Method for preparing efficient perovskite solar cell by modifying SnO2 electron transport layer with ammonium salt
An electron transport layer, solar cell technology, applied in semiconductor/solid-state device manufacturing, circuits, photovoltaic power generation, etc., can solve problems such as poor interface contact, interface defects, and low device performance, and achieve high photoelectric conversion efficiency and grain size. Increase and improve the effect of the interface
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Embodiment 1
[0031] Example 1 Based on SNO 2 Electronic transport layer made of perovskite solar cells
[0032] Step 1: Cleaning and processing of FTO conductive substrate
[0033] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.
[0034] Step 2: Preparation of Electronic Transport Layers
[0035] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Sno 2 The solution was added dropwise on the conductive substrate, spin 30s at a rate of 3000 rpm, and then annealed on a thermometer at a temperature of 150 ° C for 30 min, and prepared an electron transport layer.
[0036] Step 3: Preparation of the perovskite film:
[0037] 613.14 mg of lead, 25.69 mg of bromide, 228.72 mg of iodide, 7.84 mg bromethylamine, 26.94 mg o...
Embodiment 2
[0042] Example 2 Based on D-SNO 2 (1 mg / ml) perovskite solar cell made by electronic transport layer
[0043] Step 1: Cleaning and processing of FTO conductive substrate
[0044] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.
[0045] Step 2: Preparation of Electronic Transport Layers
[0046] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Then 1 mg of dimethylamine hydroiodine (DMAPAI) 2 Add to 1ML SNO 2 In aqueous solution, oscillate 1min, filtered from a 0.22 μm aperture filter to give an ammonium salt-modified SNO 2 Solution D-SNO 2 . D-SNO 2 The solution was added dropwise on the conductive substrate, and 30 m was applied to 30 m in a thermometer at a temperature of 150 ° C to form an ele...
Embodiment 3
[0053] Example 3 Based on D-SNO 2 (3mg / ml) Calcium-talent solar cell made by electronic transport layer
[0054] Step 1: Cleaning and processing of FTO conductive substrate
[0055] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.
[0056] Step 2: Preparation of Electronic Transport Layers
[0057] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Then 3 mg of dimethylamine hydroiodine (DMAPAI) 2 Add to 1ML SNO 2 In aqueous solution, oscillate 1min, filtered from a 0.22 μm aperture filter to give an ammonium salt-modified SNO 2 Solution D-SNO 2 . D-SNO 2 The solution was added dropwise on the conductive substrate, and 30 m was applied to 30 m in a thermometer at a temperature of 150 ° C to form an ...
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