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Method for preparing efficient perovskite solar cell by modifying SnO2 electron transport layer with ammonium salt

An electron transport layer, solar cell technology, applied in semiconductor/solid-state device manufacturing, circuits, photovoltaic power generation, etc., can solve problems such as poor interface contact, interface defects, and low device performance, and achieve high photoelectric conversion efficiency and grain size. Increase and improve the effect of the interface

Pending Publication Date: 2022-04-05
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In perovskite photovoltaic devices, TiO 2 or SnO 2 It is often used as an electron transport layer, but due to the poor interface contact or interface defects in the device preparation process, the device performance is low

Method used

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  • Method for preparing efficient perovskite solar cell by modifying SnO2 electron transport layer with ammonium salt
  • Method for preparing efficient perovskite solar cell by modifying SnO2 electron transport layer with ammonium salt
  • Method for preparing efficient perovskite solar cell by modifying SnO2 electron transport layer with ammonium salt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1 Based on SNO 2 Electronic transport layer made of perovskite solar cells

[0032] Step 1: Cleaning and processing of FTO conductive substrate

[0033] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.

[0034] Step 2: Preparation of Electronic Transport Layers

[0035] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Sno 2 The solution was added dropwise on the conductive substrate, spin 30s at a rate of 3000 rpm, and then annealed on a thermometer at a temperature of 150 ° C for 30 min, and prepared an electron transport layer.

[0036] Step 3: Preparation of the perovskite film:

[0037] 613.14 mg of lead, 25.69 mg of bromide, 228.72 mg of iodide, 7.84 mg bromethylamine, 26.94 mg o...

Embodiment 2

[0042] Example 2 Based on D-SNO 2 (1 mg / ml) perovskite solar cell made by electronic transport layer

[0043] Step 1: Cleaning and processing of FTO conductive substrate

[0044] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.

[0045] Step 2: Preparation of Electronic Transport Layers

[0046] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Then 1 mg of dimethylamine hydroiodine (DMAPAI) 2 Add to 1ML SNO 2 In aqueous solution, oscillate 1min, filtered from a 0.22 μm aperture filter to give an ammonium salt-modified SNO 2 Solution D-SNO 2 . D-SNO 2 The solution was added dropwise on the conductive substrate, and 30 m was applied to 30 m in a thermometer at a temperature of 150 ° C to form an ele...

Embodiment 3

[0053] Example 3 Based on D-SNO 2 (3mg / ml) Calcium-talent solar cell made by electronic transport layer

[0054] Step 1: Cleaning and processing of FTO conductive substrate

[0055] The FTO conductive glass was sequentially washed with deionized water, ethanol, acetone and isopropanol, washed 30 min, and then the cleaning glass was dried in a drying tank and then treated with UV-ozone for 15 min.

[0056] Step 2: Preparation of Electronic Transport Layers

[0057] Sno 2 In combination with water, according to the volume ratio of 1: 3, the shock is mixed with a mixture of 0.22 μm aperture filtration, resulting in SNO 2 Solution. Then 3 mg of dimethylamine hydroiodine (DMAPAI) 2 Add to 1ML SNO 2 In aqueous solution, oscillate 1min, filtered from a 0.22 μm aperture filter to give an ammonium salt-modified SNO 2 Solution D-SNO 2 . D-SNO 2 The solution was added dropwise on the conductive substrate, and 30 m was applied to 30 m in a thermometer at a temperature of 150 ° C to form an ...

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Abstract

The invention belongs to the technical field of perovskite solar cells, and relates to a method for preparing an efficient perovskite solar cell through an ammonium salt modified SnO2 electron transport layer, and a perovskite solar cell device structure sequentially comprises a conductive glass substrate, an electron transport layer, a perovskite layer, a hole transport layer and a metal electrode from bottom to top. Compared with a traditional SnO2 electron transport layer, the interface between the electron transport layer and perovskite can be effectively improved by adding the ammonium salt dimethylaminopropylamine hydriodate (DMAPAI2) into SnO2. The electrical property of the electron transport layer can be effectively improved, and the crystallization process of the upper layer perovskite can be influenced at the same time, so that the grain size of the perovskite is increased. The perovskite solar cell with high photoelectric conversion efficiency is prepared based on the DMAPAI2 modified SnO2 as an electron transport layer.

Description

Technical field [0001] The present invention belongs to the technical field of perovskite solar cells, involving an ammonium salt modification SNO 2 Method for preparing a high-efficular perovskite solar cell for electron transport layers. Background technique [0002] Solar energy is a reserved, clean renewable energy source compared to traditional non-renewable fossil energy. Solar cells are one way of human use of solar energy, which can achieve direct conversion of solar to electrical energy. The perovskite solar cell is a new concept solar cell. In recent years, it has achieved rapid development in recent years, and the certification efficiency has reached 25.5% [Nature, 2021, 598, 444]. Further enhance the efficiency of the perovskite solar cell and solve the stability problem of the calcito-titanium-titanium battery is very significant for the industrialization of the perovskite solar cell. [0003] The perovskite solar cell mainly includes five parts, a transparent electr...

Claims

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Application Information

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IPC IPC(8): H01L51/42H01L51/48
CPCY02E10/549
Inventor 史彦涛马红茹
Owner DALIAN UNIV OF TECH