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A method to reclaim and dispose waste secondary lithium ion battery

A lithium-ion battery, recycling technology, applied in battery recycling, electronic waste recycling, waste collector recycling, etc., can solve the problems of electrode material and carrier film shell metal adhesion, mechanical processing hazards, environmental pollution, etc., to achieve high efficiency and safety. The effect of clean industrialization, reduction of corrosion resistance requirements, and reduction of cross-contamination

Inactive Publication Date: 2007-05-16
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Used secondary lithium-ion batteries usually have some charge remaining when they are discarded. A large number of battery accumulations can cause fire or even explosion. At the same time, it may also cause danger due to short circuit during mechanical handling.
[0005] Secondary lithium-ion batteries contain electrolytes and positive and negative electrodes. If they are discarded randomly, they will cause great pollution to the environment.
[0007] This technology is aimed at all kinds of hybrid batteries. Although the processing range is wide, the technical feature 1) adopts wet discharge, electrolyte leakage, and the treatment of discharge medium has complicated procedures; feature 3) uses the whole battery core to break , the electrode material and the carrier film and the shell metal are very seriously adhered, making the subsequent separation process difficult or incomplete; the cleaning process after crushing consumes a lot of water; The human body and the environment are highly toxic, so breaking them together will cause the diffusion of pollution; in addition, in features 4) and 5), acid and alkali are repeatedly used to process the mixed pure metal at a higher temperature, which not only wastes materials, but also requires equipment. The use of materials with high corrosion resistance will inevitably result in high processing costs, making it difficult to achieve industrialization

Method used

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  • A method to reclaim and dispose waste secondary lithium ion battery

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example 1

[0032] A waste battery marked with the words "lithium-ion battery", model A4NN4229A, nominal voltage 3.7V, weight 19.6g, measured voltage 3.6V. Carry out manual disassembly to obtain the plastic case (identified as PC), circuit board and battery core. The battery core is put into the discharge circuit, the circuit resistance is 3.5 ohms, and the voltage drops to 0.3V after 20 minutes. The battery core is continued to be manually disassembled to obtain the battery core casing (aluminum) and the battery core winding structure. The battery core winding structure was placed in 20ml of propylene carbonate, soaked at 70°C for 30 minutes, the positive and negative electrode materials were soft and separated from the current collector foil, and the current collector copper foil, aluminum foil and insulating paper tape were taken out, and the black substance was obtained by filtration. The solution was distilled at 70°C under 0.5 atmospheric pressure environment, and 5ml of residual li...

example 2

[0034] A waste battery marked with the words "lithium-ion battery" and "Li-ion", model TJT-SA P802, nominal voltage 3.6V, weight 19.6g, measured voltage 0.1V. Mechanically cut to obtain a plastic casing (marked as PC), a circuit board and a battery core. The battery core does not need to be discharged, and is further mechanically cut directly to obtain the battery core casing (aluminum) and the battery core winding structure. Put the winding structure of the battery core into 20ml of dimethylacetamide, soak at room temperature, and assist with mechanical stirring. After 30 minutes, the positive and negative electrode materials are soft and completely separated from the current collector foil. Take out the current collector copper foil, aluminum foil and insulating paper tape , and filtered to obtain black matter. The solution was distilled at 50°C and 0.2 atmospheric pressure, and 6ml of residual liquid (a concentrated solution of electrolyte in dimethylacetamide) was collect...

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Abstract

The related recovery and process method for waste secondary Li-ion cell comprises: separating cell shell, circuit board and cell core by mechanical means; discharging the core; then separating to obtain the shell and coiling material of cell core; putting the last one into some organic solvent to separate the cell polar material from collector foil, filtering to obtain the foil and active material for recovery by chemical way. With small investment, this invention is simple and safe and high yield.

Description

technical field [0001] It belongs to the technical field of electronic waste recycling and reuse, so as to ensure the pollution-free and sustainable development of the electronic industry. Background technique [0002] The invention is a recycling treatment technology researched and developed aiming at the secondary lithium ion battery produced by a large number of waste electronic products at present. Secondary lithium-ion batteries can also be called rechargeable lithium batteries. All countries in the world are facing the problem of recycling waste electronic products. Secondary lithium-ion batteries are widely used in portable electronic products such as mobile phones and digital cameras. The mobile phone is a communication tool with a very high elimination rate. Although its design service life is generally about seven or eight years, the service life of mobile phone batteries is shorter, generally about two or three years, and the service life of mobile phone batter...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/54B09B3/00B09B5/00
CPCY02E60/12Y02W30/82Y02W30/84
Inventor 夏志东郭雅峰雷永平郭福史耀武毛倩瑾刘建勇王爱菊
Owner BEIJING UNIV OF TECH
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