The present invention relates to synergistic herbicidal compositions comprising combination of two or more herbicides. The present invention also relates to herbicidal composition comprising combination of Penoxsulam and one or more additional herbicides selected from Pyrazosulfuron or its derivative, Bispyribac and 2,4-Dichlorophenoxy
acetic acid derivatives or combinations thereof. The present invention also relates to herbicidal composition comprising combination of Penoxsulam and one or more additional herbicides,
wetting agent, dispersing agent and other
agrochemical auxiliaries, wherein said additional herbicides are selected from Pyrazosulfuron or its derivative, Bispyribac, 2,4-Dichlorophenoxy
acetic acid derivatives (2,4-DEE and 2,4-D
sodium salt) or combinations thereof. The present invention also relates to a process for the preparation of herbicidal composition comprising combination of Penoxsulam and one or more additional herbicides.