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Method for modifying fibers

A fiber modification and fiber technology, applied in the direction of post-treatment modification of cellulose pulp, no pigment coating, etc., can solve problems such as reduction, and achieve the effect of excellent wear resistance and enhanced tensile strength

Inactive Publication Date: 2011-04-13
AICHI PREFECTURE +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, this method not only requires dissolving the cellulose in aqueous sodium hydroxide solution at low temperature, but also requires the use of this type of cellulose with a reduced crystal structure sufficient to increase solubility, e.g. by acid hydrolysis of wood pulp and in Cellulose obtained by grinding it in a ball mill, or regenerated cellulose obtained from viscose, thereby limiting the process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Disperse 50 g of the low-substituted cellulose ethers shown in Table 1 into 950 g of 0.5 wt % sodium hydroxide aqueous solution, and then use the relative collision unit "ALTEMIZER" manufactured by Sugino Machine Ltd to the dispersion to be sheared under a pressure of 150 MPa Perform high pressure dispersion. This high-pressure dispersion process was repeated 10 times to obtain a sheared low-substituted cellulose ether dispersion. A dispersion sample was prepared by adding 8 g of diphenylmethane diisocyanate per 100 g of the sheared cellulose ether dispersion. Next, the Knit Comber cotton thread #30 / 1 was dipped into the dispersion and squeezed with a roller calender to an absorption of 108%, dried thereupon, and then heated at 145° C. for 10 samples in minutes.

[0045] Each sample obtained in this way was subjected to the following test methods to evaluate fuzziness, tensile strength, abrasion resistance, antistatic property, water absorption and washing durability....

Embodiment 2 to 8

[0047] 50 g of the low-substituted cellulose ether shown in Table 1 was dispersed in 950 g of water, and then the dispersion to be sheared was subjected to high-pressure dispersion at a pressure of 150 MPa using a relative collision unit "ALTEMIZER" manufactured by SuginoMachine Ltd. This high-pressure dispersion process was repeated 10 times to obtain a sheared low-substituted cellulose ether dispersion. A dispersion sample was prepared by adding 8 g of diphenylmethane diisocyanate per 100 g of the sheared cellulose ether dispersion. Next, Knit Comber cotton thread (Knit Comber cotton thread) #30 / 1 or wool #2 / 48 was dipped into the dispersion and squeezed with a roller calender to an absorption of 108%, followed by drying , and then heated at 145°C for 10 minutes to obtain a sample.

[0048] Each sample obtained in this manner was subjected to the following test methods to evaluate fuzziness, tensile strength, abrasion resistance, antistatic property, water absorption and wa...

Embodiment 9

[0050] 50 g of the low-substituted cellulose ether shown in Table 1 was dispersed in 950 g of water, and then the dispersion to be sheared was subjected to high-pressure dispersion at a pressure of 150 MPa using an opposing collision unit "ALTEMIZER" manufactured by SuginoMachine Ltd. This process was repeated 10 times to obtain a sheared low-substituted cellulose ether dispersion. A dispersion sample was prepared by adding 8 g of a cross-linked product of polyethylene oxide glycol and diphenylmethane diisocyanate per 100 g of the sheared cellulose ether dispersion as an aqueous emulsion of a cross-linked polyurethane resin. Next, wool #2 / 48 was dipped into the dispersion and squeezed with a roller calender with an absorption of 108%, and then heated at 95° C. for 20 minutes to obtain a sample. The samples thus obtained were subjected to the following test methods, and the results are shown in Table 1.

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Abstract

A method for modifying fibers is provided, which method comprises suspending and dispersing in water under shear force a cellulose ether having such a low degree of substitution that a molar degree of substitution with an alkyl group and / or a hydroxyalkyl group ranges from 0.05 to 1.3, applying the resulting dispersion and a crosslinking agent or an aqueous resin emulsion to fibers, and thermallytreating the applied fibers.

Description

technical field [0001] The invention relates to a fiber modification method. Background technique [0002] In order to avoid fiber fuzzing, enhance the tensile strength and wear resistance of fibers, make the fibers antistatic and water-absorbent, and make the fibers have a good feel and texture such as a smooth and dry touch to the fibers, a method called A method of "linen-like finishing" in which viscose is adhered to the fibers and set to regenerate, then rinsed with water and dried to coat the surface of the fibers with regenerated cellulose. [0003] However, in this connection, the fiber modification method for forming a coating from regenerated fibers derived from viscose comprises the steps of dissolving cellulose xanthate obtained by denaturing cellulose with highly reactive carbon disulfide in aqueous sodium hydroxide solution , followed by coagulation and regeneration of the cellulose resulting in a viscose solution coated on the fibers. This presents a problem...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H19/34D21H11/20
Inventor 丸山直亮早川和久谷冈庄治都筑秀典鹿野刚河村博司早田常夫
Owner AICHI PREFECTURE
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