatment to remove large-particle impurities; in the biological enhancement and nitrogen and phosphorus removal stage, a microbial agent is added to regulate and control the reaction environment so as to improve the pollutant degradation efficiency; accurate management and control of sludge performance and membrane pollution are realized by using an online monitoring technology; finally, sludge, cleaning wastewater and the like generated in all links are collected in a classified mode, the sludge is subjected to resource utilization after stabilization treatment, the cleaning wastewater is reused in the pretreatment stage, and a closed-loop treatment system is formed; through the steps, the problems of incomplete removal of COD (Chemical Oxygen Demand) and ammonia nitrogen, low removal rate of total nitrogen and total phosphorus, sludge bulking, fast membrane pollution and high risk of secondary pollution in the traditional process are effectively solved.

The utility model relates to the technical field of water treatment, in particular to a coking wastewater treatment system which comprises an electrocatalytic oxidation unit, and a nanofiltration unit, a reverse osmosis unit, a fluorine and silicon removal unit and an evaporative crystallization unit which are connected in sequence, the electrocatalytic oxidation unit is connected with the nanofiltration unit and the evaporative crystallization unit so as to respectively receive nanofiltration concentrated water and evaporative crystallization mother liquor, and the electrocatalytic oxidation unit is used for carrying out electrocatalytic oxidation treatment on the nanofiltration concentrated water and the evaporative crystallization mother liquor; and an anode of the electrocatalytic oxidation unit adopts a boron-doped diamond electrode. By adopting the boron-doped diamond electrode as the anode of the electrocatalytic oxidation unit, electrocatalytic oxidation treatment can be directly carried out on the nanofiltration concentrated water and the evaporative crystallization mother liquor, enrichment of the nanofiltration concentrated liquor and the evaporative crystallization mother liquor is avoided, the purity of industrial salt is improved, meanwhile, the treatment cost of the mother liquor as hazardous waste is avoided, and the salt recovery cost is reduced.

The utility model belongs to the technical field of industrial wastewater treatment, and particularly relates to a coking wastewater treatment system for industrial continuous production. Comprising a decomposition bin which comprises a moisture evaporation bin, an ammonia decomposition bin, a horizontal transmission belt penetrating through the moisture evaporation bin and the ammonia decomposition bin, a sedimentation tank, a filter connected to an outlet of the sedimentation tank, and a buffer bin connected to an outlet of the filter. The coking wastewater generates struvite in the sedimentation tank, redundant water is filtered out in the filter, and the struvite is stored in the surge bin and then sent to the decomposition bin. The ammonia gas enters the water evaporation bin through the horizontal conveying belt to evaporate redundant water, and then is fed into the ammonia gas decomposition bin to be thermally decomposed to release ammonia gas. The buffer bin can enable intermittent work of the filter not to affect continuous production of the system, the decomposition bin can achieve continuous evaporation dehydration and thermal decomposition processes, the wastewater treatment efficiency is improved, meanwhile, struvite decomposition products are reused in wastewater treatment, cyclic utilization of resources is achieved, and the energy consumption is reduced. The method has good economic benefits and environmental benefits.

The invention relates to the field of coal chemical industry, the field of environmental engineering and the technical field of sewage treatment, in particular to a biochemical treatment process for coal chemical industry wastewater, which comprises a cascade physicochemical treatment unit, a phenol ammonia recovery unit, a biochemical enhanced treatment unit and a deep treatment unit which are connected in sequence, the cascade physicochemical treatment unit is used for three-stage gradient oil removal; the phenol-ammonia recovery unit is used for removing phenol and ammonia and recovering resources; the biochemical enhanced treatment unit is used for efficiently degrading organic matters and removing nitrogen; the deep treatment unit is used for removing refractory pollutants and hardness and fluorine ions; through system integration and synergistic effects of four process units of cascade physicochemical treatment, phenol ammonia recovery, biochemical enhanced treatment and deep treatment, the whole-process efficient purification capacity for the coal chemical wastewater (such as semi-coke wastewater) is formed.

The utility model relates to the technical field of wastewater treatment, in particular to a high-efficiency defoaming device for coal coking wastewater treatment, and aims to solve the technical problem of poor defoaming effect caused by difficulty in uniformly covering a sedimentation tank with a larger area during feeding. The threaded shaft is in threaded connection with a scraping plate, the scraping plate is slidably connected to the sliding rail, the upper portions of the two sliding ends of the scraping plate are each provided with a corresponding defoaming mechanism, the defoaming mechanisms are connected to the side wall of the sedimentation tank, the defoaming mechanisms can add a defoaming agent to the lower portion, and foam is scraped to the two sides of the sedimentation tank through the scraping plate moving back and forth in the sedimentation tank; the defoaming mechanisms located on the upper portions of the two sides of the sedimentation tank add defoaming agents downwards to eliminate foams, so that all the foams can be covered without even adding, compared with full-tank adding, the agent consumption can be reduced, and the scraper advances on the liquid level of the upper portion of the sedimentation tank, and precipitation on the lower portion cannot be affected.

This invention provides a semi-coke wastewater treatment device and process. The semi-coke wastewater treatment device comprises, in sequence, a semi-coke production wastewater conditioning system, an electrolytic flotation system, a freeze crystallization system, a salt phase conditioning system, a high-temperature wet oxidation system, and an ammonia nitrogen stripping and distillation system. The freeze crystallization system is connected to an aqueous phase conditioning system, a BDD electro-oxidation system, and a biochemical system. The ammonia nitrogen stripping and distillation system is connected to the biochemical system. This invention effectively solves a series of technical problems in existing semi-coke wastewater treatment devices, such as lengthy process flows, high equipment investment and operating energy consumption, and clogging of the ammonia stripping and phenol removal unit due to phenol polymerization and coking, and oil adhesion. This invention also provides a semi-coke wastewater treatment process.

The utility model relates to a catalytic ozonation tower for advanced treatment of coking wastewater, which comprises an upper tower section and a lower tower section, the top of the lower tower section is detachably communicated with the bottom of the upper tower section, a plurality of partition plates are vertically distributed in the lower tower section at intervals, one end of each partition plate is fixedly connected with the inner side wall of the lower tower section, and a gap is reserved between the other end of each partition plate and the inner side wall of the lower tower section. The fixed ends of every two adjacent partition plates are opposite, an ozone channel is arranged in the fixed end of each partition plate, air inlet pipes are arranged on the left outer side and the right outer side of the lower tower section, the two air inlet pipes are communicated through a conveying pipeline, one end of each ozone channel is communicated with the adjacent air inlet pipe through an air inlet branch pipe, and the other end of each ozone channel is communicated with an aeration head fixedly arranged at the bottom of the corresponding partition plate. Two mesh plates are distributed between the aeration head and the free end of the corresponding partition plate, a catalyst is filled between the two mesh plates, and the bottom of the lower tower section corresponding to the fixed end of the lowermost partition plate is communicated with a water inlet pipe. According to the utility model, multiple aeration mixing and catalytic oxidation of wastewater can be realized, and the overall treatment quality is higher.

The present application relates to a kind of coking wastewater advanced treatment method and system, method includes: the water quality characteristics of coking wastewater are pre-configured with modified polyurethane suspended filler, modified anode electrode and modified fly ash filler;Coking wastewater is sent into biochemical pool and carries out biochemical reaction, and modified polyurethane suspended filler is placed in biochemical pool;The effluent of biochemical pool is sent into electro-catalytic oxidation device and carries out electrolysis reaction, and electro-catalytic oxidation device uses modified anode electrode as anode electrode, and uses graphite electrode as cathode electrode;The effluent of electro-catalytic oxidation device is sent into filler adsorption tower and carries out adsorption treatment, and modified fly ash filler is placed in filler adsorption tower.The present application is pre-configured with modified polyurethane suspended filler, modified anode electrode and modified fly ash filler for coking wastewater advanced treatment for the water quality characteristics of coking wastewater, can economically and efficiently reduce the content of TOC, total fluorinated alkyl compound and total cyanide in coking wastewater.

The present application relates to a kind of new process combination for coke wastewater evaporation treatment, and the present application discloses a kind of new process combination for coke wastewater evaporation treatment.The process is first to coke wastewater for deacidification, ammonia evaporation pretreatment, after adding liquid alkali and inhibitor, in turn into one effect, two effect falling film evaporation system and three effect double-heater forced circulation evaporation system, each effect separator is equipped with demister to strengthen gas-liquid separation, to prevent mist entrainment.Three effect concentrated liquid is separated by centrifugal desalting, mother liquor is recovered with carbon dioxide decomposition process, and the clear liquid is recycled;Each effect condensate is uniformly collected and can be directly introduced into biochemical treatment, and the water quality is stable and up to standard.The present application solves the problems of easy scaling, corrosion, high energy consumption and unstable effluent in traditional process by using heat energy cascade utilization, anti-fouling structure and corrosion-resistant material, and has the advantages of stable operation, energy saving, high resource utilization rate and long-term continuous operation, and is suitable for efficient treatment and resource recovery of high-salt and high-phenol coke wastewater.

A phenol extraction system for semi-coke wastewater treatment is characterized in that a solvent conveying header pipe is divided into two paths, one path is connected with a solvent inlet in the lower part of a first extraction tower, and the other path is connected with a solvent inlet in the lower part of a second extraction tower; the upper part of the first extraction tower is connected with a wastewater input pipe and an extract overflow pipe, an extract input port at the lower part of the first extraction tower is connected with an extract output port of an extract tank through an extract conveying pump set, and an extract input port of the extract tank is connected with an extract output port at the upper part of the second extraction tower; a wastewater output port at the bottom of the first extraction tower is connected with an input port of a wastewater conveying pump set I, an output port of the wastewater conveying pump set I is connected with a wastewater inlet at the upper part of the second extraction tower, and a wastewater output port at the bottom of the second extraction tower is connected with an input port of a wastewater conveying pump set II; and an output port of the wastewater conveying pump set II is connected with the extracted wastewater conveying pipe. The device disclosed by the utility model has the advantages of high removal efficiency of phenolic substances and stability in operation.

The invention discloses a coking wastewater treatment method based on gas ratio combined precipitation, which comprises the following steps: adding an acidic reagent and PAM (polyacrylamide) into coking wastewater, and removing small molecular weight toxic substances, specifically thiocyanide and cyanide, and large molecular weight toxic substances, specifically more than ternary phenol and tar in the wastewater through a gas ratio combined precipitation device, the method comprises the following steps: treating the coking wastewater through a GDiAR-F anaerobic reactor, removing three-element or less phenol and macromolecular COD (Chemical Oxygen Demand) through a GDiAR-F anaerobic reactor, removing micromolecular COD, ammonia nitrogen, TN (Total Nitrogen) and TP (Total Phosphorus) in the wastewater through a secondary A / O (Anaerobic / Oxic) device, and finally enabling the effluent to reach the standard, thereby completing the comprehensive and efficient treatment The coking wastewater is treated by adopting a gas ratio combination precipitation device, a GDiAR-F anaerobic reactor and a secondary A / O device, so that the effluent of the coking wastewater is stably discharged in a standard reaching manner. The method does not need to add activated carbon, is simple to operate and low in cost, can greatly reduce the operating cost of each ton of wastewater, and achieves the direct emission standard of Emission Standard of Pollutants in Coking Industry, thereby having wide development potential.

The present invention relates to an oil removal system for treating semi-coke wastewater, which comprises a pretreatment unit, a primary separation unit and a secondary separation unit connected in sequence. The pretreatment unit is used for preliminary oil-water separation. The primary separation unit includes an oil drainage area, a separation area and a heavy oil area from top to bottom. A water distribution pipe and an air pipe are arranged in the separation area to input semi-coke wastewater and air bubbles into the separation area respectively. At least one movable separation rotor is arranged in the separation area to stir the semi-coke wastewater and promote oil-water separation. The oil drainage area is provided with a first oil drainage port for discharging the separated light oil, and the heavy oil area is provided with a heavy oil drainage port for discharging the separated heavy oil and oil residue. The secondary separation unit includes an oil phase area and a mixing area from top to bottom. A water inlet pipe and at least one movable demulsification rotor are arranged in the mixing area to demulsify the wastewater treated by the primary separation unit and further separate oil and water.

The utility model discloses a coking wastewater purification treatment device which comprises a base and a group of cylindrical filters arranged on two sides of the base, and a continuous filtering mechanism and a cleaning mechanism are respectively arranged in the group of cylindrical filters. The cleaning mechanism comprises a mounting plate, an adjusting motor, an adjusting disc, a group of guide sleeves, a group of sliding rods, a cleaning motor, a rotating shaft, a sliding shaft sleeve, a group of driving gears, a group of cleaning shafts and a group of cleaning brushes, and the continuous filtering mechanism comprises a flow guide pipe I, a group of filtering inner cylinders, a flow guide pipe II, a group of rotating shafts and two groups of circular switching valves. The continuous filtering device has the beneficial effects that the continuous filtering mechanism is arranged in one group of cylindrical filters, and two groups of circular switching valves are adopted to alternately switch one group of cylindrical filters for use, so that continuous filtering treatment of coking wastewater can be realized, the filtering inner cylinder needing to be cleaned can be automatically cleaned by matching with the cleaning mechanism, and the continuous filtering device is convenient to use and high in practicability. And the purification treatment efficiency of the coking wastewater is improved.

The present application belongs to the technical field of wastewater treatment, and relates to a method for pretreating coking wastewater by zero-valent iron process combined with ultrasonic-flocculation method, comprising the following steps: 1) the wastewater is subjected to heating and ultrasonic degradation treatment; 2) air is introduced into the wastewater after ultrasonic degradation, and a composite flocculant, iron filings and coal-based acicular coke powder are sequentially added, and ultrasonic stirring and standing and sedimentation are performed to complete the pretreatment. The present application provides a method for pretreating coking wastewater by zero-valent iron process combined with ultrasonic-flocculation method, which effectively removes pollutants in the coking wastewater, improves the subsequent biodegradability of the wastewater, has low implementation cost, and has large-scale popularization and application value.

This invention pertains to a coking wastewater oil removal device in the field of coking wastewater treatment technology. Multiple floats (15) are arranged around the filter pipe (13) of the floating oil suction component. The floats (15) are connected to the filter pipe (13) via a connecting frame (14). A recessed structure (40) is provided at the upper end of the filter pipe (13), and an opening is provided on the recessed structure (40) to connect to the filter pipe (13). A telescopic pipe (17) is connected to the lower end of the filter pipe (13). One end of the telescopic pipe (17) is connected to a rope (7), and the other end of the rope (7) passes around a pulley (5) and connects to a lifting motor (12). The telescopic pipe (17) extends to the outside of the sedimentation tank (8) and connects to the main oil outlet pipe (34). The coking wastewater oil removal device of this invention has a simple structure, can conveniently and quickly remove oil from coking wastewater, and can reliably adjust the sinking depth of the floating oil suction device in the sedimentation tank.

The utility model belongs to the technical field of treatment devices, and particularly relates to a coking wastewater ozone catalytic oxidation advanced treatment device, which comprises a reaction tower, a catalytic oxidation device, a catalytic oxidation device and a catalytic oxidation device, the ozone generator can guide ozone into the cavity; the driving assembly can apply rotating force into the cavity, so that the catalytic ozonation advanced treatment of the coking wastewater is more uniform; and the collecting assembly is coupled with the driving assembly, the collecting assembly is set to rotate along with the driving assembly and collect floating foam in the cavity, the driving piece is started to drive the first rod to rotate, the first rod drives the third rod to rotate, the third rod drives the plate body to rotate, and the plate body drives the collecting protrusion to rotate; at the moment, the collecting protrusions continuously make contact with the floating foam above the liquid level in the cavity, part of the floating foam is collected between the plate body and the collecting protrusions to be stored, and therefore the influence of the floating foam on the interior of the cavity is reduced.

The application relates to an oil-displacing demulsifier and a preparation method thereof. First, magnetic carbon nanotubes are prepared by depositing ferric chloride hexahydrate and copper sulfate pentahydrate on the surface of carbon nanotubes; second, hyperbranched polymers with terminal double bonds are prepared; then, the two are mixed to obtain hyperbranched grafted magnetic carbon nanotubes; finally, allyl polyoxyethylene ether is continuously polymerized in situ to obtain the oil-displacing demulsifier. The oil-displacing demulsifier prepared by the application is suitable for oil-displacing demulsification treatment of coking wastewater in the early stage. The coking wastewater is complex in composition, contains little oil, but contains a lot of organic components. The polyether with multiple branched chains can form a net trapping effect in the water body, so that oil and water can be quickly gathered and separated in an emulsified state, and the oil removal rate can reach more than 97%. Meanwhile, the demulsifier has magnetism, can be recycled through magnetic separation, and the oil removal rate can still reach more than 92% after ten cycles of demulsification. The oil removal effect is good with a small amount of addition, and the coking wastewater treatment process is simplified.

The invention discloses a semi-coke wastewater treatment process and a resource utilization method, and relates to the technical field of wastewater treatment. Relates to a combined method for adjusting oil separation, alkaline coagulation, electrocatalytic flotation oil removal, acidification demulsification and filtration, extraction dephenolization, multistage countercurrent centrifugal extraction and crude phenol recovery, alkaline stripping deamination and ammonium sulfate recovery, and can efficiently remove oil, phenols and ammonia nitrogen pollutants, realize resource recovery and enable effluent to reach the standard. The process is compact in structure and simple and convenient to operate, does not depend on a complex biochemical or membrane technology, has good industrial applicability, and provides a feasible wastewater zero discharge and resource utilization path for semi-coke production enterprises.

According to the semi-coke wastewater zero-discharge treatment device and method, for semi-coke wastewater subjected to oil removal, ammonia distillation and dephenolization pretreatment, firstly, the oil content is reduced to be smaller than 20 mg / L through nitrogen gas flotation, and the wastewater is subjected to hydrolytic acidification, two-stage anaerobic and aerobic biochemical treatment and secondary sedimentation to be subjected to primary biochemical treatment till the COD is smaller than 150 mg / L; secondly, further reducing COD (Chemical Oxygen Demand) to 60mg / L through dosing coagulation reaction precipitation, catalytic ozonation and BAF (Biological Aerated Filter) deep biochemical treatment; heavy metals, hardness and suspended matters are removed through reaction precipitation and multi-stage filtration, a reverse osmosis system is used for concentration and purification, pure water with TDS smaller than 300 mg / L is produced for reuse, and the TDS of concentrated water reaches 120000 mg / L; finally, the concentrated water is subjected to evaporative crystallization hot-method salt separation through MVR, sodium chloride with the purity being 98.5% and anhydrous sodium sulfate with the purity being 98% are produced, and the purpose of semi-coke wastewater zero-discharge treatment is achieved.

The invention relates to the technical field of waste resource utilization, in particular to an amino capronitrile residue modified titanium silicalite molecular sieve as well as a preparation method and application thereof. The method comprises the following steps: by taking a waste titanium silicalite molecular sieve as an adsorbent, carrying out adsorption treatment on the coking wastewater by adopting the adsorbent, and carrying out primary ball milling and primary drying treatment to obtain a pretreated titanium silicalite molecular sieve; and mixing the pretreated titanium silicalite molecular sieve, the amino-capronitrile residue and an aldehyde compound, and carrying out secondary ball milling and secondary drying treatment to obtain the amino-capronitrile residue modified titanium silicalite molecular sieve. According to the method, the waste titanium silicalite molecular sieves adsorbing the coking wastewater are subjected to surface modification by taking the amino capronitrile residues as a modifier, so that the problems of poor dispersity and poor interfacial compatibility of the waste molecular sieves in a rubber matrix are solved, and the mechanical property of the rubber composite material is also remarkably improved; therefore, the purposes of treating waste with waste and harmlessness and resource utilization of solid waste are achieved.

The present invention discloses an integrated treatment device for coal-based semi-coke wastewater, which relates to the technical field of wastewater treatment and includes support legs. A platform plate is fixedly installed on the support legs. A slag filtering assembly is rotatably installed on the platform plate through a first support plate, a second support plate, and a third support plate. The slag filtering assembly includes a sedimentation barrel, on which a rotating track, a rotating water outlet, a rotating water inlet, a sediment collection tank, and a slag discharge port are provided. The slag filtering assembly provided by the present invention can preliminarily filter out the coal slag in the semi-coke wastewater, prevent blockage of the equipment, and thus improve the treatment speed of the wastewater. The provided limiting assembly can automatically and regularly discharge the coal slag filtered by the slag filtering assembly, so as to ensure that the slag filtering effect of the slag filtering assembly will not be reduced after long-term operation. The provided oil separation part can separate the floating oil, water, and heavy oil in the wastewater, and solve the problem that the excessive oil content in the semi-coke wastewater will cause blockage of the phenolic recovery heat exchanger and the trays.

The invention discloses a collaborative deep purification method and system for phenol-cyanamide in coking wastewater, and belongs to the technical field of industrial wastewater treatment. According to the invention, a quality-based grading and recycling coupled system is adopted, and oil-water separation and soluble tar reduction are simultaneously realized through front-stage pretreatment, so that the subsequent treatment load is effectively reduced; catalytic oxidation and ozone oxidation are synergistically enhanced in the middle section, so that favorable conditions are created for biochemical treatment; the biochemical section is used for constructing a poison-resistant flora and coupling a short-cut nitrification and denitrification or anaerobic ammonia oxidation process to realize low-carbon denitrification; at the tail end, through the synergistic effect of membrane separation and selective adsorption, the water quality of recycled water is guaranteed, and meanwhile resource recycling of ammonia nitrogen is achieved.

The present invention provides a method and system for zero-emission treatment of wastewater. The wastewater includes coking wastewater, cold rolling wastewater, power plant desulfurization wastewater, and sintering acid-making wastewater. The treatment method includes: performing first concentration pretreatment on the coking wastewater; performing second concentration pretreatment on the cold rolling wastewater; performing concentrated wastewater pretreatment on the power plant desulfurization wastewater, sintering acid-making wastewater, first concentrated water, and second concentrated water; performing membrane separation and concentration treatment on the first produced water; performing first crystallization treatment on the second produced water; and performing second crystallization treatment on the third concentrated water. The zero-emission treatment method for wastewater provided by the present invention, through the first concentration pretreatment of the coking wastewater and the second concentration pretreatment of the cold rolling wastewater, and then mixing the first concentrated water, second concentrated water, power plant desulfurization wastewater, and sintering acid-making wastewater for concentrated wastewater pretreatment, membrane separation and concentration treatment, first crystallization treatment, and second crystallization treatment, realizes the co-production of salt and nitrate by extracting salt from the wastewater, and reuses the obtained industrial fresh water to achieve zero-emission of wastewater.

The invention relates to the technical field of wastewater treatment, in particular to a coking wastewater treatment device and method.The coking wastewater treatment device comprises a box body, a plurality of supporting seats and a filter assembly, the supporting seats are arranged at the bottom of the box body, and the filter assembly comprises a filter plate, a cylinder, a through groove, a butt joint plate, a round hole, a sliding assembly and a first bolt; the filter plate is fixedly connected with the inner wall of the box body, the through groove is formed in the box body, one end of the cylinder is connected with the filter plate, the sliding assembly is arranged on the side face of the box body, the sliding assembly is connected with the butt joint plate through the first bolt, the butt joint plate is matched with the through groove, and the through groove is formed in the box body. A circular hole is formed in the butt joint plate, the circular hole is matched with the cylinder, and a liquid outlet assembly is arranged at the bottom of the front face of the box body. According to the coking wastewater treatment device and method, the problem that existing equipment is inconvenient to clean is solved.

The utility model relates to the technical field of wastewater treatment, and discloses a novel efficient biological treatment combined device for semi-coke wastewater, which comprises a DO / pH probe, a water bath pool, and a water inlet pool, a first water inlet pump, an anaerobic co-metabolism reactor, a second water inlet pump, a one-section SPNA reactor and a water outlet pool which are connected in sequence, the DO / pH probe is used for detecting the dissolved oxygen content and the pH value of sewage in the anaerobic co-metabolism reactor, the DO / pH probe is used for detecting the dissolved oxygen content and the pH value of sewage in the one-stage SPNA reactor, the water bath pool is communicated with the interlayer between the inner wall and the outer wall of the anaerobic co-metabolism reactor, and the water bath pool is communicated with the interlayer between the inner wall and the outer wall of the one-stage SPNA reactor. According to the scheme, the treatment efficiency of the coal gas wastewater is integrally improved on the basis of coupling of an anaerobic co-metabolism strengthening process technology and an anaerobic ammonia oxidation process technology, and the treatment cost of the semi-coke wastewater is reduced.