Starch-based drilling fluid and preparation method thereof
A drilling fluid and starch-based technology, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of weakening the environmental protection effect of an environmentally friendly starch-based single agent, to inhibit hydration and dispersion, stabilize the well wall, reduce the dehydration effect
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[0045] In the embodiment of the present invention and comparative example, the preparation method of described nanoscale starch microspheres comprises the following content:
[0046] (1) Weigh a certain amount of starch, α-amylase and mix with water for curing treatment;
[0047] (2) Add an organic solvent to the feed liquid obtained in step (1), and carry out solid-liquid separation after standing;
[0048] (3) The solid phase material obtained after separation is further subjected to centrifugation, washing and drying;
[0049] (4) Mix the material obtained in step (3) with the sodium trimetaphosphate solution, mix evenly, and then carry out standing treatment, and then perform centrifugation, washing and drying after further curing treatment;
[0050] (5) Mix the material obtained in step (4) with water and heat to boiling state, and cool down to 30-80°C after a period of treatment;
[0051] (6) Add stabilizer and zwitterionic surfactant to the material obtained in step (...
Embodiment 1
[0064] Weigh 7 parts of corn starch and 0.035 parts of α-amylase into 100 parts of deionized water, and maintain at 50°C for 25 minutes. Add 200 parts of ethanol dropwise to the feed liquid, let the feed liquid settle after the addition of ethanol is complete, discard the supernatant, centrifuge, stir and wash the bottom insoluble matter, and dry at 35°C for 2.5 hours to obtain nano starch crystals. Weigh 5.5 parts of sodium trimetaphosphate to prepare 58 parts of solution, add nano-starch crystals into the solution and mix well, then soak for 2.5 hours, then keep the solution at 30°C for 2 hours, centrifuge, stir and wash, and dry at 30°C for 6 hours to obtain Esterified nano starch crystals. Add the esterified nano-starch crystals to 100 parts of deionized water, boil the feed solution for 25 minutes to lower the feed liquid to 65°C, add 35 parts of glycerol and 3 parts of dimethyl dodecyl sulfopropyl ammonium salt to the feed liquid , mix well. Weigh 20 parts of sodium ch...
Embodiment 2
[0067] Weigh 15 parts of mung bean starch and 0.125 parts of α-amylase into 100 parts of deionized water, and maintain at 60°C for 40 minutes. Add 400 parts of acetone dropwise to the feed liquid, and let the feed liquid settle after the addition of acetone is complete, discard the supernatant, centrifuge, stir and wash the bottom insoluble matter, and dry at 45°C for 8 hours to obtain nano-starch crystals. Weigh 10 parts of sodium trimetaphosphate to prepare 75 parts of solution, add nano-starch crystals to the solution and mix well and soak for 3 hours, then heat the solution to 60°C, maintain for 2.5 hours, centrifuge, stir and wash, and dry at 50°C for 8 hours to obtain Esterified nano starch crystals. Add the esterified nano-starch crystals to 100 parts of deionized water, boil the feed solution for 30 minutes to lower the feed liquid to 45°C, add 50 parts of polyethylene glycol 2000, 4.5 parts of dimethyl hexadecyl sulfoethyl to the feed liquid Ammonium salt, mix well. ...
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