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Composite material comprising photocatalyst and phenolic resin group active carbon and preparation method thereof

A technology of photocatalyst and phenolic resin, which is applied in the direction of catalyst carrier, chemical instrument and method, physical/chemical process catalyst, etc. It can solve the problems of affecting the efficiency of photocatalyst decomposition of organic poison, reducing the surface area of ​​porous substances, and large consumption of oxidant. , to achieve the effect of increasing the catalytic surface area, low price and low production cost

Inactive Publication Date: 2006-01-11
WUHAN UNIV OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Scientific research has confirmed that phenol wastewater contains a large amount of harmful substances such as carcinogens and environmental hormones, and has a wide range of sources, posing a serious threat to human life and the environment. It is one of the key monitoring and treatment objects in all countries in the world. The phenol content in sewage entering urban sewers should not exceed 1.0 mg / L. At present, domestic and foreign treatment methods generally include activated carbon adsorption, biodegradation, and photocatalytic degradation. Long, high cost and other disadvantages
In recent years, Japan has successively developed photocatalyst inorganic gel coated on the surface of activated carbon, porous ceramics, and porous metal to make porous photocatalytic composite materials (Japanese Patent Application No. 2001-232206, Patent Application No. 8-196903). Collecting organic and toxic substances is beneficial to improve the efficiency of photocatalysts in decomposing organic and toxic substances. However, since photocatalysts are only coated on the surface of porous substances and cannot enter the porous interior, the efficiency of photocatalysts in decomposing organic and toxic substances will be further improved. At the same time, due to the photocatalyst coating, which reduces the surface area of ​​porous substances

Method used

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  • Composite material comprising photocatalyst and phenolic resin group active carbon and preparation method thereof
  • Composite material comprising photocatalyst and phenolic resin group active carbon and preparation method thereof
  • Composite material comprising photocatalyst and phenolic resin group active carbon and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0022] Embodiment 1: get 70 parts by weight of novolak resin powder by weight, photocatalyst (TiO 2 ) 35 parts by weight of micropowder, 70 parts by weight of activator (KOH). The phenolic resin powder is mixed with the photocatalyst micropowder, ground into a container after 200 mesh sieves, and carbonized at 500° C. for 3 hours under nitrogen protection. The carbon material obtained above is mixed with 35 parts by weight of an activator (KOH ), fully mixed, put into a container, and activated under nitrogen protection at 550°C for 2 hours. In the wastewater containing phenol, add the photocatalyst composite material identical with the weight of phenol and stir evenly, under ultraviolet light (intensity 53w / m 2 ), and irradiated for 8 hours, the measured amount of decomposition of phenol (the amount of decomposition of phenol) reached more than 51.3%. The results are shown in Table 1.

Embodiment 2

[0023] Embodiment 2: get 70 parts by weight of novolac resin powder by weight, photocatalyst (WO 3 ) 35 parts by weight, 35 parts by weight of activator (zinc chloride), press the manufacturing process method of the photocatalytic composite material of implementing 1, can obtain, photocatalyst (WO 3 ) composite material, according to the method for the treatment of phenol-containing waste water of embodiment 1, the decomposition amount of measuring phenol can reach 47.8%, the results are shown in Table 1.

Embodiment 3

[0024] Embodiment 3: get 100 weight parts of novolac resins by weight, photocatalyst (TiO 2 ) 10 parts by weight, 100 parts of activator (KOH), 5 parts of zinc chlorides, press the manufacturing process method of the photocatalyst composite material of embodiment 1, can obtain photocatalyst (TiO 2 ) composite material, the decomposition amount of phenol can reach 37.5% as measured by the method for the treatment of phenol waste water of embodiment 1. The results are shown in Table 1.

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Abstract

The invention relates to a composite of decomposing organic phenol- containing waste water, namely a photocatalyst-Arcolitebased active carbon composite, as well as its preparing method. Its character: Arcolite 40-100 shares; photocatalyst 10-50 shares; active agent 20-100 shares. Its preparing method: (1) batching; (2) carbonizing: proportionally mixing powdery Arcolite and photocatalyst powder to finely mill, screening by 200-eye sieve, and then carbonizing into powdery carbon after 1-4 hours under the protection of nitrogen gas; (3) activating: fully mixing the powdery carbon with the active agent in the weight proportion to activate for 2-4 hours under the protection of nitrogen gas, cooling the product to fully wash by water to eliminate alkali component, and then drying to obtain the finished product. Under the action of ultraviolet ray, it can make high-efficiency decomposition on organic and harmful matters of organic phenol; its production process is simple and its production cost is low.

Description

technical field [0001] The invention relates to a composite material for decomposing and treating organic phenol-containing wastewater and a preparation method thereof, in particular to a photocatalyst-phenolic resin-based activated carbon composite material and a preparation method thereof, which is suitable for decomposing and treating phenol-containing wastewater and other organic-toxic wastewater (such as Organic wastewater containing benzene, wastewater containing organic pesticides, wastewater containing organic sulfur, etc.). Background technique [0002] Scientific research has confirmed that phenol wastewater contains a large amount of harmful substances such as carcinogens and environmental hormones, and has a wide range of sources, posing a serious threat to human life and the environment. It is one of the key monitoring and treatment objects in all countries in the world. The phenol content in sewage entering urban sewers should not exceed 1.0 mg / L. At present, d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J21/06B01J23/06B01J23/30B01J23/18B01J32/00B01J20/20
Inventor 王勇吴承思万涛
Owner WUHAN UNIV OF TECH
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