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Oiling Agent for Fiber Treatment

a technology of oiling agent and fiber, which is applied in the direction of lubricant composition, chemistry apparatus and processes, organic chemistry, etc., can solve the problems of poor rewindability in the subsequent processing step, marked reduction in productivity, and high rate of rewinding in the step of warping, and achieve excellent anti-tackiness properties, stable rewinding, and marked tendency to tack

Inactive Publication Date: 2008-08-21
SANYO CHEM IND LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0007]Accordingly, it is an object of the present invention to provide a lubricant for treating fibers which produces good anti-tacking property against fiber-to-fiber tackiness in the production of fibers. A further object is to increase the time-dependent stability of a lubricant for fibers and provide a lubricant for fibers which makes it possible to stably produce fibers while eliminating the problem of aggregation and precipitation of anti-tackiness agents or the problem of uneven application to fibers, among others, in or during use thereof.

Problems solved by technology

However, every method encounters a problem, namely poor rewindability in a subsequent processing step due to a marked tendency for fiber-to-fiber tackiness.
In the field of warp knitting, in particular, a high rate of rewinding is required in the step of warping.
If the rewindability is poor, yarn breaking, among others, is caused in the step of warping, leading to a marked reduction in productivity.
However, such a solid ingredient as mentioned above in the lubricants proposed in Patent Documents 1 and 2 is poor in dispersion stability, aggregating and precipitating in lubricants with the passage of time; therefore, when such lubricants are used, uniform application thereof to fibers becomes difficult and, accordingly, the anti-tacking property can hardly be produced to a sufficient extent and such a problem as yarn breaking may possibly be produced due to changes in tension in a subsequent processing step.
For attaining a sufficient anti-tacking property, the amount of addition of the anti-tackiness agent must be raised; the result is that the viscosity of the lubricants increases and the uniform application to fibers becomes difficult to attain.
It is also a problem that the silicone-modified anti-tackiness agents are expensive.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
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Effect test

production example 1

[0199]A powder (71.2 parts) of low-molecular-weight polypropylene with a Mn of 2,500 and a density of 0.89 as obtained by the thermal degradation method was dispersed in 500 ml of tetrahydrofuran (THF), 6.5 parts of 9-borabicyclononane was added, and the mixture was heated at 55° C. for 5 hours with stirring. The temperature was lowered to 45° C., 30 ml of oxygen was passed through the liquid, 22.3 parts of maleic anhydride was added, and the reaction was allowed to proceed for 16 hours. Thereafter, the reaction mixture was poured into 5 liters of 2-propanol, the solid was filtered off to give acid-modified polypropylene [acid value: 335.1, Mn: 3,000, number of carboxyl groups per molecule: 16.0].

example 1

[0201]A mixture of 1 part of magnesium distearate, 2 parts of polyoxyethylene isotridecyl ether-acetic acid sodium salt (adduct with 3 moles of EO), 4 parts of polyoxyethylene lauryl ether-acetic acid (adduct with 2.5 moles of EO), 2 parts of didecyldimethylammonium polyoxyethylene lauryl ether-acetate (adduct with 2.5 moles of EO) and 60 parts of liquid paraffin was stirred at 70 to 80° C. for 1 hour. Then, 31 parts of polydimethylsiloxane was added, and the resulting mixture was cooled to 30° C., whereby the lubricant for treating fibers of Example 1 was prepared.

example 2

[0202]A mixture of 2 parts of magnesium distearate, 3 parts of polyoxyethylene isotridecyl ether-acetic acid sodium salt (adduct with 3 moles of EO), 6 parts of polyoxyethylene lauryl ether-acetic acid (adduct with 2.5 moles of EO), 3 parts of didecyldimethylammonium polyoxyethylene lauryl ether-acetate (adduct with 2.5 moles of EO) and 68 parts of liquid paraffin was stirred at 70 to 80° C. for 1 hour. Then, 18 parts of polydimethylsiloxane was added, and the resulting mixture was cooled to 30° C., whereby the lubricant for treating fibers of Example 2 was prepared.

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Abstract

The present invention has its object to provide a lubricant for fibers which shows, in particular, good anti-tackiness property against fiber-to-fiber tackiness in the manufacture of elastic fibers, and good time-dependent stability for a long period of time as a lubricant for treating fibers.The present invention provides a lubricant for treating fibers to be used for fibers made of a polymer material (a) wherein the angle of contact with water at 25° C. of the surface of a sheet made of the material (a) is not greater than 60° and the angle of contact with water at 25° C. of the surface of the sheet made of the material (a) applied with the lubricant for treating fibers is 70° to 180°.

Description

TECHNICAL FIELD[0001]The present invention relates to a lubricant for fibers and, more particularly, to a lubricant for treating fibers to be used in the spinning step in the manufacture of elastic polyurethane fibers for obtaining elastic polyurethane fibers showing little tendency toward fiber-to-fiber tackiness and showing good rewindability.BACKGROUND ART[0002]Among the methods of producing elastic polyurethane fibers that are known in the art, there are the melt spinning, dry spinning and wet spinning methods, among others. However, every method encounters a problem, namely poor rewindability in a subsequent processing step due to a marked tendency for fiber-to-fiber tackiness.[0003]In recent years, the need has been increasing to improve the productivity in producing elastic fibers by increasing the rate of rewinding. In the field of warp knitting, in particular, a high rate of rewinding is required in the step of warping. If the rewindability is poor, yarn breaking, among oth...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10M105/76C10M107/02C10M101/02C10M107/50C10M129/28C10M135/10C10M145/10C10M169/04D06M13/02D06M13/188D06M15/643
CPCD21C9/002D06M15/643C10M129/28C10M101/02C10M107/50
Inventor AZUSE, IKUNORIWAKAHARA, YOSHIYUKISUZUKI, KAZUMITSU
Owner SANYO CHEM IND LTD
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