High-temperature alloy mold material as well as preparation method and application thereof

A mold material and high-temperature alloy technology, applied in the field of high-temperature alloy mold materials and their preparation, can solve problems such as insufficient mechanical properties, insufficient depth of nitriding layer, excess thermal strength, etc., to improve high-temperature mechanical properties, reduce material costs, Effect of improving surface hardness

Active Publication Date: 2022-07-15
NANJING INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional non-ferrous metal hot extrusion dies are mainly die steels, such as 3Cr2W8V, 4Cr5MoSiV1(H13), etc. The main problem of this type of iron-based materials is insufficient mechanical properties at high temperatures, such as red hardness and high temperature toughness, etc.
In recent years, superalloys have begun to be used in the manufacture of non-ferrous metal hot extrusion dies. This type of alloy is based on nickel and has better high temperature resistance than steel. Since the original design of nickel-based superalloys is for long-term use at high temperatures The bearing part does not consider the surface hardness required by the mold material. Therefore, when using commercial superalloys to manufacture non-ferrous metal thermal processing molds, the thermal strength is excessive and the wear resistance is insufficient, and the excessively high alloying degree makes the thermal conductivity of the material poor. The mold material is prone to thermal stress during the service process of alternating cold and hot, and even leads to cracking
[0003] Nitriding treatment is a common method to improve the surface hardness and wear resistance of steel, but for nickel-based superalloys, nitrogen atoms are almost insoluble in nickel, and stable nitrides cannot be formed at high temperatures, and nickel-based alloys face-centered The atomic stacking of the cubic crystal structure is relatively tight, which is not conducive to the diffusion of nitrogen atoms. The addition of a large number of alloy elements further reduces the diffusion ability of nitrogen in the alloy, making the nitriding of superalloys more difficult. The nitriding time of gas nitriding is generally More than 100 hours, and the depth of the nitriding layer is insufficient

Method used

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  • High-temperature alloy mold material as well as preparation method and application thereof
  • High-temperature alloy mold material as well as preparation method and application thereof
  • High-temperature alloy mold material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] The alloy composition in this example is shown in Table 1. like figure 1 As shown, the preparation steps are as follows:

[0040] (1) The total weight of the superalloy mold material is 50kg, after vacuum induction melting and protective atmosphere electroslag remelting, the composition is shown in Table 1;

[0041] (2) During the batching process before alloy smelting, the burning loss rate of Al, Ti, and B elements must be considered as 0.3, 0.2 and 0.5 respectively. After batching, it is added to the vacuum induction furnace for melting. The melting process includes melting, refining, alloying and Pouring; first put nickel, chromium, molybdenum, iron, and carbon into the crucible, and refine for 35 minutes after refining. After refining, stir the alloy liquid melt, and then power off and cool down to make the alloy liquid film; then power on, add aluminum and titanium, and smelt After 10 minutes, stir the alloy liquid melt, fill with argon, add boron and smelt for ...

Embodiment 2

[0053] The difference between this example and Example 1 is that the flow ratio of nitrogen and hydrogen in step (7) is 1:4.

Embodiment 3

[0055] The difference between this embodiment and Embodiment 1 is that the air pressure in the furnace is maintained at 400Pa in step (7).

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Abstract

The invention discloses a high-temperature alloy die material which comprises the following alloy chemical components in percentage by mass: 0.02 to 0.05 percent of C, 17.00 to 20.00 percent of Cr, 2.00 to 3.00 percent of Mo, 1.50 to 2.50 percent of Al, 1.50 to 2.50 percent of Ti, 8.00 to 10.00 percent of Fe, 0.01 to 0.05 percent of B, less than or equal to 0.01 percent of S and the balance of Ni, and the sum of the mass fractions of the Al element and the Ti element in the alloy is not less than 3.50 percent. The invention further discloses a preparation method of the high-temperature alloy die material and application of the high-temperature alloy die material in die steel. According to the method, the problem that the surface wear resistance is insufficient when an existing commercial high-temperature alloy serves as a non-ferrous metal hot working mold material is solved, the aging treatment process and the ion nitriding process are fused, the technological process is obviously shortened, and meanwhile the ion nitriding technology is environmentally friendly.

Description

technical field [0001] The invention relates to a high-temperature alloy mold material, a preparation method and application thereof, and belongs to the technical field of metal processing. Background technique [0002] In the hot processing of non-ferrous metals, especially in the production process of hot extrusion, the mold is in a harsh service environment such as high temperature, high friction and high load. The quality and life of the mold play a key role in the production quality, cost and efficiency. Traditional non-ferrous metal hot extrusion dies are mainly die steel, such as 3Cr2W8V, 4Cr5MoSiV1 (H13), etc. The main problem of such iron-based materials is insufficient mechanical properties at high temperature, such as red hardness and high temperature toughness. In recent years, superalloys have begun to be used to manufacture non-ferrous metal hot extrusion dies. These alloys are based on nickel and have better high temperature resistance than steel. Because nick...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05C22C1/02C22F1/10C23C8/36B21C25/02
CPCC22C19/056C22C1/023C22F1/10C23C8/36B21C25/025Y02P10/25
Inventor 王珏成志路顾晔林
Owner NANJING INST OF TECH
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