Novel boron-containing organic compound and application thereof
The technology of a compound and a compound of the general formula is applied in the application field of the compound in the organic electroluminescence device, and the effect of prolonging the service life of the device, excellent service life and easy availability of raw materials is achieved.
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Synthetic example 1
[0136] Synthesis Example 1: Synthesis of M5
[0137] Synthesis Example 1
[0138] Synthesis of Compound M-5:
[0139]
[0140] Preparation of Intermediate M5-1:
[0141] Add α-carbazole (29.1g, 173.3mmol, 2.2eq), 1-chloro-2,6-dibromo-4-fluorobenzene (22.4g, 78.7mmol, 1eq) and cesium carbonate to a 1L single-necked bottle at room temperature (118.1g, 354.1mmol, 4.5eq), N,N-dimethylformamide (500ml), and react overnight at 120°C under nitrogen protection.
[0142] Heating was stopped, and after cooling to room temperature, 500 ml of water was added and stirred for 10 min. A large amount of white solid was precipitated. Suction filtration and column chromatography yielded 30.2 g of white solid.
[0143] Synthesis of Intermediate M5-2:
[0144] At room temperature, M5-1 (43.4g, 100mmol), 3,6-di-tert-butylaniline (90g, 320mmol), Pd 2 (dba) 3 (2.8g, 3mmol), s-Phos (1.2g, 3mmol), sodium tert-butoxide (33.6g, 350mmol), and xylene (1200ml) were added to a 2L single-necked bottle...
Embodiment approach
[0184] The OLED includes a first electrode and a second electrode, and a layer of organic material between the electrodes. The organic material can in turn be divided into regions. For example, the organic material layer may include a hole transport region, a light emitting layer, and an electron transport region.
[0185] In particular embodiments, a substrate may be used either below the first electrode or above the second electrode. The substrates are all glass or polymer materials with excellent mechanical strength, thermal stability, water resistance and transparency. In addition, a thin-film transistor (TFT) may be provided on a substrate for a display.
[0186] The first electrode may be formed by sputtering or depositing a material used as the first electrode on the substrate. When the first electrode is used as the anode, oxide transparent conductive materials such as indium tin oxide (ITO), indium zinc oxide (IZO), tin dioxide (SnO2), zinc oxide (ZnO) and any comb...
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