Process of making rare earth doped optical fibre

A rare earth, optical fiber technology, applied in manufacturing tools, glass manufacturing equipment, optics, etc., can solve problems such as unreliability and reproducibility, parameter sensitivity, and difficult to control porosity

Inactive Publication Date: 2004-12-29
科学和工业研究委员会 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0024] 3. It is difficult to control the porosity of the deposited green layer because it is particularly sensitive to the deposition temperature, the speed at which the burner moves back and forth, and the flo

Method used

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  • Process of making rare earth doped optical fibre
  • Process of making rare earth doped optical fibre
  • Process of making rare earth doped optical fibre

Examples

Experimental program
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Effect test

Embodiment 1

[0113] Er-doped fiber

[0114] Amorphous silica microspheres synthesized by hydrolysis of tetraethoxyorthosilicate (Stober method) were dispersed in an erbium nitrate solution (kept in an ice bath) under sonication so that 98.5 mol %SiO 2 and 1.5 mol% Er 2 o 3 , followed by the addition of aqueous ammonia by known methods. The resulting product was washed with water, then centrifuged and dried under vacuum.

[0115] ·The preparation composition is 94.98SiO 2 : 3GeO 2 : 2Al 2 o 3 :0.02Er 2 o 3 (equivalent oxide mole %) for coating the inner walls of high purity transparent fused silica glass tubes.

[0116] Diluted with 98.5 mol% SiO with a silica sol containing the desired amount of tetraethoxysilane (TEOS) 2 and 1.5 mol% Er 2 o 3 coated with erbium oxide (Er 2 o 3 ) of silicon dioxide powder, so that the composition is 94.98 equivalent oxide mol% SiO 2 and 0.02 equivalent oxide mole % Er 2 o 3 of silica sol.

[0117] In the presence of a mixed solvent of 1-...

Embodiment 2

[0130] Nd-doped fiber

[0131] Amorphous silica microspheres synthesized by hydrolysis of tetraethoxyorthosilicate (Stober method) were dispersed in a neodymium nitrate solution (kept in an ice bath) under sonication so that 98.5 mol %SiO 2 and 1.5 mol% Nd 2 o 3 , followed by the addition of aqueous ammonia by known methods. The resulting product was washed with water, then centrifuged and dried under vacuum.

[0132] ·The preparation composition is 94.8SiO 2 : 3GeO 2 : 2Al 2 o 3 : 0.20Nd 2 o 3 (equivalent oxide mole %) for coating the inner walls of high purity transparent fused silica glass tubes.

[0133] Diluted with 98.5 mol% SiO with a silica sol containing the desired amount of tetraethoxysilane (TEOS) 2 and 1.5 mol% Nd 2 o 3 coated with neodymium oxide (Nd 2 o 3 ) of silicon dioxide powder, so that the composition is 94.8 equivalent oxide mol% SiO 2 and 0.20 equivalent oxide mol% Nd 2 o 3 of silica sol.

[0134] In the presence of a mixed solvent of ...

Embodiment 3

[0147] Eu doped fiber

[0148] Amorphous silica microspheres synthesized by hydrolysis of tetraethoxyorthosilicate (Stober method) were dispersed in a solution of europium nitrate (kept in an ice bath) under the action of sonication so that 99.0 mol %SiO 2 and 1.0 mol% Eu 2 o 3 , followed by the addition of aqueous ammonia by known methods. The resulting product was washed with water, then centrifuged and dried under vacuum.

[0149] ·The preparation composition is 95.99SiO 2 : 3GeO 2 : 1Al 2 o 3 : 0.01Eu 2 o 3 (equivalent oxide mole %) for coating the inner walls of high purity transparent fused silica glass tubes.

[0150] Diluted with 99.0 mol% SiO with a silica sol containing the desired amount of tetraethoxysilane (TEOS) 2 and 1.0 mol% Eu 2 o 3 coated with europium oxide (Eu 2 o 3 ) of silicon dioxide powder, so that the composition is 95.99 equivalent oxide mol% SiO 2 and 0.01 equivalent oxide mol% Eu 2 o 3 of silica sol.

[0151] In the presence of a ...

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Abstract

The present invention discloses a process for making rare earth (RE) doped optical fibre by using RE oxide coated silica nanoparticles as the precursor materia, more particularly the method of the present invention involves preparation of stable dispersions (sol) of RE oxide coated silica nanoparticles at ambient temperature and applying a thin coating on the inner surface of silica glass tube following dip coating technique or any other conventional methods, of the said silica sol containing suitable dopants selected from Ge, Al, P, etc., the coated tubes were further processed into optical preforms by following MCVD technique and fiberised in desired configuration, the novelty lies in eliminating the step of the formation of porous soot layer at high temperature by CVD process inside a fused silica glass tube for formation of the core and also in the elimination of the incorporation of the rare earth ions into the porous soot layer following the solution doping technique or other conventional methods, the direct addition of RE oxides in the sol eliminates the formation of microcrystalites and clusters of rare earth ions and prevents change in composition including variation of RE concentration in the core which results in increase in the reproducibility and reliability of the process to a great extent, further the addition of Ge(OET)4 at ambient temperature in the silica sol reduces the quantity of GeCl4 which is required at high temperature to achieve the desired Numerical Aperture.

Description

technical field [0001] The invention relates to a method of manufacturing rare earth doped optical fiber. Background technique [0002] Optical fibers based on high-purity silica have been identified as the most efficient interconnection media for optical telecommunication networks. Such optical fibers can be used as passive transmission media to guide the long-distance transmission of optical signals. However, if rare earth (RE) ions are doped into the core of such fibers, the fibers are optically active because the rare earths are pumped at appropriate wavelengths to produce characteristic emissions. Because of the aforementioned properties, rare earth-doped fibers show great potential as active devices for photonic devices such as optical amplifiers and fiber lasers at various wavelengths. It has also been found that such fibers are expected to be used as sensors for monitoring temperature and radiation dose, among other things. [0003] Erbium-doped fiber is the activ...

Claims

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Application Information

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IPC IPC(8): G02B6/00C03B37/016C03B37/018C03C1/02H01S3/06
CPCC03B37/016C03B2201/02C03B2201/12C03C1/02C03B37/01838C03C1/026C03B2201/31C03B2201/36C03B2201/28Y02P40/57B82Y30/00C03B37/018
Inventor 兰詹·森密斯·米纳提·查特吉米兰·坎蒂·纳斯卡尔米尔梅·帕尔穆库尔·钱德拉·保罗西尔玛·库马尔·巴德拉卡迈勒·达斯古普塔迪比亚杜·甘古利塔伦·班迪奥帕迪亚雅阿哈龙·热当基安
Owner 科学和工业研究委员会
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