Application of carbon nano tube in polyethylene fiber composite weftless fabric

A polyethylene fiber and carbon nanotube technology, which is applied in the direction of hydrocarbon copolymer adhesives, single-component polyolefin artificial filaments, non-woven fabrics, etc., can solve the impact of composite non-woven fabrics on comprehensive performance and comprehensive mechanical strength Poor, increased load and other problems, to achieve the effect of excellent anti-shock performance, blunt impact force, and improve heat resistance

Inactive Publication Date: 2007-08-15
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, this kind of composite non-weft fabric, due to the shortcomings of the adhesive itself as the matrix, affects the comprehensive performance of the composite non-weft fabric, which is reflected in poor heat resistance, poor comprehensive mechanical streng

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0027] Example 1

[0028] Immerse 2g of carbon nanotubes in a mixed solution of 100ml of sulfuric acid and potassium permanganate, and treat them at reflux temperature for 1.5 hours. The concentration of potassium permanganate in sulfuric acid is 5g / 100ml; combine 2g of purified carbon nanotubes with The butyl titanate coupling agent was refluxed in ethanol for 2 hours to obtain carbon nanotubes grafted with the coupling agent. The concentration of the titanate coupling agent in the ethanol was 0.03 g / ml.

[0029] Mix a certain amount of carbon nanotubes with the adhesive, stir at 60-80°C for 1-2h, and defoam in vacuum. The reinforced UHMWPE fiber is wound in parallel on a winder, and then glue is applied to the UHMWPE fiber (or the UHMWPE fiber is immersed in the adhesive). The number of glue application is 1-2 times, pay attention to the glue application evenly. The adhesive used in this embodiment is KRATON G-1650, which is dissolved in a mixed solvent (hexane: diethyl ether: e...

Example Embodiment

[0031] Example 2

[0032] Except for the addition of carbon nanotubes at 2g / m 2 Except for the weftless fabric, everything else is the same as in Example 1, and a composite weftless fabric is obtained.

[0033] Bulletproof effect: 40 layers, 450mm×450mm AD=160g / m 2 UD materials are neatly superimposed on the target frame backed by cement, using 51-type ordinary bullets, according to the US 662EV 50 Test standard, V is measured with 51 type long barrel and 51 type ordinary bullet (lead core bullet) 50 ≥557m / s.

Example Embodiment

[0034] Example 3

[0035] Except that no carbon nanotubes are added, a certain amount of organic montmorillonite is mixed with the adhesive at a mixing ratio of 1:19, stirred at 60-80°C for 1-2h, and vacuum degassing, everything else is the same as in Example 1. The composite non-weft fabric was prepared. The blending amount of montmorillonite is 4.6g / m 2 Weftless cloth.

[0036] Bulletproof effect: 40 layers, 450mm×450mm AD=160g / m 2 UD materials are neatly superimposed on the target frame backed by cement, using 51-type ordinary bullets, according to the US 662EV 50 Test standard, V is measured with 51 type long barrel and 51 type ordinary bullet (lead core bullet) 50 ≥580m / s.

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Abstract

The invention relates to an application of carbon nanometer tube in polythene fiber composite weft-free cloth, wherein the nanometer particles are two-dimension nanometer carbon tube, as seamless hollow tube surrounded by hexagon carbon atom grid, whose two ends are covered by hemi-spherical large Furehee molecules, while the diameter is from zero-point nanometer to tens nanometers and the length is from several micrometers to hundreds micrometers. And the production comprises that (1) pretreatment of carbon nanometer tube as purifying and organic treatment that refluxing 1-4g carbon nanometer tube/ml and 0.01-0.04g/ml titanic acid coupler in organic solvent for 1-3h, (2) mixing carbon nanometer tube and adhesive for 1-2h at 60-80Deg. C, and defoaming at vacuum, (3) uniformly laying strengthener UHMWPE fiber on a coiler, (4) plating adhesive for 1-2 times and drying at 40-70Deg. C, (5) drying at 60+-3Deg. C for 10-20min. The invention can increase the application temperature of polythene fiber composite weft-free cloth as 10Deg. C, and improve 20% of impact resistance, with better thermal resistance, strength and creep resistance, or the like.

Description

technical field [0001] The invention belongs to the field of nano textile applications, in particular to the application of carbon nanotubes in polyethylene (UHMWPE) fiber composite non-woven fabrics. Background technique [0002] Polyethylene (UHMWPE) fiber composite non-weft fabric is made of UHMWPE fibers after they are uniformly, parallel and straight arranged, then glued and dried. This process has been described in US4,916,000 and US5,149,391. The glued adhesives generally include polyethylene, cross-linked polyethylene, polypropylene, vinyl copolymer, propylene copolymer, ethylene-propylene copolymer and other olefin polymers and copolymers, as well as unsaturated polyester, polybutylene Many low-modulus resins such as diene, polyisoprene, natural rubber, epoxy resin, polyimide, etc., in addition, there are EVA, EEA, SBS, SIS, TPR, SEBS, etc. Styrene, PVB, PVA, etc., these thermoplastic high-tough glues. These low-modulus elastomers are coated on each fiber. In addi...

Claims

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Application Information

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IPC IPC(8): D04H1/58D04H3/12D04H5/04D01F6/04C01B31/02C09J11/04C09J125/08
Inventor 王依民彼・杰・莱姆斯特刘术佳
Owner DONGHUA UNIV
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