Heat-aging-resistant polylactic acid composite material and preparation method thereof

A polylactic acid material and heat-resistant aging technology, applied in the field of polymer materials, can solve the problems of poor heat resistance, poor heat resistance of polylactic acid, and limited application range, etc., to achieve improved heat aging resistance, improved heat aging resistance, The effect of improving compatibility

Pending Publication Date: 2022-04-12
WANHUA CHEMICAL (NINGBO) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, due to the low glass transition temperature of polylactic acid, there is a problem of poor long-term heat resistance, which cannot meet the long-term use requirements in hot environments, which greatly limits its application range to a certain extent.
Chinese patent CN201610711838.0 preparation method of heat-resistant and durable polylactic acid composite material and heat-resistant and durable polylactic acid composite material discloses that the performance of polylactic acid is improved by adding modified sisal fiber and shell powder, However, the improvement of its thermal aging resistance is not obvious; Chinese patent CN201510253197.4, a PLA resin toughening modified material and its preparation method, discloses a method of improving the thermal aging resistance of polylactic acid res...

Method used

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Examples

Experimental program
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Effect test

preparation example

[0022] First, prepare monomethoxy polyethylene glycol-polylactic acid (MPEG-PLA) diblock copolymer: weigh 80% polylactic acid and 20% polyethylene glycol monomethyl ether, polylactic acid, Polyethylene glycol monomethyl ether is dissolved with acetone and ethanol respectively to be 10% polylactic acid and 10% polyethylene glycol monomethyl ether solution in mass fraction, and then add 1% stannous octoate in polylactic acid solution The catalyst is uniformly added to the polyethylene glycol monomethyl ether solution while stirring, and polymerized for 30 minutes under a vacuum condition of 10 Pa to obtain a methoxy polyethylene glycol-polylactic acid (MPEG-PLA) diblock copolymer.

[0023] Secondly, prepare diethyl tartrate modified terpene resin: heat the terpene resin of mass fraction 80% to molten state, keep warm for 30min, then add 10% polyvinyl alcohol to the terpene resin of melting, then with 2000r / / Stir at a high speed of min for 2 hours, then add 10% diethyl tartrate ...

Embodiment 1

[0026] The composition is: polylactic acid 56%, polyadipate-butylene terephthalate 20%, diethyl tartrate modified terpene resin grafted modified monomethoxy polyethylene glycol-polylactic acid ( MPEG-PLA) double-block copolymer 20%, plasticizer 2%, lubricant 2%, the above materials were dried at 80°C for 4 hours, mixed evenly, and melted and extruded at 180°C through a twin-screw extruder Pelletize and dry at 80°C for 4 hours to prepare a polylactic acid composite material.

Embodiment 2

[0028] The composition is: polylactic acid 66%, polyadipate-terephthalate 20%, diethyl tartrate modified terpene resin grafted modified monomethoxy polyethylene glycol-polylactic acid ( MPEG-PLA) double-block copolymer 10%, plasticizer 2%, lubricant 2%, the above materials were dried at 80°C for 4 hours and mixed evenly, melted and extruded at 180°C through a twin-screw extruder Pelletize and dry at 80°C for 4 hours to prepare a polylactic acid composite material.

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PUM

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Abstract

The invention discloses a heat-aging-resistant polylactic acid composite material and a preparation method thereof, and relates to the technical field of biodegradable plastics, and the heat-aging-resistant polylactic acid composite material is prepared from the following components in percentage by weight: 20-80% of polylactic acid, 10-50% of poly (butylene adipate-co-terephthalate), 5-10% of a compatilizer, 1-5% of an antioxidant and 1-5% of a lubricant. The adhesive comprises the following components in percentage by weight: 5-20% of diethyl tartrate modified terpene resin grafted modified monomethoxy polyethylene glycol-polylactic acid double-block copolymer, 0.2-5% of plasticizer and 0.2-5% of lubricant. The polylactic acid material can be used in food fields of meal boxes, water cups and the like, has certain light aging resistance, can be applied to the fields of mulching films, food packaging films and the like, and expands the application field of the polylactic acid material.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a heat-resistant aging polylactic acid composite material. Background technique [0002] Traditional plastic packaging materials and plastic water cups and lunch boxes are usually made of polypropylene and polycarbonate, but they are difficult to recycle after use, causing serious environmental pollution problems. With the enhancement of people's awareness of environmental protection, Environmentally friendly polymer materials have received extensive attention. As a renewable resource, polylactic acid not only has good biodegradability, but also has good mechanical strength and processing properties. Therefore, polylactic acid has broad application prospects in the field of plastic applications. [0003] However, due to the low glass transition temperature of polylactic acid, there is a problem of poor long-term heat resistance, which cannot meet the long-t...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08L67/02C08L51/00C08L51/08
Inventor 师杰吴俊李明哲陈景威彭水娇
Owner WANHUA CHEMICAL (NINGBO) CO LTD
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